Synthesis, characterization and thermal decomposition kinetics of  poly(2-imidazolidinthione-formaldehyde)

Naushad Ahmad; Rizwan Wahab; Suliman Yousef Al Oma

doi:10.5155/eurjchem.5.1.155-161.929

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Published: Mar 31, 2014

DOI: https://doi.org/10.5155/eurjchem.5.1.155-161.929

Keywords:

Kinetics, Polymers, Activation energy, Polycondensation, Thermal degradation, Antibacterial activity

Section

Research Article

Issue

Vol. 5 No. 1 (2014): March 2014

Dates

Received 2013-09-21
Accepted 2013-10-30
Published 2014-03-31

Naushad Ahmad

Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Rizwan Wahab

Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Suliman Yousef Al Oma

Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

Abstract

A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.

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How to Cite

(1)

Ahmad, N.; Wahab, R.; Al Oma, S. Y. Synthesis, Characterization and Thermal Decomposition Kinetics of poly(2-Imidazolidinthione-Formaldehyde). Eur. J. Chem. 2014, 5, 155-161.

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King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

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