European Journal of Chemistry

Spectrophotometric determination of palladium using 2-hydraziniopyridine

Article Sidebar

PDF
Published: Mar 31, 2014
DOI: https://doi.org/10.5155/eurjchem.5.1.150-154.926
Keywords:
Palladium, Stoichiometry, Stability complexes, 2-Hydraziniopyridine, Validation parameters, Spectrophotometric determination
Section
Research Article
Issue
Vol. 5 No. 1 (2014): March 2014
Dates
Received 2013-09-11
Accepted 2013-11-05
Published 2014-03-31


Main Article Content

Ahmed Ahmed Soliman
Department of Chemistry, Faculty of Science, Cairo University, 12613 Giza, Egypt
Sattar Rajab Majeed
Department of Chemistry, Faculty of Science, Al-Anbar University, 31001 Al-Ramady, Iraq
Fawzy Ali Attaby
Department of Chemistry, Faculty of Science, Cairo University, 12613 Giza, Egypt

Abstract

Rapid, simple, sensitive and validated spectrophotometric method has been described for the determination of palladium (II) using 2-hydrazinopyridine. The complex product was quantitatively measured at 510 nm and the reaction conditions were studied and optimized. The stoichiometry and the stability constant of the purple colored complex has been determined spectrophotometrically in aqueous solution at 25 oC using Job’s continuous variation and the molar ratio methods. The complex has 1:1 (M:L) molar ratio and Beer’s plot was linear in the concentration ranges 1.06-9.00 μg/mL with corresponding molar absorptivity 2.978×103 L/mol.cm. The limits of detection and Sandell’s sensitivity were also evaluated. The accuracy was evaluated as the % recovery (96.61-102.58) and precision was evaluated as RSD% (0.04-0.41) using inter-day and intraday analyses of multiple samples. The effect of various diverse ions on the determination of Pd(II) has been investigated.


icon graph This Abstract was viewed 1599 times | icon graph Article PDF downloaded 1046 times

How to Cite
(1)
Soliman, A. A.; Majeed, S. R.; Attaby, F. A. Spectrophotometric Determination of Palladium Using 2-Hydraziniopyridine. Eur. J. Chem. 2014, 5, 150-154.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Angelone, M.; Nadri, E.; Pinto, V.; Cremisini Palladium Emissions in the Environment (review chapter) Springer-Verlag Berlin Heidelberg 2006.

[2]. WHO, Environmental health criteria 226: palladium. International program on chemical safety, World Health Organization (2002), Geneva Johnson Matthey (2001).

[3]. Ravindra, K.; Bencs, L.; Van Grieken, R. Sci. Total Environ. 2004, 318, 1-43.
http://dx.doi.org/10.1016/S0048-9697(03)00372-3

[4]. Georgieva, M.; Pilar, B. Fresenius J. Anal. Chem. 1997, 357, 847-880.
http://dx.doi.org/10.1007/s002160050266

[5]. Kollensperger, G.; Hann, S.; Stingeder, G. J. Anal. At. Spectrom. 2000, 15, 1553-1557.
http://dx.doi.org/10.1039/b006695h

[6]. Bencs, L.; Ravindra, K.; Van Grieken, R. Spectrochim. Acta B 2003, 58, 1723-1755.

[7]. Fritsche, J.; Meisel, T. Sci. Total Environ. 2004, 325, 145-154.
http://dx.doi.org/10.1016/j.scitotenv.2003.11.019

[8]. Schuster, M.; Schwarzer, M. Anal. Chim. Acta 1996, 328, 1-11.
http://dx.doi.org/10.1016/0003-2670(96)00091-8

[9]. Gojare, P. T.; Gaikwad, S. H.; Anuse, M. A. Reserch J. Chem. Envir. 2001, 5(3), 51-56.

[10]. Huang, Z.; Wei, Q.; Yang, X.; Hu, Q.; Chen, J.; Yang, G. Bull. Korean Chem. Soc. 2005, 26(10), 1623-1626.
http://dx.doi.org/10.5012/bkcs.2005.26.10.1623

[11]. Ratre, P.; Kumar, D. Int. J. Emerg. Tech. Comput. Appl. Sci. 2013, 5(4), 421-429.

[12]. Po, B. L.; Hengchuan, L. Talanta 1991, 38(10), 1143-1146.
http://dx.doi.org/10.1016/0039-9140(91)80233-P

[13]. Kadyan, P. S.; Singh, D.; Sharma, A.; Singh, I. Der Pharma Chemica 2011, 3 (6), 70-74.

[14]. Pethe G. B.; Bhadange, S. G.; Joshi, M. D.; Aswar, A. S. Adv. Appl. Sci. Res. 2010, 1(2), 58-64.

[15]. Borhade, S. Life sciences Leaflets 2012, 10, 1-9

[16]. Müller, C.; Dumas, C.; Hoffmann, U.; Schubiger, P. A.; Schibli, A. J. Organomet. Chem. 2004, 689, 4712-4721.
http://dx.doi.org/10.1016/j.jorganchem.2004.08.045

[17]. Machuqueiro, M.; Darbre, T. J. Inorg. Biochem. 2003, 94, 193-196.
http://dx.doi.org/10.1016/S0162-0134(02)00625-6

[18]. Gultneh, Y.; Khan, A. R.; Blaise, D.; Chaudhry, S.; Ahvazi, B.; Marvey, B. B.; Butcher, R. J. J. Inorg. Biochem. 1999, 75, 7-18.
http://dx.doi.org/10.1016/S0162-0134(99)00025-2

[19]. Soliman, A. A.; Khattab, M. M.; Ramadan, R. M. Trans. Met. Chem. 2007, 32, 325-331.
http://dx.doi.org/10.1007/s11243-006-0171-5

[20]. Soliman, A. A.; Khattab, M. M.; Linert W. J. Coord. Chem. 2008, 61(13), 2017-2031.
http://dx.doi.org/10.1080/00958970701824373

[21]. Khattab, M. M.; Soliman, A. A.; and Linert, W. Int. J. Chem. Kinet. 2010, 42, 132-142.
http://dx.doi.org/10.1002/kin.20470

[22]. Baranska, M.; Lasocha, W.; Kozlowski, H; Soliman, L. M. J. Inorg. Biochem. 2004, 98, 995-1001.
http://dx.doi.org/10.1016/j.jinorgbio.2004.02.016

[23]. Beaulieu, N.; Graham, S. J.; Sears, R. W.; Lovering, E. G. J. Pharmaceut. Biomed. 1989, 7, 1705-1709.
http://dx.doi.org/10.1016/0731-7085(89)80184-0

[24]. Job, P. Ann. Chim. 1936, 6, 97-144.

[25]. Yoe, J. H.; Jones, A. L. Ind. End. Chem. Anal. 1944, 16, 111-115.
http://dx.doi.org/10.1021/i560126a015

[26]. Miller J. N.; Miller, J. C. Statistics and Chemometrics for Analytical Chemistry, 6th ed., Prentice Hall, England, 2006.

[27]. Tirmizi, S. A.; Muhammad H. S.; Wattoo, S. S.; Waheed. A. Arab. J. Sci. Eng. 2009, 34(2), 43-48.

[28]. Inczedy, J. Analytical Application of Complex Equilibra, John Wiley, Budapest, 1976.

[29]. Thipyapong, K.; Suksai, C. B. Korean Chem. Soc. 2003, 24(12), 1767-1770
http://dx.doi.org/10.5012/bkcs.2003.24.12.1767

[30]. Ramadan, A.; Mandil, H.; Dahhan, M. Int. J. Pharm. Pharm. Sci. 2012, 5(1), 428-433.

[31]. Benesi, H. A.; Hildebrand, J. H. J. Am. Chem. Soc. 1949, 71, 2703-2707.
http://dx.doi.org/10.1021/ja01176a030

[32]. Issa, Y. M.; El-Hawary, W. F.; Yousef, A. F. A.; Senosy, A. R. Spectrochim. Acta A 2010, 75(4), 1297-1303.
http://dx.doi.org/10.1016/j.saa.2009.12.068

[33]. Gouda, A. A.; El-sheikh, R.; El Shafey, Z.; Hossny, N.; El-Azzazy, R. Int. J. Biomde. Sci. 2008, 4(4), 294-302.

[34]. Kumar, A. Anal. Sci. 1995, 11, 281-284.
http://dx.doi.org/10.2116/analsci.11.281

Supporting Agencies

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).