Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Synthesis, characterization, biological activity and equilibrium studies of cadmium(II) with 2,6-diaminopyridine and various bio-relevant ligands
Azza Abdelwahab Shoukry (1,*)
, Saedah Rwede Al-Mhayawi (2) (1) Department of Chemistry, Faculty of Science, Cairo University, 12613 Giza, Egypt
(2) Department of Chemistry, Faculty of Science for Girls, King Abdulaziz University, 50918 Jeddah, 21533 Kingdom of Saudi Arabia
(*) Corresponding Author
Received: 18 Apr 2013 | Revised: 23 May 2013 | Accepted: 29 May 2013 | Published: 30 Sep 2013 | Issue Date: September 2013
Abstract
The complexing properties of 2,6-diaminopyridine (DAP) with cadmium(II) were investigated via measuring pH (i.e., pH-metrically). Binary and ternary complexes of Cd(II) involving DAP and various biologically relevant ligands are investigated. The ligands used (L) were amino acids, dicarboxylic acids, amides and DNA unit constituents. The ternary complexes are formed by simultaneous reactions. The results showed the formation of Cd(DAP)(L) complexes with amino acids and dicarboxylic acids. Amides form both Cd(DAP)(L) complex and the corresponding deprotonated amide species Cd(DAP)(LH-1). The concentration distributions of the various complex species formed in solution were also evaluated as a function of pH. The effect of dioxane as a solvent on the protonation constant of DAP and the formation constants of Cd(II)-DAP complexes were discussed. The solid complexes [Cd(DAP)L)] where L = methionine and glycine, were isolated and characterized. The isolated solid complexes have also been screened for their antimicrobial activities against some selected bacteria and fungi. The activity data show that the complexes are found to have antibacterial and antifungal activity.
Announcements
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).
2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).
3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.4.3.260-267.800
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 1253 times |
PDF Article downloaded 654 times
Funding information
Microanalytical Center and the Bacteriology Laboratory of the Faculty of Science, Cairo University, Egypt
Citations
[1]. Azza Abdelwahab Shoukry
Complex formation equilibria of imipenem with some transition metal ions. Ternary complex formation reactions involving Cu(II) with imipenem and various bio-relevant ligands
European Journal of Chemistry 4(4), 379, 2013
DOI: 10.5155/eurjchem.4.4.379-387.868
[2]. Faten M. Ali Zainy, Aisha M. Turkustani, Azza A. Shoukry
Synthesis, Characterization, Physicochemical Studies and Antimicrobial Evaluation of Mixed Ligand Complexes Involving Co(II) with 2,2′-Dipyridylamine and Dicarboxylic Acids
Journal of Transition Metal Complexes 3, 1, 2020
DOI: 10.32371/jtmc/246098
[3]. Azza A. Shoukry, Saedah R. Al-Mhayawi
Solution Equilibria of Binary and Ternary Complexes Involving Zinc(II) with 2,6-Diaminopyridine and Various Biologically Relevant Ligands
Journal of Solution Chemistry 44(10), 2073, 2015
DOI: 10.1007/s10953-015-0395-0
[4]. Jihong Li, Yajun Zhou, Zongping Li, Zhiyuan Ma, Qingshu Ma, Lu Wang
Mechanism for improving the gel properties of transglutaminase-mediated porcine myofibrillar protein by ultrasonic pretreatment combined with carrageenan
Food Chemistry 426, 136635, 2023
DOI: 10.1016/j.foodchem.2023.136635
References
[1]. Shoukry, A. A.; Shoukry, M. M. Annali di Chimica 2007, 97, 733-744.
http://dx.doi.org/10.1002/adic.200790057
PMid:17899886
[2]. Briggs, B. R. L. Bulln. Eniviron. Contam. Toxicol. 1979, 22, 838-845.
http://dx.doi.org/10.1007/BF02027034
PMid:486788
[3]. Sugwara, C.; Sugwara, N.; Bulln. Eniviron. Contam. Toxicol. 1975, 14, 159-162.
http://dx.doi.org/10.1007/BF01701307
[4]. Dressing, S. A.; Maas, R. P. Bulln. Eniviron. Contam. Toxicol. 1982, 28, 172-180.
http://dx.doi.org/10.1007/BF01608571
PMid:7066557
[5]. Titus, J. A.; Pfister, R. M. Bulln. Eniviron. Contam. Toxicol. 1982, 28, 697-703.
http://dx.doi.org/10.1007/BF01605638
PMid:7104504
[6]. Hung, Y. -W. Bulln. Eniviron. Contam. Toxicol. 1982, 28, 546-551.
http://dx.doi.org/10.1007/BF01605582
PMid:6212092
[7]. Margoshes, M.; Vallee, B. L. J. Am. Chem. Soc. 1957, 79, 4813-4814.
http://dx.doi.org/10.1021/ja01574a064
[8]. Kagi, J. H. R.; Valle, B. L. J. Biol. Chem. 1961, 236, 2433-2441.
[9]. Byerrum, R. U.; Anwar, R. A.; Hoppert, C. A. J. Am. Water Work Assoc. 1960, 52, 651-657.
[10]. Rabenestein, D. L.; Isab, A. A.; Kadima, W.; Mohanakrishnan, P. Biochim. Biophys. Acta. 1983, 762, 531-541.
http://dx.doi.org/10.1016/0167-4889(83)90057-5
[11]. Shoukry, M. M.; Shehata, M. R.; Mohamed, M. M. Microchim. Acta, 1998, 129, 107-113.
http://dx.doi.org/10.1007/BF01246857
[12]. Shoukry, A. A. J. Solut. Chem. 2011, 40, 1796-1818.
http://dx.doi.org/10.1007/s10953-011-9753-8
[13]. Shoukry, A. A.; Hosney W. M. Cent. Eur. J. Chem. 2012, 10(1), 59-70.
http://dx.doi.org/10.2478/s11532-011-0116-5
[14]. Shoukry, A. A.; Shoukry, M. M. Hafez, M. N. Cent. Eur. J. Chem. 2010, 8(4), 797-805.
http://dx.doi.org/10.2478/s11532-010-0047-6
[15]. Shoukry, M. M.; Shoukry, A. A.; Hafez, M. N. J. Coord. Chem. 2010, 63, 652-664.
http://dx.doi.org/10.1080/00958971003639766
[16]. Shoukry, M. M.; Shoukry, A. A.; Khalaf, P. A. A.; Hassan, S. S. Int. J. Chem. Kinet. 2010, 42(10), 608-618.
http://dx.doi.org/10.1002/kin.20511
[17]. Shoukry, A. A.; Brindell, A. A.; Eldik, V. R. Dalton. Trans. 2007, 4169-4174.
http://dx.doi.org/10.1039/b706856e
[18]. Shoukry, A. A.; Mohamed, M. M.; Shoukry, M. M. J. Solut. Chem. 2006, 35, 853- 856.
http://dx.doi.org/10.1007/s10953-006-9032-2
[19]. Shoukry, A. A. Trans. Met. Chem. 2005, 30, 814-827.
http://dx.doi.org/10.1007/s11243-005-5718-3
[20]. Grayer, R. J.; Harbone, J. B. Phytochemistry 1994, 37, 19-42
http://dx.doi.org/10.1016/0031-9422(94)85005-4
[21]. El-Sherif, A. J. Solut. Chem. 2010, 39, 1562-1581.
http://dx.doi.org/10.1007/s10953-010-9593-y
[22]. Stark, J. G.; Wallac, E. H. G.; Chemistry Data Book, (eds.), 75. Murray, London, 1975.
[23]. Van Uitert, G. L; Hass, C. G. J. Am. Chem. Soc. 1971, 75, 451-455.
http://dx.doi.org/10.1021/ja01098a057
[24]. Motekaitis, R. J.; Martell, A. E.; Nelson D. A. Inorg. Chem. 1984, 23, 275-283.
http://dx.doi.org/10.1021/ic00171a005
[25]. Serjeant, E. P. Potentiometry and Potentiometric Titrations., Wiley, New York, 1984.
[26]. Jameson. R. F.; Wilson. M. F, J. Chem. Soc. Dalton Trans. 1972, 23, 2610-2614.
http://dx.doi.org/10.1039/dt9720002610
[27]. Hay, R. W.; Morris, P. J.; Sige, l. H. Metal Ions in Biological Systems. pp. 73. Dekker, New York, 1976.
[28]. Gans, P.; Sabatini, A.; Vacca, A. J. Inorg. Chim. Acta 1976, 18, 237-239.
http://dx.doi.org/10.1016/S0020-1693(00)95610-X
[29]. Pettit, L. D. SPECIES, available program supplied to the authors, Academic Software, Old Farm, Timbly, Otley, 1993 York, LS21 2PW, UK
[30]. El-Sherif, A. J. Coord. Chem. 2011, 64(7), 1240-1253.
http://dx.doi.org/10.1080/00958972.2011.565755
[31]. Pettit, L.; Swash, J. J. Chem. Soc. Dalton Trans. 1976, 2416-2419.
[32]. Kozlowki, H.; Becock, B. R.; Delarulle, J. L.; Loucleux, C. Ancian B. Inorg. Chim. Acta 1983, 78, 31-35.
http://dx.doi.org/10.1016/S0020-1693(00)86484-1
[33]. Savago, I.; Kiss, A.; Farkas, A.; Sanna, D.; Marras P.; Micerain, G. J. Inorg. Biochem. 1997, 65, 103-108.
http://dx.doi.org/10.1016/S0162-0134(96)00094-3
[34]. Daniele, P. G.; Zerbinati, O.; Zelano, V.; Ostacoli, G. Dalton Trans. 1991, 2711-2715.
[35]. Lim, M. C. J. Inorg. Nucl. Chem. 1981, 43, 221-223.
http://dx.doi.org/10.1016/0022-1902(81)80478-2
[36]. Maskos, K. Acta Biochem. Pol. 1981, 28, 317-335.
PMid:7342594
[37]. Maskos, K. J. Inorg. Biochem. 1985, 25, 1-14.
http://dx.doi.org/10.1016/0162-0134(85)83002-6
[38]. Snell, F. D.; Hilton, C. L. Encyclopaedia of Industrial Chemical Analysis, 4, 74 Interscience, New York, 1967.
[39]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and coordination compounds, 3rd edn., 311 Wiley, New York, 1978.
[40]. Anacona, J. R.; Lopez, M. Int J. Inorg. Chem. 2012, 106187-106195.
[41]. Jawetz, E.; Melnick, J. I.; Adelberg, E. A. Review of Medical Microbiology, 16th edn., LangMedical, Los Angeles, 1979.
PMCid:PMC414180
[42]. El-Sherif, A. J. Solut. Chem. 2012, 41, 392-409.
http://dx.doi.org/10.1007/s10953-012-9806-7
[43]. El-Sherif, A. J. Solut. Chem. 2010, 39, 131-150.
http://dx.doi.org/10.1007/s10953-009-9486-0
[44]. El-Sherif, A. J. Cood. Chem. 2011, 4, 1240-1253.
http://dx.doi.org/10.1080/00958972.2011.565755
[45]. Akerlof, G.; Short, O. A. J. Am. Chem. Soc. 1953, 75, 6357-6357.
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.4.3.260-267.800
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2013, 4(3), 260-267 | doi: https://doi.org/10.5155/eurjchem.4.3.260-267.800 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.