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A simple formal stereoselective synthesis of Herbarumin III
Nagendra Siddavatam (1)
, Krishnaiah Martha (2) , Krishna Reddy Vanka (3) , Biswanath Das (4,*) (1) Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad-500007, India
(2) Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad-500007, India
(3) Department of Chemistry, Sri Krishnadevaraya University, Anantapur, 515055, India
(4) Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad-500007, India
(*) Corresponding Author
Received: 16 Mar 2012 | Revised: 10 Apr 2012 | Accepted: 12 Apr 2012 | Published: 30 Sep 2012 | Issue Date: September 2012
Abstract
A formal stereoselective synthesis of Herbarumin III has been accomplished starting from butanal involving Maruoka asymmetric allylation, diastereoselective iodine-induced electrophilic cyclization and conversion of iodocarbonate into syn-epoxy alcohol as the key steps.
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DOI: 10.5155/eurjchem.3.3.337-339.609
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Council of Scientific and Industrial Research and University Grants Commission, New Delhi, India
Citations
[1]. Rathod Aravind Kumar, Jajula Kashanna, Paramesh Jangili, Biswanath Das
A simple stereoselective synthesis of (+)-[6]-gingerdiol
European Journal of Chemistry 4(3), 191, 2013
DOI: 10.5155/eurjchem.4.3.191-194.768
[2]. Shaoxiang Yang, Wei Gong, Baoguo Sun, Yongguo Liu, Hongyu Tian
Synthesis of a New Odourant, 2-Mercapto-4-Heptanol
Journal of Chemical Research 39(3), 184, 2015
DOI: 10.3184/174751915X14253193792383
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DOI Link: https://doi.org/10.5155/eurjchem.3.3.337-339.609
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European Journal of Chemistry 2012, 3(3), 337-339 | doi: https://doi.org/10.5155/eurjchem.3.3.337-339.609 | Get rights and content
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