European Journal of Chemistry 2011, 2(2), 229-234 | doi: https://doi.org/10.5155/eurjchem.2.2.229-234.317 | Get rights and content






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Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere


Munusamy Vennila (1) , Govindasamy Manikandan (2) , Venugopal Thanikachalam (3) , Jayaraman Jayabharathi (4,*)

(1) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(2) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(3) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(4) Department of Chemistry, Annamalai University, Annamalai Nagar 608 002, India
(*) Corresponding Author

Received: 14 Nov 2010 | Revised: 24 Dec 2010 | Accepted: 26 Jan 2011 | Published: 30 Jun 2011 | Issue Date: June 2011

Abstract


The thermal degradation of N-(salicylidene)-L-leucine was studied under non-isothermal conditions in air atmosphere. For kinetic analysis, the TG/DTA/DTG data obtained at three different heating rates were processed by Friedman, Kissinger-Akahira-Sunose, Flynn-Wall-Ozawa and Kissinger methods. The analysis indicates a complex reaction process which can be best described by the three dimensional (Ginstling-Brounshtein) model D4.

2_2_229_234_800


Keywords


Schiff base; Thermal degradation; Isoconversional; Crystal deformation; Non-isothermal; Activation energy

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DOI: 10.5155/eurjchem.2.2.229-234.317

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How to cite


Vennila, M.; Manikandan, G.; Thanikachalam, V.; Jayabharathi, J. Eur. J. Chem. 2011, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, M.; Manikandan, G.; Thanikachalam, V.; Jayabharathi, J. Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere. Eur. J. Chem. 2011, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, M., Manikandan, G., Thanikachalam, V., & Jayabharathi, J. (2011). Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere. European Journal of Chemistry, 2(2), 229-234. doi:10.5155/eurjchem.2.2.229-234.317
Vennila, Munusamy, Govindasamy Manikandan, Venugopal Thanikachalam, & Jayaraman Jayabharathi. "Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere." European Journal of Chemistry [Online], 2.2 (2011): 229-234. Web. 2 Jun. 2020
Vennila, Munusamy, Manikandan, Govindasamy, Thanikachalam, Venugopal, AND Jayabharathi, Jayaraman. "Thermal decomposition of N-(salicylidene)-L-leucine in static air atmosphere" European Journal of Chemistry [Online], Volume 2 Number 2 (30 June 2011)

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DOI Link: https://doi.org/10.5155/eurjchem.2.2.229-234.317

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