European Journal of Chemistry 2011, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317

Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere


Munusamy Vennila (1) , Govindasamy Manikandan (2) , Venugopal Thanikachalam (3) , Jayaraman Jayabharathi (4,*)

(1) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(2) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(3) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(4) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(*) Corresponding Author

Received: 14 Nov 2010, Accepted: 26 Jan 2011, Published: 30 Jun 2011

Abstract


The thermal degradation of N-(salicylidene)-L-leucine was studied under non-isothermal conditions in air atmosphere. For kinetic analysis, the TG/DTA/DTG data obtained at three different heating rates were processed by Friedman, Kissinger-Akahira-Sunose, Flynn-Wall-Ozawa and Kissinger methods. The analysis indicates a complex reaction process which can be best described by the three dimensional (Ginstling-Brounshtein) model D4.

2_2_229_234_800


Keywords


Schiff base; Thermal degradation; Isoconversional; Crystal deformation; Non-isothermal; Activation energy

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DOI: 10.5155/eurjchem.2.2.229-234.317

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References

[1]. Nejati, K.; Rezvani. Z.; Massoumi, B. Dyes and Pigments 2007, 75, 653-657.
doi:10.1016/j.dyepig.2006.07.019

[2]. Souza, P.; Garcia-Vazqueez, J. A.; Masaquer, J. R. Transit. Metal Chem. 1985, 10, 410¬-412.

[3]. Naeimi, H.; Safari, J.; Heidarzezhad, A. Dyes and Pigments 2007, 73, 251-253.
doi:10.1016/j.dyepig.2005.12.009

[4]. Lippard, S. S.; Berg, J. M.; Principles of Bioinorganic Chemistry, California, University Science Books, 1994.

[5]. Tumer, M.; Ekiria, D.; Tumer, F.; Bulur, A. Spectrochim. Acta A 2007, 67, 916-929.
doi:10.1016/j.saa.2006.09.009
PMid:17046317

[6]. Puri, A.; Berden, I.; Morgenstem-Badarasu; Gref, A.; Perrae-Fluvet, M. Inorg. Chim. Acta 2001, 320, 167-171.

[7]. Ispin, E. Dyes and Pigments 2009, 82, 13-19.
doi:10.1016/j.dyepig.2008.09.019

[8]. Wang, M. Z.; Meng, Z. X.; Liu, Bo. Li.; Cai, G. L.; Zhang, C. L.; Wang, X. Y. Inorg. Chem. Commun. 2005, 8, 368-371.
doi:10.1016/j.inoche.2005.01.023

[9]. Guirard, B. M.; Snell, E. E.; In: Florkin, M.; Stotz, E. H. (Eds.) Comprehensive Biochemistry, Elsevier, Amsterdam, 1981.

[10]. Sigman, D. S.; Mazumter, A.; Perrin, D. M.; Chem. Rev. 1993, 93, 2295-2316.
doi:10.1021/cr00022a011

[11]. Gaussian 98, Gaussian, Inc., Pittsburgh PA, 1998.

[12]. Howard, E. S.; Elizabeth, P.; Burrows, Maurice, J.; Marks, Robert, D.; Lynch, Chen, F. M. J. Am. Chem. Soc. 1977, 99, 707-713.
PMid:833383

[13]. Khawam, A.; Flangan, D. R. Thermochim. Acta 2005, 436, 101-112.
doi:10.1016/j.tca.2005.05.015

[14]. Chen, H. J.; Lai, K. M. J. Chem. Eng. Japan 2004, 37(a), 1172-1178.

[15]. Doyle, C. D. J. Appl. Polym. Sci. 1961, 5, 285-292.
doi:10.1002/app.1961.070051506

[16]. Agarwal, R. K.; Sivasubramanian, M. S. Aiche. J. 1987, 33, 1212-1214.
doi:10.1002/aic.690330716

[17]. Coats, A. W.; Redfern, J. P. Nature (London) 1964, 201, 68-69.
doi:10.1038/201068a0

[18]. Ahmaruzzamam, M.; Sharma, D. K. J. Anal. Appl. Pyrol. 2005, 73, 263-275.
doi:10.1016/j.jaap.2004.11.035

[19]. Perez-Maqueda, L. A.; Sanchez-Jimenez, P. E.; Criado, J. M. Polymer 2005, 46, 2950-2954.
doi:10.1016/j.polymer.2005.02.061

[20]. Barral, L.; Difz, F. J.; Garcia-Garbal, S.; Lopez, J.; Montero, B.; Montes, R.; Ramirez, C.; Rico, M. Eur. Poly. J. 2005, 41, 1662-1666.
doi:10.1016/j.eurpolymj.2005.01.021

[21]. Slovak, V.; Susak, P. J. Anal. Appl. Pyrolysis 2004, 72, 249-252.
doi:10.1016/j.jaap.2004.07.005

[22]. Vlaev, L. T.; Markoversuska, G.; Lyubchev, L. A. Thermochim. Acta 2003, 406, 1-7.
doi:10.1016/S0040-6031(03)00222-3

[23]. Srikanth, S.; Chakravortty, M. Thermochim. Acta 2001, 370, 141-148.
doi:10.1016/S0040-6031(00)00776-0

[24]. Ei-Hm, D.; Gabal, M. A.; El-Bellihi, A. A.; Eissa, N. A.; Thermochim. Acta 2001, 376, 43-50.
doi:10.1016/S0040-6031(01)00535-4

[25]. Joseph, K.; Sridharan, R.; Gnanasekaran, T. J. Nucl. Mater. 2000, 281, 129-139.
doi:10.1016/S0022-3115(00)00241-5

[26]. Hu, H.; Chen, Q.; Yin, Z.; Zhang, P.; Zou, J.; Che, H. Thermochim. Acta 2002, 389, 79-83.

[27]. Huang, J. W.; Chang, C. C.; Kang, C. C.; Yeh, M. Y. Thermochim. Acta 2008, 468, 66-74.
doi:10.1016/j.tca.2007.12.001

[28]. Friedman, H. L. J. Polym. Sci. Polym. Lett. 1963, 6C, 183-195.

[29]. Flynn, J. H.; Wall, L. A. J. Res. Nat. Bur. Stand. 1966, 70A, 487-523.

[30]. Ozawa, T. Bull. Chem. Soc. Jpn. 1965, 38, 1881-1886.
doi:10.1246/bcsj.38.1881

[31]. Kissinger, H. E. Anal. Chem. 1957, 29, 1702-1706.
doi:10.1021/ac60131a045

[32]. Kissinger, H. E. J. Res. Nat. Bur. Stand. 1956, 57, 217-221.

[33]. Akahira, T.; Sunose, T.; Res. Report CHIBA Inst. Technol. 1971, 16, 22-31.

[34]. Lesnikovich, A. I.; Levchik, S. V. J. Therm. Anal. Calorim. 1983, 27, 89-93.
doi:10.1007/BF01907324

[35]. Lesnikovich, A. I.; Levchik, S. V. J. Therm. Anal. Calorim. 1985, 30, 237-262.
doi:10.1007/BF02128134

[36]. Bamford, C. H.; Tipper, C. F. H. (Eds.) Comprehensive chemical kinetics, Vol. 22, Reactions in the solid state, Elsevier Sci. Publ. Comp. Amsterdam, 1980.

[37]. Cordes, H. F. J. Phys. Chem. 1968, 72, 2185-2189.
doi:10.1021/j100852a052

[38]. Criado, J. M.; Perez-Maqueda, L. A.; Sanchez-Jimenez, P. E. J. Therm. Anal. Calorim. 2005, 82, 671-675.
doi:10.1007/s10973-005-0948-3

[39]. Sokolskii, D. A.; Druz, V. A. Introduction in theory heterogenous catalysis, Vyshaya Shkola, Moscow, 1981 (in Russian).


How to cite


Vennila, M.; Manikandan, G.; Thanikachalam, V.; Jayabharathi, J. Eur. J. Chem. 2011, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, M.; Manikandan, G.; Thanikachalam, V.; Jayabharathi, J. Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere. Eur. J. Chem. 2011, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, M., Manikandan, G., Thanikachalam, V., & Jayabharathi, J. (2011). Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere. European Journal of Chemistry, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, Munusamy, Govindasamy Manikandan, Venugopal Thanikachalam, & Jayaraman Jayabharathi. "Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere." European Journal of Chemistry [Online], 2.2 (2011): 229-234. Web. 19 Nov. 2019
Vennila, Munusamy, Manikandan, Govindasamy, Thanikachalam, Venugopal, AND Jayabharathi, Jayaraman. "Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere" European Journal of Chemistry [Online], Volume 2 Number 2 (30 June 2011)

DOI Link: https://doi.org/10.5155/eurjchem.2.2.229-234.317

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