European Journal of Chemistry 2014, 5(1), 18-23 | doi: https://doi.org/10.5155/eurjchem.5.1.18-23.876 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate


Mohammed Rizk (1,*) , Safaa Shafik Toubar (2) , Hossam Ezz El-Din Sayour (3) , Dalia Mohamed (4) , Rehab Moussa Touny (5)

(1) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(2) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(3) Analytical Chemistry Department, Animal Health Research Institute, Dokki, 12311, Giza, Egypt
(4) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(5) Quality Control Department, Chemical Industries Development Company, El-Haram, 12111, Giza, Egypt
(*) Corresponding Author

Received: 13 Jul 2013 | Revised: 11 Aug 2013 | Accepted: 11 Aug 2013 | Published: 31 Mar 2014 | Issue Date: March 2014

Abstract


A new potentiometric sensor based on molecularly imprinted polymer (MIP) was fabricated for the recognition and determination of imidocarb dipropionate. The MIP was synthesized using imidocarb as the template material, methacrylic acid as a functional monomer, and ethylene glycol dimethacrylate as a cross linking agent. The sensor showed a high selectivity and a sensitive response to the template molecule in aqueous solution. The MIP-electrode exhibited a near-Nernstian response in a wide concentration range 10-5 - 10-2 M with a lower detection limit of 2×10-6 M. The potentiometric conditions were carefully studied and all measuring parameters were optimized including pH, buffer type, plasticizer type, response time and stability. The applicability of the sensor was tested through potentiometric determination of imidocarb dipropionate in pure drug as well as in pharmaceutical formulation. The proposed method was statistically compared with a reported one showing no significant difference regarding accuracy and precision, which assured a good reliable novel sensor for imidocarb estimation.


Announcements


Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.

1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).

2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).

3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).


Editor-in-Chief
European Journal of Chemistry

Keywords


Imidox injection; Binding experiments; Potentiometric sensor; Imidocarb dipropionate; PVC polymeric membrane; Molecular imprinted polymer

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.5.1.18-23.876

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 2299 times | icon graph PDF Article downloaded 874 times


Citations

/


[1]. Abbas J. Kadhem, Guillermina J. Gentile, Maria M. Fidalgo de Cortalezzi
Molecularly Imprinted Polymers (MIPs) in Sensors for Environmental and Biomedical Applications: A Review
Molecules  26(20), 6233, 2021
DOI: 10.3390/molecules26206233
/


[2]. Ayman H. Kamel, Somaia G. Mohammad, Nasser S. Awwad, Yomna Y. Mohammed
Survey on the Integration of Molecularly Imprinted Polymers as Artificial Receptors in Potentiometric Transducers for pharmaceutical Drugs
International Journal of Electrochemical Science  14(2), 2085, 2019
DOI: 10.20964/2019.02.23
/


[3]. Menna El-Beshlawy, Hassan Arida
New Miniaturized Disposable Screen-Printed Microchip Integrated with Molecularly Imprinted Polymer for Metronidazole Benzoate Drug Detection
Micromachines  13(12), 2107, 2022
DOI: 10.3390/mi13122107
/


[4]. Ghada AbdElHamid Sedik, Doha Mohamed Naguib, Fahima Morsy, Hala Elsayed Zaazaa
Validated Stability Indicating Chromatographic Methods for Quantification of Imidocarb Dipropionate; Application for the Determination of Its Residues in Bovine Meat and Milk Samples
Journal of AOAC INTERNATIONAL  103(4), 980, 2020
DOI: 10.1093/jaoacint/qsaa008
/


[5]. Dan Yang, Shiliang Mei, Zhuoqi Wen, Xian Wei, Zhongjie Cui, Bobo Yang, Chang Wei, Yi Qiu, Min Li, Hui Li, Wanlu Zhang, Fengxian Xie, Le Wang, Ruiqian Guo
Dual-emission of silicon nanoparticles encapsulated lanthanide-based metal-organic frameworks for ratiometric fluorescence detection of bacterial spores
Microchimica Acta  187(12), , 2020
DOI: 10.1007/s00604-020-04643-7
/


[6]. Nesrine Abdelrehim El Gohary, Adel Madbouly, Rasha Mohamed El Nashar, Boris Mizaikoff
Synthesis and application of a molecularly imprinted polymer for the voltammetric determination of famciclovir
Biosensors and Bioelectronics  65, 108, 2015
DOI: 10.1016/j.bios.2014.10.024
/


[7]. Nora H. Al-Shaalan, Jenny Jeehan Nasr, Shereen Shalan, Areej M. El-Mahdy
Use of green-modified micellar liquid chromatography for the determination of Imidocarb dipropionate residues in food samples
Microchemical Journal  178, 107316, 2022
DOI: 10.1016/j.microc.2022.107316
/


[8]. Yonghong Han, Juan Tao, Nisar Ali, Adnan Khan, Sumeet Malik, Hamayun Khan, Chunhao Yu, Yong Yang, Muhammad Bilal, Ahmed A. Mohamed
Molecularly imprinted polymers as the epitome of excellence in multiple fields
European Polymer Journal  179, 111582, 2022
DOI: 10.1016/j.eurpolymj.2022.111582
/


[9]. Guat Wei Lim, Jit Kang Lim, Abdul Latif Ahmad, Derek Juinn Chieh Chan
Molecularly imprinted polymer layers using Navicula sp. frustule as core material for selective recognition of lysozyme
Chemical Engineering Research and Design  101, 2, 2015
DOI: 10.1016/j.cherd.2015.06.005
/


[10]. Shimaa A. Atty, Hala E. Zaazaa, Fahima A. Morsy, Doha M. Naguib, Ghada A. Sedik
Nano Green Voltammetric Determination of Imidocarb Dipropionate and Its Residues in Bovine Meat, Milk and Urine Samples
Journal of The Electrochemical Society  167(4), 047510, 2020
DOI: 10.1149/1945-7111/ab7115
/


References


[1]. Chow, C. F.; Lam, M. H. W.; Leung, M. K. P. Anal. Chim. Acta 2002, 466, 17-30.
http://dx.doi.org/10.1016/S0003-2670(02)00520-2

[2]. Martin-Esteban, A. Anal. Bioanal. Chem. 2004, 378, 1875-1875.
http://dx.doi.org/10.1007/s00216-004-2502-8

[3]. Roche, P. J. R.; Ng, S. M.; Narayanaswamy, R.; Goddard, N.; Page, K. M. Sens. Actuators B Chem. 2009, 139, 22-29.
http://dx.doi.org/10.1016/j.snb.2008.07.029

[4]. He, C. Y.; Liu, F.; Li, K. A.; Liu, H. W. Anal. Lett. 2006, 39, 275-286.
http://dx.doi.org/10.1080/00032710500476946

[5]. Yang, H. H.; Zhang, S. Q.; Tan, F.; Zhuang, Z. X.; Wang, X. R. J. Am. Chem. Soc. 2005, 127, 1378-1379.
http://dx.doi.org/10.1021/ja0467622

[6]. Chai, C.; Liu, G.; Li, F.; Liu, X.; Yao, B.; Wang, L. Anal. Chim. Acta 2010, 675, 185-190.
http://dx.doi.org/10.1016/j.aca.2010.07.012

[7]. Kriz, D.; Mosbach, K. Anal. Chim. Acta 1995, 300, 71-75.
http://dx.doi.org/10.1016/0003-2670(94)00368-V

[8]. Chen,P.; Nien, P.; Wu, C.; Wu, T.; Lin, C.; Ho, K. Anal. Chim. Acta 2009, 643, 38-44.
http://dx.doi.org/10.1016/j.aca.2009.04.004

[9]. Chen, P.; Vittal, R.; Nien, P.; Liou, G.; Ho, K. Talanta 2010, 80, 1145-1151.
http://dx.doi.org/10.1016/j.talanta.2009.08.041

[10]. Sadeghi, S.; Motaharian, A.; Moghaddam, A. Z. Sens. Actuators B Chem. 2012, 168, 336-344.
http://dx.doi.org/10.1016/j.snb.2012.04.031

[11]. Tarley, C. R. T.; Kubota, L. T. Anal. Chim. Acta 2005, 548, 11-19.
http://dx.doi.org/10.1016/j.aca.2005.05.055

[12]. Say, R.; Gultekin, A.; Ozcan, A. A.; Denizli, A.; Ersoz, A. Anal. Chim. Acta 2009, 640, 82-86.
http://dx.doi.org/10.1016/j.aca.2009.03.022

[13]. Kobayashi, T.; Murawaki, Y.; Reddy, P. S.; Abe, M.; Fujii, N. Anal. Chim. Acta 2001, 435, 141-149.
http://dx.doi.org/10.1016/S0003-2670(00)01281-2

[14]. Hao, H. X.; Zhou, H.; Chang, J.; Zhu, J.; Wei, T. X. Chin. Chem. Lett. 2011, 22, 477-480.
http://dx.doi.org/10.1016/j.cclet.2010.11.004

[15]. Sadeghi, S.; Fathi, F.; Abbasifar, J. Sens. Actuators B Chem. 2007, 122, 58-164.

[16]. Tonelli, D.; Ballarin, B.; Guadagnini, L.; Mignani, A.; Scavetta, E. Electrochim. Acta. 2011, 56, 7149-7154.
http://dx.doi.org/10.1016/j.electacta.2011.05.076

[17]. Coldham, N. G.; Moore, A. S.; Dave, M.; Graham, P. J.; Sivapathasundardm, S.; Lake, B. G.; Sauer, M. J. Drug Metab. Disp. I995, 23, 501-505.

[18]. Edelhofer, R.; Muller, A.; Schuh, M.; Obritzhauser, W.; Kanout, A. Parasitol. Res. 2004, 92, 433-435.
http://dx.doi.org/10.1007/s00436-003-1060-x

[19]. Kuttler, K. L.; Johnson, L. W. Vet. Parasitol. 1986, 21, 107-118.
http://dx.doi.org/10.1016/0304-4017(86)90151-2

[20]. Tarbin, J. A.; Shearer, G. J. Chromatogr. B. Biomed. Sci. Appl. 1992, 577, 376-381.
http://dx.doi.org/10.1016/0378-4347(92)80263-P

[21]. Ishii, R.; Takahashi, K.; Matsumoto, R. Shokuhin Eiseigaku Zasshi 2010, 52, 34-39.
http://dx.doi.org/10.3358/shokueishi.52.34

[22]. Lehner, A. F.; Hitron, J. A.; May, J.; Hughes, C.; Eisenberg, R.; Schwint, N.; Knowles, D. P.; Timoney, P.; Tobin, T. J. Anal. Toxicol. 2011, 35, 199-204.
http://dx.doi.org/10.1093/anatox/35.4.199

[23]. Koichi, I.; Mari, N.; Tomoaki, H.; Hisao, O. J. Liq. Chromatogr. Relat. Technol. 2011, 34, 2149-2156.
http://dx.doi.org/10.1080/10826076.2011.585484

[24]. Duffy, D.J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. J. Am. Chem. Soc. 2002, 124, 8290-8296.
http://dx.doi.org/10.1021/ja0201146

[25]. Katz, A.; Davis, M. E. Macromolecules 1999, 32, 4113-4121.
http://dx.doi.org/10.1021/ma981445z

[26]. Umezawa, Y.; Umezawa, K.; Sato, H. Pure Appl. Chem. 1995, 67, 507-518.
http://dx.doi.org/10.1351/pac199567030507

[27]. Miller, J. C.; Miller, J. N. Statistics for Analytical Chemistry, fifth edition, Wiley, New York, 2005, p. 256.


How to cite


Rizk, M.; Toubar, S.; Sayour, H.; Mohamed, D.; Touny, R. Eur. J. Chem. 2014, 5(1), 18-23. doi:10.5155/eurjchem.5.1.18-23.876
Rizk, M.; Toubar, S.; Sayour, H.; Mohamed, D.; Touny, R. A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate. Eur. J. Chem. 2014, 5(1), 18-23. doi:10.5155/eurjchem.5.1.18-23.876
Rizk, M., Toubar, S., Sayour, H., Mohamed, D., & Touny, R. (2014). A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate. European Journal of Chemistry, 5(1), 18-23. doi:10.5155/eurjchem.5.1.18-23.876
Rizk, Mohammed, Safaa Shafik Toubar, Hossam Ezz El-Din Sayour, Dalia Mohamed, & Rehab Moussa Touny. "A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate." European Journal of Chemistry [Online], 5.1 (2014): 18-23. Web. 23 Sep. 2023
Rizk, Mohammed, Toubar, Safaa, Sayour, Hossam, Mohamed, Dalia, AND Touny, Rehab. "A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate" European Journal of Chemistry [Online], Volume 5 Number 1 (31 March 2014)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.5.1.18-23.876


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2014, 5(1), 18-23 | doi: https://doi.org/10.5155/eurjchem.5.1.18-23.876 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)





© Copyright 2010 - 2023  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.