Synthesis, characterization and thermal decomposition kinetics of  poly(2-imidazolidinthione-formaldehyde)

Naushad Ahmad; Rizwan Wahab; Suliman Yousef Al Oma

doi:10.5155/eurjchem.5.1.155-161.929

PDF

Published: Mar 31, 2014

DOI: https://doi.org/10.5155/eurjchem.5.1.155-161.929

Keywords:

Kinetics, Polymers, Activation energy, Polycondensation, Thermal degradation, Antibacterial activity

Section

Research Article

Issue

Vol. 5 No. 1 (2014): March 2014

Dates

Received 2013-09-21
Accepted 2013-10-30
Published 2014-03-31

Naushad Ahmad

Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Rizwan Wahab

Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Suliman Yousef Al Oma

Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Abstract

A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.

This Abstract was viewed 2010 times |

Article PDF downloaded 845 times

How to Cite

(1)

Ahmad, N.; Wahab, R.; Al Oma, S. Y. Synthesis, Characterization and Thermal Decomposition Kinetics of poly(2-Imidazolidinthione-Formaldehyde). Eur. J. Chem. 2014, 5, 155-161.

Links for Article

Crossref - Scopus - Google - European PMC

References

[1]. Li, X.; Jiao, Y.; Li, S. Eur. Polym. J. 1991, 27, 1345-1351.
http://dx.doi.org/10.1016/0014-3057(91)90233-E

[2]. Chen, I.; Xu, H.; Yu, X.; Zhu, Y.; Yang, C. J. Polym. Sci. Part A, Polym. Chem. 1996, 34, 721-728.
http://dx.doi.org/10.1002/(SICI)1099-0518(19960415)34:5<721::AID-POLA1>3.0.CO;2-Q

[3]. Kaliyappan, T.; Kannan, T. Prog. Polym. Sci. 2000, 25, 343-347.
http://dx.doi.org/10.1016/S0079-6700(00)00005-8

[4]. Yesilkaynak, T.; Binzet, G.; Emen, FM.; Florke, U.; Kulcu, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3

[5]. Yue, D.; Larock, R. C. J. Org. Chem. 2002, 67, 1905-1909.
http://dx.doi.org/10.1021/jo011016q

[6]. Adams, R.D. Aldrichimica Acta 2000, 33, 39-48.

[7]. Mukherjee, C.; Kamila, S.; De, A. Terahedron 2003, 59, 4767-4774.
http://dx.doi.org/10.1016/S0040-4020(03)00710-5

[8]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39.
http://dx.doi.org/10.5155/eurjchem.3.1.37-39.591

[9]. Finkelmann, H. Angew. Chem. Int. Ed. Eng. 1987, 26, 816-824.
http://dx.doi.org/10.1002/anie.198708161

[10]. Aguilera, C.; Parra, M.; Fuentes, G. Naturforsch. B 1998, 53, 367-370.

[11]. Choi, M. H.; Jeon, B. H.; Chung, I. J. Polymer 2000, 41, 3243-3252.
http://dx.doi.org/10.1016/S0032-3861(99)00532-7

[12]. Choi, M. H.; Chung, I. J.; Lee, J. D. Chem. Mater. 2000, 12, 2977-2983.
http://dx.doi.org/10.1021/cm000227t

[13]. Wahab, R.; Kim, Y. S.; Mishra, A. S.; Yun, Il.; Shin, H. S. Nanoscale Res. Lett. 2010, 5, 1675-1681.
http://dx.doi.org/10.1007/s11671-010-9694-y

[14]. Wahab, R.; Kim, Y. S.; Mishra, A.; Yun, S. Il.; Shin, H. S. Appl. Micro. Biotech. 2010, 87, 1917-1925.
http://dx.doi.org/10.1007/s00253-010-2692-2

[15]. Abdullah, B. H.; Salh, Y. M. Oriental J. Chem. 2010, 26, 763-773.

[16]. Kausar, A.; Zulfiqar, S.; Yavuz, C. T.; Sarwar, M. I. Polym. Degrad. Stabil. 2011, 96, 1333-1341.
http://dx.doi.org/10.1016/j.polymdegradstab.2011.03.017

[17]. Bajia, S. C.; Swarnkar, P.; Kumar, S.; Bajia, B. A E-J Chem. 2007, 4(4), 457-460.

[18]. Safavi, A.; Iranpoor, N.; Saghir, N. Sep. Purif. Technol. 2004, 40, 303-308.
http://dx.doi.org/10.1016/j.seppur.2004.03.013

[19]. Shockravi, A.; Abouzari-Lotf, E.; Javadi, A. A.; Atabaki, F. Euro. Poly. J. 2009, 45, 1599-1606.
http://dx.doi.org/10.1016/j.eurpolymj.2009.01.014

[20]. Kausar, A.; Zulfiqar, S.; Ahmad, Z.; Sarwar, M. I. Polym. Degrad. Stabil. 2010, 95, 2281-2288.
http://dx.doi.org/10.1016/j.polymdegradstab.2010.09.006

[21]. Fan, D. B.; Chang, J. M.; Li, J.; Mao, A.; Zhang, L. T. J. Appl. Polym. Sci. 2009, 112, 2195-2102.
http://dx.doi.org/10.1002/app.29532

[22]. Milena, M. C.; Dragan, B.; Renata, J.; Katarina, P. P.; Miroslav, P. Polym. Degrad. Stabil. 2003, 81, 387-392.
http://dx.doi.org/10.1016/S0141-3910(03)00121-6

[23]. Sueoka, K.; Nagata, M.; Ohtani, H.; Nagai, N.; Tsuge, S. J. Appl. Polym. Sci. Part A, Polym. Chem. 1999, 29, 1903-1908.
http://dx.doi.org/10.1002/pola.1991.080291309

[24]. Jin, X.; Chung, T. S. J. Appl. Polym. Sci. 1999, 73, 2195-2206.
http://dx.doi.org/10.1002/(SICI)1097-4628(19990912)73:11<2195::AID-APP17>3.0.CO;2-3

[25]. Willium, P. T.; Besler, S. Renew Energ. 1996, 7, 233-250.
http://dx.doi.org/10.1016/0960-1481(96)00006-7

[26]. Teng, X. G.; Li, F. Q.; Ma, P. H.; Ren, Q. D.; Li, S. Y. Thermochim. Acta. 2005, 436, 30-34.
http://dx.doi.org/10.1016/j.tca.2005.07.004

[27]. Ozawa, T. Bull. Chem. Soc. Jpn. 1965, 38, 1881-1886.
http://dx.doi.org/10.1246/bcsj.38.1881

[28]. Flynn, J. H.; Wall, L. A. J. Polym. Sci. B: Polym. Lett. 1996, 4, 323-328.
http://dx.doi.org/10.1002/pol.1966.110040504

[29]. Friedman, H. L. J. Polym. Sci. C 1964, 6, 183-195.

[30]. Kissinger, H. E. Anal. Chem. 1957, 29, 1702-1706.
http://dx.doi.org/10.1021/ac60131a045

[31]. Tao, R. M.; Xin, Li.; Yao, C. G. Front. Mater. Sci. China. 2010, 4, 78-83.

[32]. Khattab, M. A.; Price, D.; Horrocks, A. R. J. Appl. Polym. Sci. 1990, 41, 3069-3078.
http://dx.doi.org/10.1002/app.1990.070411139

[33]. Corres, M. A.; Zubitur, M.; Cortazar, M.; Mugica, A. J. Anal. Appl. Pyrol. 2011, 92(2), 407-416.
http://dx.doi.org/10.1016/j.jaap.2011.08.002

[34]. Chang, T. C.; Shen, W. S.; Chiu, Y. S.; Ho, S. Y. Polym. Degrad. Stab. 1995, 49, 353-360.
http://dx.doi.org/10.1016/0141-3910(95)00116-4

[35]. Ciofi, N.; Torsi, L.; Ditaranto, N.; Tantillo, G.; Ghibelli, L.; Sabatini, L.; Zacheo, T. T.; Alessio, M. D.; Zambonin, P. G.; Traversa, E. Chem. Mater. 2005, 17, 5255-5262.
http://dx.doi.org/10.1021/cm0505244

Supporting Agencies

King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Most read articles by the same author(s)

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)

Downloads

Metrics