

A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate
Mohammed Rizk (1,*)





(1) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(2) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(3) Analytical Chemistry Department, Animal Health Research Institute, Dokki, 12311, Giza, Egypt
(4) Analytical Chemistry Department, Faculty of Pharmacy-Helwan University, Ein Helwan, 11795, Cairo, Egypt
(5) Quality Control Department, Chemical Industries Development Company, El-Haram, 12111, Giza, Egypt
(*) Corresponding Author
Received: 13 Jul 2013 | Revised: 11 Aug 2013 | Accepted: 11 Aug 2013 | Published: 31 Mar 2014 | Issue Date: March 2014
Abstract
A new potentiometric sensor based on molecularly imprinted polymer (MIP) was fabricated for the recognition and determination of imidocarb dipropionate. The MIP was synthesized using imidocarb as the template material, methacrylic acid as a functional monomer, and ethylene glycol dimethacrylate as a cross linking agent. The sensor showed a high selectivity and a sensitive response to the template molecule in aqueous solution. The MIP-electrode exhibited a near-Nernstian response in a wide concentration range 10-5 - 10-2 M with a lower detection limit of 2×10-6 M. The potentiometric conditions were carefully studied and all measuring parameters were optimized including pH, buffer type, plasticizer type, response time and stability. The applicability of the sensor was tested through potentiometric determination of imidocarb dipropionate in pure drug as well as in pharmaceutical formulation. The proposed method was statistically compared with a reported one showing no significant difference regarding accuracy and precision, which assured a good reliable novel sensor for imidocarb estimation.
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DOI: 10.5155/eurjchem.5.1.18-23.876
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Citations
[1]. Abbas J. Kadhem, Guillermina J. Gentile, Maria M. Fidalgo de Cortalezzi
Molecularly Imprinted Polymers (MIPs) in Sensors for Environmental and Biomedical Applications: A Review
Molecules 26(20), 6233, 2021
DOI: 10.3390/molecules26206233

[2]. Ayman H. Kamel, Somaia G. Mohammad, Nasser S. Awwad, Yomna Y. Mohammed
Survey on the Integration of Molecularly Imprinted Polymers as Artificial Receptors in Potentiometric Transducers for pharmaceutical Drugs
International Journal of Electrochemical Science 14(2), 2085, 2019
DOI: 10.20964/2019.02.23

[3]. Menna El-Beshlawy, Hassan Arida
New Miniaturized Disposable Screen-Printed Microchip Integrated with Molecularly Imprinted Polymer for Metronidazole Benzoate Drug Detection
Micromachines 13(12), 2107, 2022
DOI: 10.3390/mi13122107

[4]. Ghada AbdElHamid Sedik, Doha Mohamed Naguib, Fahima Morsy, Hala Elsayed Zaazaa
Validated Stability Indicating Chromatographic Methods for Quantification of Imidocarb Dipropionate; Application for the Determination of Its Residues in Bovine Meat and Milk Samples
Journal of AOAC INTERNATIONAL 103(4), 980, 2020
DOI: 10.1093/jaoacint/qsaa008

[5]. Dan Yang, Shiliang Mei, Zhuoqi Wen, Xian Wei, Zhongjie Cui, Bobo Yang, Chang Wei, Yi Qiu, Min Li, Hui Li, Wanlu Zhang, Fengxian Xie, Le Wang, Ruiqian Guo
Dual-emission of silicon nanoparticles encapsulated lanthanide-based metal-organic frameworks for ratiometric fluorescence detection of bacterial spores
Microchimica Acta 187(12), , 2020
DOI: 10.1007/s00604-020-04643-7

[6]. Nesrine Abdelrehim El Gohary, Adel Madbouly, Rasha Mohamed El Nashar, Boris Mizaikoff
Synthesis and application of a molecularly imprinted polymer for the voltammetric determination of famciclovir
Biosensors and Bioelectronics 65, 108, 2015
DOI: 10.1016/j.bios.2014.10.024

[7]. Nora H. Al-Shaalan, Jenny Jeehan Nasr, Shereen Shalan, Areej M. El-Mahdy
Use of green-modified micellar liquid chromatography for the determination of Imidocarb dipropionate residues in food samples
Microchemical Journal 178, 107316, 2022
DOI: 10.1016/j.microc.2022.107316

[8]. Yonghong Han, Juan Tao, Nisar Ali, Adnan Khan, Sumeet Malik, Hamayun Khan, Chunhao Yu, Yong Yang, Muhammad Bilal, Ahmed A. Mohamed
Molecularly imprinted polymers as the epitome of excellence in multiple fields
European Polymer Journal 179, 111582, 2022
DOI: 10.1016/j.eurpolymj.2022.111582

[9]. Guat Wei Lim, Jit Kang Lim, Abdul Latif Ahmad, Derek Juinn Chieh Chan
Molecularly imprinted polymer layers using Navicula sp. frustule as core material for selective recognition of lysozyme
Chemical Engineering Research and Design 101, 2, 2015
DOI: 10.1016/j.cherd.2015.06.005

[10]. Shimaa A. Atty, Hala E. Zaazaa, Fahima A. Morsy, Doha M. Naguib, Ghada A. Sedik
Nano Green Voltammetric Determination of Imidocarb Dipropionate and Its Residues in Bovine Meat, Milk and Urine Samples
Journal of The Electrochemical Society 167(4), 047510, 2020
DOI: 10.1149/1945-7111/ab7115

References
[1]. Chow, C. F.; Lam, M. H. W.; Leung, M. K. P. Anal. Chim. Acta 2002, 466, 17-30.
http://dx.doi.org/10.1016/S0003-2670(02)00520-2
[2]. Martin-Esteban, A. Anal. Bioanal. Chem. 2004, 378, 1875-1875.
http://dx.doi.org/10.1007/s00216-004-2502-8
[3]. Roche, P. J. R.; Ng, S. M.; Narayanaswamy, R.; Goddard, N.; Page, K. M. Sens. Actuators B Chem. 2009, 139, 22-29.
http://dx.doi.org/10.1016/j.snb.2008.07.029
[4]. He, C. Y.; Liu, F.; Li, K. A.; Liu, H. W. Anal. Lett. 2006, 39, 275-286.
http://dx.doi.org/10.1080/00032710500476946
[5]. Yang, H. H.; Zhang, S. Q.; Tan, F.; Zhuang, Z. X.; Wang, X. R. J. Am. Chem. Soc. 2005, 127, 1378-1379.
http://dx.doi.org/10.1021/ja0467622
[6]. Chai, C.; Liu, G.; Li, F.; Liu, X.; Yao, B.; Wang, L. Anal. Chim. Acta 2010, 675, 185-190.
http://dx.doi.org/10.1016/j.aca.2010.07.012
[7]. Kriz, D.; Mosbach, K. Anal. Chim. Acta 1995, 300, 71-75.
http://dx.doi.org/10.1016/0003-2670(94)00368-V
[8]. Chen,P.; Nien, P.; Wu, C.; Wu, T.; Lin, C.; Ho, K. Anal. Chim. Acta 2009, 643, 38-44.
http://dx.doi.org/10.1016/j.aca.2009.04.004
[9]. Chen, P.; Vittal, R.; Nien, P.; Liou, G.; Ho, K. Talanta 2010, 80, 1145-1151.
http://dx.doi.org/10.1016/j.talanta.2009.08.041
[10]. Sadeghi, S.; Motaharian, A.; Moghaddam, A. Z. Sens. Actuators B Chem. 2012, 168, 336-344.
http://dx.doi.org/10.1016/j.snb.2012.04.031
[11]. Tarley, C. R. T.; Kubota, L. T. Anal. Chim. Acta 2005, 548, 11-19.
http://dx.doi.org/10.1016/j.aca.2005.05.055
[12]. Say, R.; Gultekin, A.; Ozcan, A. A.; Denizli, A.; Ersoz, A. Anal. Chim. Acta 2009, 640, 82-86.
http://dx.doi.org/10.1016/j.aca.2009.03.022
[13]. Kobayashi, T.; Murawaki, Y.; Reddy, P. S.; Abe, M.; Fujii, N. Anal. Chim. Acta 2001, 435, 141-149.
http://dx.doi.org/10.1016/S0003-2670(00)01281-2
[14]. Hao, H. X.; Zhou, H.; Chang, J.; Zhu, J.; Wei, T. X. Chin. Chem. Lett. 2011, 22, 477-480.
http://dx.doi.org/10.1016/j.cclet.2010.11.004
[15]. Sadeghi, S.; Fathi, F.; Abbasifar, J. Sens. Actuators B Chem. 2007, 122, 58-164.
[16]. Tonelli, D.; Ballarin, B.; Guadagnini, L.; Mignani, A.; Scavetta, E. Electrochim. Acta. 2011, 56, 7149-7154.
http://dx.doi.org/10.1016/j.electacta.2011.05.076
[17]. Coldham, N. G.; Moore, A. S.; Dave, M.; Graham, P. J.; Sivapathasundardm, S.; Lake, B. G.; Sauer, M. J. Drug Metab. Disp. I995, 23, 501-505.
[18]. Edelhofer, R.; Muller, A.; Schuh, M.; Obritzhauser, W.; Kanout, A. Parasitol. Res. 2004, 92, 433-435.
http://dx.doi.org/10.1007/s00436-003-1060-x
[19]. Kuttler, K. L.; Johnson, L. W. Vet. Parasitol. 1986, 21, 107-118.
http://dx.doi.org/10.1016/0304-4017(86)90151-2
[20]. Tarbin, J. A.; Shearer, G. J. Chromatogr. B. Biomed. Sci. Appl. 1992, 577, 376-381.
http://dx.doi.org/10.1016/0378-4347(92)80263-P
[21]. Ishii, R.; Takahashi, K.; Matsumoto, R. Shokuhin Eiseigaku Zasshi 2010, 52, 34-39.
http://dx.doi.org/10.3358/shokueishi.52.34
[22]. Lehner, A. F.; Hitron, J. A.; May, J.; Hughes, C.; Eisenberg, R.; Schwint, N.; Knowles, D. P.; Timoney, P.; Tobin, T. J. Anal. Toxicol. 2011, 35, 199-204.
http://dx.doi.org/10.1093/anatox/35.4.199
[23]. Koichi, I.; Mari, N.; Tomoaki, H.; Hisao, O. J. Liq. Chromatogr. Relat. Technol. 2011, 34, 2149-2156.
http://dx.doi.org/10.1080/10826076.2011.585484
[24]. Duffy, D.J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. J. Am. Chem. Soc. 2002, 124, 8290-8296.
http://dx.doi.org/10.1021/ja0201146
[25]. Katz, A.; Davis, M. E. Macromolecules 1999, 32, 4113-4121.
http://dx.doi.org/10.1021/ma981445z
[26]. Umezawa, Y.; Umezawa, K.; Sato, H. Pure Appl. Chem. 1995, 67, 507-518.
http://dx.doi.org/10.1351/pac199567030507
[27]. Miller, J. C.; Miller, J. N. Statistics for Analytical Chemistry, fifth edition, Wiley, New York, 2005, p. 256.
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