European Journal of Chemistry

Interaction of charge transfer fluorescence probe with non-ionic surfactants: Estimation of physico-chemical properties and association constant

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Published: Dec 22, 2010
DOI: https://doi.org/10.5155/eurjchem.1.4.341-347.98
Keywords:
Fluorescence, Non-ionic surfactants, Intramolecular charge transfer, CMC, Micropolarity, Association constant
Section
Research Article
Issue
Vol. 1 No. 4 (2010): December 2010
Dates
Received 2010-05-06
Accepted 2010-09-20
Published 2010-12-22


Main Article Content

Takhellambam Sanjoy Singh
Department of Chemistry, North-Eastern Hill University, Shillong, IN-793022, India
Sivaprasad Mitra
Department of Chemistry, North-Eastern Hill University, Shillong, IN-793022, India

Abstract

Fluorescence behavior of intramolecular charge transfer probe trans-ethyl-p-(dimethylamino) cinnamate (EDAC) is extremely sensitive to the local environment. This study explores the interaction of EDAC with several Igepal, Brij and Tween series of non-ionic surfactants by steady state and picoseconds time-resolved fluorescence spectroscopy. The physico-chemical properties, like critical micelle concentration and micropolarity of the micellar media surrounding the probe were determined. In most of the cases, the observed values were in good agreement with the data reported in the literature. Results obtained from time-resolved fluorescence experiments show a substantial reduction in total non-radiative decay rate of the probe in micellar medium compared to that in aqueous phase. This indicates preferential association of the probe inside the micellar core. The association constant of the probe-micelle interaction was also evaluated in different cases.

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Singh, T. S.; Mitra, S. Interaction of Charge Transfer Fluorescence Probe With Non-Ionic Surfactants: Estimation of Physico-Chemical Properties and Association Constant. Eur. J. Chem. 2010, 1, 341-347.

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