European Journal of Chemistry

Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition

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Published: Mar 31, 2010
DOI: https://doi.org/10.5155/eurjchem.1.1.15-19.6
Keywords:
Sulfides, Sulfoxides, Sulfoxidation, Catalyst-Free Condition
Section
Research Article
Issue
Vol. 1 No. 1 (2010): March 2010
Dates
Received 2010-03-24
Accepted 2010-03-24
Published 2010-03-31


Main Article Content

Davood Azarifar
Department of Chemistry, Bu-Ali Sina University, Hamedan, IR-65178, Iran
Kaveh Khosravi
Department of Chemistry, Bu-Ali Sina University, Hamedan, IR-65178, Iran

Abstract

Application of trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as an efficient and high-oxygen content reagent in selective oxidation of sulfides into sulfoxides has been successfully explored. The reactions proceeded under mild and catalyst-free conditions in dichloromethane at room temperature to provide the sulfoxides in excellent yields without any significant over-oxidation to sulfones.

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Azarifar, D.; Khosravi, K. Trans-3,5-Dihydroperoxy-3,5-Dimethyl-1,2-Dioxolane As a Novel and Efficient Reagent for Selective Sulfoxidation of Sulfides under Catalyst-Free Condition. Eur. J. Chem. 2010, 1, 15-19.

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Research Council of Bu-Ali Sina University
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