Mixed bivalent transition metal complexes of 1,10-phenanthroline and  2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities

Mutlaq Shedeed Aljahdali; Ahmed Abdou El-Sherif; Rifaat Hasan Hilal; Abeer Taha Abdel-Karim

doi:10.5155/eurjchem.4.4.370-378.803

European Journal of Chemistry 2013, 4(4), 370-378 | doi: https://doi.org/10.5155/eurjchem.4.4.370-378.803 | Get rights and content

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Mixed bivalent transition metal complexes of 1,10-phenanthroline and 2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities

Mutlaq Shedeed Aljahdali ⁽¹⁾

, Ahmed Abdou El-Sherif ^(2,*)

, Rifaat Hasan Hilal ⁽³⁾

, Abeer Taha Abdel-Karim ⁽⁴⁾

⁽¹⁾ Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Kingdom of Saudi Arabia
⁽²⁾ Department of Chemistry, Faculty of Science, Cairo University, Giza, 12613, Egypt
⁽³⁾ Department of Chemistry, Faculty of Science, Cairo University, Giza, 12613, Egypt
⁽⁴⁾ Department of Chemistry, Faculty of Science, Cairo University, Giza, 12613, Egypt
^(*) Corresponding Author

Received: 21 Apr 2013 | Revised: 31 Jul 2013 | Accepted: 26 Jun 2013 | Published: 31 Dec 2013 | Issue Date: December 2013

Abstract

Mixed ligand complexes of M(II) {M = Cu(II), Ni(II), Co(II) and Zn(II)} with 1,10-phenanthroline (1,10-Phen) and Schiff base namely 2-aminomethylthiophenyl-4-bromosalicylaldehyde (ATS) have been synthesized. These metal chelates have been characterized by elemental analyses, IR, ¹H NMR, solid reflectance, magnetic moment and molar conductance. Spectral data showed that the 1,10-phenanthroline act as neutral bidentate ligand coordinating to the metal ion through two nitrogen donor atoms and Schiff base (ATS) acts as monobasic bidentate coordinating through through azomethine-N and phenolic-oxygen groups. The geometry of the studied M(II) complexes has been fully optimized. The metal chelates have been screened for their antimicrobial activities using the disc diffusion method against different selected types of bacteria and fungi. In vitro antitumor activity assayed against two human cell lines colon (HCT116) and larynx (HEP2) cancer cells. Solution equilibrium studies were also investigated.

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European Journal of Chemistry

Keywords

Schiff base; Bivalent metals; Biological activity; Antitumor activity; Electronic spectra; Mixed-ligand complexes

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DOI: 10.5155/eurjchem.4.4.370-378.803

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Citations

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DOI: 10.1016/j.ica.2018.04.038

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DOI: 10.1021/acsomega.2c08266

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DOI: 10.1007/s10953-016-0464-z

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DOI: 10.1515/ncrs-2018-0288

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DOI: 10.18596/jotcsa.589848

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DOI: 10.1039/C7MD00526A

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References

[1]. Sigman, D. S.; Mazumder, A.; Perrin, D. M.; Wang, M. Z.; Meng, Z. X.; Liu, B. L.; Cai, G. L.; Zhang, C. L.; Wang, X. Y. Inorg. Chem. Commun, 2005, 8(4), 368-371.
http://dx.doi.org/10.1016/j.inoche.2005.01.023

[2]. Sharma, V.; Piwnica-Worms, D. Chem. Rev. 1999, 99(9), 2545-2560.
http://dx.doi.org/10.1021/cr980429x
PMid:11749491

[3]. Sattari, D.; Alipour, E.; Shirani, S.; Amighian, J. J. Inorg. Biochem. 1992, 45(2), 115-122.
http://dx.doi.org/10.1016/0162-0134(92)80005-G

[4]. Hitoshi, T.; Tamao, N.; Hideyuki, A.; Manabu, F.; Takayuki, M. Polyhedron 1997, 16, 3787-3794.
http://dx.doi.org/10.1016/S0277-5387(97)00148-4

[5]. Casella, L.; Gullotti, M. Inorg. Chem. 1986, 25(9), 1293-1303.
http://dx.doi.org/10.1021/ic00229a001

[6]. Casella, L.; Gullotti, M. Inorg. Chem. 1983, 22(16), 2259-2266.
http://dx.doi.org/10.1021/ic00158a008

[7]. El-Sherif, A. A.; Shehata, M. R.; Shoukry, M. M.; Barakat, M. H. J. Spectrochim. Acta A 2012, 96, 889-897.
http://dx.doi.org/10.1016/j.saa.2012.07.047
PMid:22935596

[8]. El-Sherif, A. A.; Shoukry, M. M.; Abd-Elgawad, M. M. A. Spectrochim. Acta A 2012, 98, 307-321.
http://dx.doi.org/10.1016/j.saa.2012.08.034
PMid:23021889

[9]. Aminabhavi, T. M.; Biradar, N. S.; Patil, S. B.; Roddabasanagoudar, V. L.; Rudzinski, W. E. Inorg. Chim. Acta 1985, 107(4), 231-234.
http://dx.doi.org/10.1016/S0020-1693(00)82293-8

[10]. Wolfe, A.; Shimer Jr, G. H.; Meehan, T.; Biochem. 1987, 26(20), 6392-6396.
http://dx.doi.org/10.1021/bi00394a013

[11]. Zhang, C.; Janiak, C. J. Chem. Crystllog. 2001, 31(1), 29-35.
http://dx.doi.org/10.1023/A:1013774502147

[12]. Campbell, M. J. M. Coord. Chem. Rev. 1975, 15, 279-312.
http://dx.doi.org/10.1016/S0010-8545(00)80276-3

[13]. Williams, D. R. Chem. Rev. 1972, 72, 203-213.
http://dx.doi.org/10.1021/cr60277a001
PMid:4555559

[14]. Furst, A.; Haro, R. T. Prog. Exp. Tumor Res. 1969, 12, 102-133.
PMid:4905208

[15]. Dwyer, F. B.; Mayhew, E.; Roe, E. M. F.; Shulman, A. Brit. J. Cancer 1965, 19, 195-199.
http://dx.doi.org/10.1038/bjc.1965.24
PMid:14284381 PMCid:PMC2071418

[16]. Sylvain, R.; Bernier, J. L.; Waring, M. J. J. Org. Chem. 1996, 61, 2326-2331.
http://dx.doi.org/10.1021/jo951840c

[17]. Gravert, D. J.; Griffin, J. H.; J. Org. Chem. 1993, 58, 820-822.
http://dx.doi.org/10.1021/jo00056a009

[18]. Balasubramanian, K. P.; Parameswari, K.; Chinnusamy, V.; Prabhakaran, R.; Natarajan, K. Spectrochim. Acta A 2006, 65, 678-683.
http://dx.doi.org/10.1016/j.saa.2005.12.029
PMid:16546440

[19]. Meyer, R.; Brink, S.; Van Rensburg, C. E. J.; Joone, G. K.; Gorls, H.; Lotz, S. J. Org. Met. Chem. 2005, 690, 117-125.
http://dx.doi.org/10.1016/j.jorganchem.2004.08.046

[20]. El-Sherif, A. A.; Eldebss, T. M. A. Spectrochim. Acta A 2011, 79, 1803-1814.
http://dx.doi.org/10.1016/j.saa.2011.05.062
PMid:21705267

[21]. Konstantinivi, S. S.; Radovanovi, B. C.; Caki, Z.; Vasic, V. J. Ser. Chem. Soc. 2003, 68, 641-648.
http://dx.doi.org/10.2298/JSC0309641K

[22]. Sammes, P. G.; Yahioglu, G. Chem. Soc. Rev. 1994, 23, 327-334.
http://dx.doi.org/10.1039/cs9942300327

[23]. Farrell, N. Transition Metal Complexes as Drugs and Chemotherapeutic Agents, Kluwer Academic, Dordrecht, 1989.
http://dx.doi.org/10.1007/978-94-011-7568-5

[24]. El-Sherif, A. A. J. Solution Chem. 2006, 35, 1287-1301.
http://dx.doi.org/10.1007/s10953-006-9062-9

[25]. Mohamed, M. M. A.; El-Sherif, A. A. J. Solution Chem. 2010, 39, 639-653.
http://dx.doi.org/10.1007/s10953-010-9535-8

[26]. El-Sherif, A. A.; Shoukry, M. M. J. Coord. Chem. 2005, 58(16), 1401-1415.
http://dx.doi.org/10.1080/00958970500055435

[27]. El-Sherif, A. A.; Shoukry, M. M. J. Spectrochim. Acta A 2007, 66, 691-700.
http://dx.doi.org/10.1016/j.saa.2006.04.013
PMid:16956788

[28]. El-Sherif, A. A.; Shoukry, M. M. Inorg. Chim. Acta 2007, 360, 473-487.
http://dx.doi.org/10.1016/j.ica.2006.07.108

[29]. El-Sherif, A. A. J. Solution Chem. 2010, 39, 1562-1581.
http://dx.doi.org/10.1007/s10953-010-9593-y

[30]. El-Sherif, A. A. Inorg. Chim. Acta 2009, 362, 4991-5000.
http://dx.doi.org/10.1016/j.ica.2009.08.004

[31]. Frish, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Gaussian, Inc., Pittsburgh, PA, 2008.

[32]. Zhang, Q.; Li, Z.; Chen, B. J. Mol. Struct. (Theochem.) 2009, 901, 202-210.
http://dx.doi.org/10.1016/j.theochem.2009.01.030

[33]. Zhang, Q.; Chen, B. J. Mol. Struct. (Theochem.) 2010, 941, 41-46.
http://dx.doi.org/10.1016/j.theochem.2009.10.036

[34]. Smith, D. M.; Nicolaides, A.; Golding, B. T.; Radom, L. J. Am. Chem. Soc. 1998, 120, 10223-10233.
http://dx.doi.org/10.1021/ja980635m

[35]. Dunning, T. H.; Hay, P. J. Modern Theoretical Chemistry, Ed. H. F. Schaefer III, 1976, Vol. 3 (Plenum, New York) 1-28.

[36]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270-283.

[37]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299-310.

[38]. Ulic, S. E.; Vedova, C. O. D.; Hermann, A.; Mack, H. G.; Oberhammer, H. J. Phys. Chem. A 2008, 112, 6211-6216.
http://dx.doi.org/10.1021/jp800344m
PMid:18547036

[39]. Bauer, A. W.; Kirby, W. M.; Sherris, C.; Turck, M. J. Am. Clin. Pathol. 1966, 45, 493-496.

[40]. Pfaller, M. A.; Burmeister, L.; Bartlett, M. A.; Rinaldi, M. G. J. Clin. Microbiol. 1988, 26 1437-1441.

[41]. National Committee for Clinical Laboratory Standards (1993), Methods for dilution antimicrobial susceptibility tests for bacteria that grow aerobically. Approved standard M7-A3, Villanova, Pa.

[42]. L. D. Liebowitz, H. R. Ashbee, E. G. V. Evans, Y. Chong, N. Mallatova, M. Zaidi, D. Gibbs, Microbiol. Infet. Dis. 2001, 24, 27-33.
http://dx.doi.org/10.1016/S0732-8893(01)00243-7

[43]. National Committee for Clinical Laboratory Standards, Methods for dilution antimicrobial susceptibility tests for bacteria that grow aerobically. Approved standard M7-A3, Villanova, Pa (1993).

[44]. Matar, M. J., Ostrosky-Zeichner, L., Paetznick, V. L., Rodriguez, J. R., Chen, E., Rex, J. H. Antimicrob. Agents Chemother. 2003, 47, 1647-1651.
http://dx.doi.org/10.1128/AAC.47.5.1647-1651.2003
PMid:12709335 PMCid:PMC153338

[45]. Skehan, P.; Storeng, R.; Scudiero, D.; Monks, A.; McMahon, J.; Vistica, D.; Warren, J. T.; Bokesch, H.; Kenney, S.; Boyd, M. R. J. Nat. Cancer Inst. 1990, 82, 1107-1112.
http://dx.doi.org/10.1093/jnci/82.13.1107

[46]. Gündüz, T.; Kılıc, E.; Koseoglu, F.; Canel, E. Anal. Chim. Acta 1993, 282, 489-495.
http://dx.doi.org/10.1016/0003-2670(93)80112-X

[47]. Van Uitert, G. L.; Hass, C. G. J. Am. Chem. Soc. 1971, 75, 451-455.
http://dx.doi.org/10.1021/ja01098a057

[48]. Serjant, E. P.; Potentiometry and Potentiometric Titrations, Wiley, New York, 1984.

[49]. Gans, P.; Sabatini, A.; Vacca, A. Inorg. Chim. Acta 1976, 18, 237-239.
http://dx.doi.org/10.1016/S0020-1693(00)95610-X

[50]. Zaki, Z. M.; Haggag, S. S.; Soayed, A. A. Spectroscopy Lett. 1983, 31(4), 757-766.
http://dx.doi.org/10.1080/00387019808007397

[51]. Bellamy, L. J.; The Infrared Spectra of Complex Molecules, second ed., J. Wiley, New York, 1964.

[52]. Sarkar, S.; Dey, K. Spectrochim. Acta A 2005, 62, 383-393.
http://dx.doi.org/10.1016/j.saa.2005.01.005
PMid:16257739

[53]. West, X.; Nassar, A. A. Trans. Metal Chem. 1998, 23, 321-326.
http://dx.doi.org/10.1023/A:1006957325074

[54]. Bagihalli, G. B.; Avaji, P. G.; Patil, S. A.; Badami, P. S. Eur. J. Med. Chem. 2008, 43, 2639-2649.
http://dx.doi.org/10.1016/j.ejmech.2008.02.013
PMid:18395942

[55]. Gronowitz, S.; Katritsky, A. R.; Reavill, R. E. J. Am. Chem. Soc. 1964, 86, 3881-3882.
http://dx.doi.org/10.1021/ja01072a062

[56]. Prashanthi, Y.; Kiranmai, K.; Subhashini, N. J. P. Spectrochim. Acta A 2008, 70, 30-35.
http://dx.doi.org/10.1016/j.saa.2007.07.028
PMid:17913572

[57]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed., Part II: Applications in Coordination, Organometallic and Bioinorganic Chemistry, Wiley, New York, 1997.

[58]. Percy, C. G.; Thornton, D. A. J. Inorg. Nucl. Chem. 1973, 35, 2719-2725.
http://dx.doi.org/10.1016/0022-1902(73)80502-0

[59]. Hulett, L. G.; Thornton, D. A. Spectrochim. Acta A 1971, 27, 2089-2096.
http://dx.doi.org/10.1016/0584-8539(71)80106-X

[60]. Earnshaw, A. The Introduction to Magnetochemistry, Academic Press, London, 1980, p. 80.

[61]. Abrahim, J.; Narayana, B.; Mahadevi, S.; Ramachandra, B. Turk. J. Chem. 1994, 18, 14-19.

[62]. Lever, A. B. P. Crystal Field Spectra. Inorganic Electronic Spectroscopy first ed., Elsevier, Amsterdam, 1968.

[63]. Sanmartin, J.; Bermejo, M. R.; Deibe, A. M. G.; Maneiro, M.; Lage, C.; Filho, A. J. C. Polyhedron 2000, 19, 185-192.
http://dx.doi.org/10.1016/S0277-5387(99)00341-1

[64]. Krzyminiewska, V. P.; Litkowska, H.; Paryzek, W. R. Monatsh Chem. 1999, 130, 243-249.

[65]. Melnik, M.; Gyoryova, K.; Skorsepa, J.; Holloway, C. E. J. Coord. Chem. 1995, 35, 179-185.
http://dx.doi.org/10.1080/00958979508024038

[66]. Hathaway, B. J.; Tomlinson, A. A. G. Coord. Chem. Rev. 1970, 5, 1-44.
http://dx.doi.org/10.1016/S0010-8545(00)80073-9

[67]. Kivelson, D.; Neiman, R. R. J. Chem. Phys. 1961, 35, 149-151.

[68]. Singh, V. Spectrochim. Acta A 2008, 71, 17-23.
http://dx.doi.org/10.1016/j.saa.2007.11.004
PMid:18155639

[69]. El-Sherif, A. A.; Jeragh, B. J. A. Spectrochim. Acta A 2007, 68, 877-882.
http://dx.doi.org/10.1016/j.saa.2006.12.073
PMid:17320475

[70]. Rao, S. Asian J. Chem. 2005, 17, 2663-2668.

[71]. Nseimi, H.; Safari, J.; Heidarnezhad, A. Dyes Pigments 2007, 73, 251-260.
http://dx.doi.org/10.1016/j.dyepig.2005.12.009

[72]. Martin, D.; Hauthal, H. G.; Dimethyl Sulphoxide, Van Nostrand Reinhold, Workingham, UK, 1975.

[73]. Hermandez-Molina, R.; Mederos, A.; Gili, P.; Dominquez, S.; Numez, P.; Grmain, G.; Debaerdemaeker, T. Inorg. Chim. Acta 1997, 256, 319-325.
http://dx.doi.org/10.1016/S0020-1693(96)05440-0

[74]. Irving, H.; Williams, R. J. P. Nature, 1948, 162, 746-747.
http://dx.doi.org/10.1038/162746a0

[75]. Irving, H.; Williams, R. J. P. J. Chem. Soc. 1953, 8, 3192-3210.

[76]. Cotton, F. A.; Wilkinson. G. Adv. Inorg. Chem. Wiley, London (1962).

[77]. Cakir, S.; Bicer, E.; Odabasoglu, M.; Albayrak, C. J. Braz. Chem. Soc. 2005, 4, 711-717.
http://dx.doi.org/10.1590/S0103-50532005000500005

[78]. Sari, N.; Arslan, S.; Logoglu, E.; Sakiyan, I. J. Sci. 2003, 16, 283-288.

[79]. Jayabalakrishnan, C.; Natarajan, K. Trans. Metal Chem. 2002, 27(1), 75-79.
http://dx.doi.org/10.1023/A:1013437203247

[80]. Carcelli, M.; Mazza, P.; Pelizzi, C.; Pelizzi, G.; Zani, F. J. Inorg. Biochem. 1995, 57, 43-62.
http://dx.doi.org/10.1016/0162-0134(94)00004-T

[81]. Koch, A. L. J. Clin. Microbiol. Rev. 2003, 16, 673-681.
http://dx.doi.org/10.1128/CMR.16.4.673-687.2003
PMid:14557293 PMCid:PMC207114

How to cite

Aljahdali, M.; El-Sherif, A.; Hilal, R.; Abdel-Karim, A. Eur. J. Chem. 2013, 4(4), 370-378. doi:10.5155/eurjchem.4.4.370-378.803

Aljahdali, M.; El-Sherif, A.; Hilal, R.; Abdel-Karim, A. Mixed bivalent transition metal complexes of 1,10-phenanthroline and 2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities. Eur. J. Chem. 2013, 4(4), 370-378. doi:10.5155/eurjchem.4.4.370-378.803

Aljahdali, M., El-Sherif, A., Hilal, R., & Abdel-Karim, A. (2013). Mixed bivalent transition metal complexes of 1,10-phenanthroline and 2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities. European Journal of Chemistry, 4(4), 370-378. doi:10.5155/eurjchem.4.4.370-378.803

Aljahdali, Mutlaq, Ahmed Abdou El-Sherif, Rifaat Hasan Hilal, & Abeer Taha Abdel-Karim. "Mixed bivalent transition metal complexes of 1,10-phenanthroline and 2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities." European Journal of Chemistry [Online], 4.4 (2013): 370-378. Web. 30 Sep. 2023

Aljahdali, Mutlaq, El-Sherif, Ahmed, Hilal, Rifaat, AND Abdel-Karim, Abeer. "Mixed bivalent transition metal complexes of 1,10-phenanthroline and 2-aminomethylthiophenyl-4-bromosalicylaldehyde Schiff base: Spectroscopic, molecular modeling and biological activities" European Journal of Chemistry [Online], Volume 4 Number 4 (31 December 2013)

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DOI Link: https://doi.org/10.5155/eurjchem.4.4.370-378.803

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