

Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)
Naushad Ahmad (1)



(1) Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(2) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(3) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(*) Corresponding Author
Received: 21 Sep 2013 | Revised: 29 Oct 2013 | Accepted: 30 Oct 2013 | Published: 31 Mar 2014 | Issue Date: March 2014
Abstract
A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.
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DOI: 10.5155/eurjchem.5.1.155-161.929
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King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
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