European Journal of Chemistry

Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex



Main Article Content

Gun Binzet
Ulrich Flörke
Nevzat Külcü
Hakan Arslan

Abstract

We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3.  In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

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Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and Molecular Structure of bis(4-Bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) Complex. Eur. J. Chem. 2012, 3, 37-39.

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Supporting Agencies

Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).
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