European Journal of Chemistry

Synthesis, characterization and thermochemistry of piperazine complexes of bivalent metal bromides

Article Sidebar

PDF
Published: Sep 30, 2013
DOI: https://doi.org/10.5155/eurjchem.4.3.250-254.791
Keywords:
Adducts, Metal bromides, Transition metals, Coordinated bonds, Enthalpies of solution, Thermochemical parameters
Section
Research Article
Issue
Vol. 4 No. 3 (2013): September 2013
Dates
Received 2013-04-03
Accepted 2013-06-03
Published 2013-09-30


Main Article Content

Pedro Oliver Dunstan
Instituto de Quimica, Universidade Estadual de Campinas, C. P. 6154, 13084-971, Campinas, Sao Paulo, Brazil
Abdul Majeed Khan
Instituto de Quimica, Universidade Estadual de Campinas, C. P. 6154, 13084-971, Campinas, Sao Paulo, Brazil

Abstract

Complexes of bivalent metal bromides with piperazine were prepared in hot ethanol solution. They have the general formula: [MBr2(pipz)n], where M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II) or Zn(II); pipz = piperazine; n = 1 or 1.5. They were characterized by melting point measurements, elemental analysis, TG/DTG-DSC curves, IR and electronic spectroscopy. The enthalpies of solution of the complexes, salts and ligand were measured by thermo-chemical cycles and several thermochemical parameters were determined. The mean standard enthalpies of the metal-nitrogen coordinated bonds and the enthalpies of gaseous complex formation were also determined.

4_3_250_254

icon graph This Abstract was viewed 1237 times | icon graph Article PDF downloaded 769 times

How to Cite
(1)
Dunstan, P. O.; Khan, A. M. Synthesis, Characterization and Thermochemistry of Piperazine Complexes of Bivalent Metal Bromides. Eur. J. Chem. 2013, 4, 250-254.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Ciccarese, A.; Clemente, D. A.; Fanizzi, F. P.; Marzotto, A.; Valle, G. Acta Crystallogr. C 1998, 54, 1779-1781.
http://dx.doi.org/10.1107/S0108270198009755

[2]. Smekal, Z.; Travnycek, Z.; Mrozimski, J.; Marek, J. Inorg. Chem. Commun. 2003, 65, 1395-1399.
http://dx.doi.org/10.1016/j.inoche.2003.07.001

[3]. Bera, M.; Ribas, J.; Wong, W. T.; Ray, D. A. Inorg. Chem. Commun. 2004, 7, 1242-1245.
http://dx.doi.org/10.1016/j.inoche.2004.09.018

[4]. Johnstone, N. C.; Aazam, E. S. Hitchcock, P. B.; Fulton, J. R. J. Organomet. Chem. 2010, 695(2), 170-176.
http://dx.doi.org/10.1016/j.jorganchem.2009.10.016

[5]. Marzotto, A.; Clemente, D. A.; Valle, G. Acta Crystallogr. C 1988, 54, 27-29.
http://dx.doi.org/10.1107/S0108270197012353

[6]. Khalaj, A.; Adibpour, N.; Shahverdi, A. R.; Danaeshtalab, M. Eur. J. Med. Chem. 2004, 39, 699-705.
http://dx.doi.org/10.1016/j.ejmech.2004.04.004
PMid:15276303

[7]. Bali, A.; Sharma, K.; Bhalla, A.; Bala, S.; Reddy, D.; Singh, A.; Kumar, A. Eur. J. Med. Chem. 2010, 45, 2656-2662.
http://dx.doi.org/10.1016/j.ejmech.2010.02.008
PMid:20207451

[8]. Aytemir, M. D.; Calis, U.; Ozalp, M. Arch. Pharm. Res (Weinheim) 2004, 337, 281-288.
http://dx.doi.org/10.1002/ardp.200200754
PMid:15095421

[9]. Sapa, J.; Filipek, B.; Nowinski, L. Pharmacol Rep. 2011, 63, 455-463.
http://dx.doi.org/10.1016/j.phrs.2011.02.013

[10]. Patel,I. J.; Parmar, S. J. E-J. Chem. 2010, 7, 617-623.

[11]. Pietrzycka, A.; Stepniewski, M.; Waskielewicz, A. M.; Marona, H. Acta Pol. Pharm. Drug Res. 2006, 63, 19-24.

[12]. Rajabalian, S.; Foroumadi, A.; Shafiee, A.; Emami, S. J. Pharm. Pharm. Sci. 2007, 10, 153-158.

[13]. Niederl, J. B.; Sozzi, J. A. Microanalisis elemental organico. 1st edition, Buenos Aires, Methopress, 1958.

[14]. Koltoff, I. M.; Sandall, E. B. Tratado de Quimica Analitica Cuantitativa, 3a edicion, Libreria y Editorial Nigar S. R. L., Buenos Aires, 1956.

[15]. Flaschka, H. A. EDTA titrations: An Introduction to Theory and Practice, 2nd edition, Pergamon Press, London, 1964.

[16]. Dunstan, P. O. J. Chem. Eng. Data 1999, 44, 243-247.
http://dx.doi.org/10.1021/je980113m

[17]. Herington, E. F. Pure Appl. Chem. 1974, 40, 391-450.
http://dx.doi.org/10.1351/pac197440030391

[18]. Ahuya, I. S. Inorg. Chim. Acta 1969, 3, 110-112.
http://dx.doi.org/10.1016/S0020-1693(00)92459-9

[19]. Ahuja, I. S.; Garg, A. Inorg. Nucl. Chem Lett. 1973, 7, 937-940.
http://dx.doi.org/10.1016/0020-1650(71)80005-3

[20]. Pellacani, G. C.; Battistuzzi, R.; Marcotrigiano, G. J. Inorg. Nucl. Chem. 1973, 35, 2243-2247.
http://dx.doi.org/10.1016/0022-1902(73)80287-8

[21]. Soriego, R.; Costamagna, J. A. J. Inorg. Nucl. Chem. 1971, 33, 1528-1532.
http://dx.doi.org/10.1016/0022-1902(71)80454-2

[22]. Reedijk, J.; Van Leeuwem, P. W. N. M.; Groenveld, W. L. Recl. Trav. Chim. Pay-B. 1968, 87, 129-141.
http://dx.doi.org/10.1002/recl.19680870203

[23]. Lever, A. B. P. J. Chem. Educ. 1968, 45, 711-712.
http://dx.doi.org/10.1021/ed045p711

[24]. Bolster, M. W. G. The coordination chemistry of aminophosphinoxide and related compounds, Thesis, Leiden, 1972 pp. 88, 89, 95, 98, 100.

[25]. Dunstan, P. O. J. Chem. Eng. Data. 2009, 54, 842-846.
http://dx.doi.org/10.1021/je8006315

[26]. Dunstan, P. O. Thermochim. Acta 2004, 409, 19-24.
http://dx.doi.org/10.1016/S0040-6031(03)00333-2

[27]. Dunstan, P. O. Thermochim. Acta 1997, 303, 209-218.
http://dx.doi.org/10.1016/S0040-6031(97)00280-3

[28]. Wagmam, D. D.; Evans, W. H.; Parker, V. B.; Schumm, R. H. Halow, I.; Churney, S.; Nuttall, R. L. J. Phys. Chem. Ref. Data 1982, 2, 50-191.

[29]. Skinner, H. A.; Pilcher, G. Q. Rev. Chem. Soc. 1963, 17, 264-288.
http://dx.doi.org/10.1039/qr9631700264

Supporting Agencies

TWAS (The Academy of Sciences for the Developing World) and CNPq (Conselho Nacional de Pesquisa)
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).