European Journal of Chemistry

An N-heterocyclic carbene-palladium-η3-allyl chloride complex for the Suzuki-Miyaura coupling of aryl halides

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Published: Mar 31, 2014
DOI: https://doi.org/10.5155/eurjchem.5.1.162-166.940
Keywords:
Carbenes, Palladium, Aryl chlorides, Aryl bromides, Cross-coupling, Homogeneous catalysis
Section
Research Article
Issue
Vol. 5 No. 1 (2014): March 2014
Dates
Received 2013-09-29
Accepted 2013-10-29
Published 2014-03-31


Main Article Content

Noland William Broekemier
Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA
Noah Curtis Broekemier
Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA
Randall Thomas Short
Department of Chemistry, Ball State University, Muncie, IN 47306, USA
Hector Palencia
Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA

Abstract

An unsymmetrical, well-defined N-heterocyclic carbene-palladium-η3-allyl chloride complex has been synthesized and used as an efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides. The catalyst provides moderate to high yields of cross-coupling products at 50 °C in 2 hours, using 1 mol % of the catalyst and isopropyl alcohol as solvent.


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(1)
Broekemier, N. W.; Broekemier, N. C.; Short, R. T.; Palencia, H. An N-Heterocyclic Carbene-Palladium-η3-Allyl Chloride Complex for the Suzuki-Miyaura Coupling of Aryl Halides. Eur. J. Chem. 2014, 5, 162-166.

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