Synthesis, characterization and thermal decomposition kinetics of  poly(2-imidazolidinthione-formaldehyde)

Naushad Ahmad; Rizwan Wahab; Suliman Yousef Al Oma

doi:10.5155/eurjchem.5.1.155-161.929

European Journal of Chemistry 2014, 5(1), 155-161 | doi: https://doi.org/10.5155/eurjchem.5.1.155-161.929 | Get rights and content

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Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)

Naushad Ahmad ⁽¹⁾

, Rizwan Wahab ^(2,*)

, Suliman Yousef Al Oma ⁽³⁾

⁽¹⁾ Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
⁽²⁾ Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
⁽³⁾ Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
^(*) Corresponding Author

Received: 21 Sep 2013 | Revised: 29 Oct 2013 | Accepted: 30 Oct 2013 | Published: 31 Mar 2014 | Issue Date: March 2014

Abstract

A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.

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Keywords

Kinetics; Polymers; Activation energy; Polycondensation; Thermal degradation; Antibacterial activity

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DOI: 10.5155/eurjchem.5.1.155-161.929

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King Saud University, Riyadh 11451, Kingdom of Saudi Arabia

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How to cite

Ahmad, N.; Wahab, R.; Al Oma, S. Eur. J. Chem. 2014, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929

Ahmad, N.; Wahab, R.; Al Oma, S. Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde). Eur. J. Chem. 2014, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929

Ahmad, N., Wahab, R., & Al Oma, S. (2014). Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde). European Journal of Chemistry, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929

Ahmad, Naushad, Rizwan Wahab, & Suliman Yousef Al Oma. "Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)." European Journal of Chemistry [Online], 5.1 (2014): 155-161. Web. 24 Sep. 2023

Ahmad, Naushad, Wahab, Rizwan, AND Al Oma, Suliman. "Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)" European Journal of Chemistry [Online], Volume 5 Number 1 (31 March 2014)

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