European Journal of Chemistry 2014, 5(2), 237-240. doi:10.5155/eurjchem.5.2.237-240.981

The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study


Jinhuan Shan (1,*) , Ziwei Zhang (2)

(1) College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
(2) College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
(*) Corresponding Author

Received: 22 Nov 2013, Accepted: 04 Jan 2014, Published: 30 Jun 2014

Abstract


The kinetics of oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV) (DPN) had been studied spectrophotometrically in alkaline medium in the temperature range of 293.2 to 313.2 K. The reaction rate showed first order dependence on DPN, 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol. It was found that the pseudo-first-order rate constant kobs increased with an increase in concentration of OH- and a decrease in concentration of IO4-. There was a positive salt effect and no free radicals were detected. A plausible mechanism is proposed and the rate equations derived from the mechanism can explain all the experimental observations.


Keywords


Kinetics; Oxidation; Mechanism; 2-(2-Ethoxyethoxy)-ethanol; 2-(2-Methoxyethoxy)-ethanol; Dihydroxydiperiodatonickelate(IV)

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DOI: 10.5155/eurjchem.5.2.237-240.981

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References

[1]. Shan, J. H.; Li, Y.; Huo, S. H.; Yin, C. H. J. Chem. 2013, 2013, Article ID 627324.

[2]. Shan, J. H.; Li, Y. Eur. J. Chem. 2013, 4(3), 203-206.
http://dx.doi.org/10.5155/eurjchem.4.3.203-206.778

[3]. Shan, J. H.; Liu, Y. P.; Zhang, J. Y. Chinese J. Chem. 2011, 29(4), 639-642.
http://dx.doi.org/10.1002/cjoc.201190134

[4]. Shan, J. H.; Liu, Y. P.; Shen, H. X.; Zhang, J. Y.; Yang, Y. F. Int. J. Chem. 2011, 3(2), 111-116.
http://dx.doi.org/10.5539/ijc.v3n2p111

[5]. Naik, K. M.; Nandibewoor, S. T. Oxid. Commun. 2012, 35, 545-559.

[6]. Shan, J. H.; Wang, X. Q.; Zhao, N. Chinese J. Chem. 2010, 28(7), 1081-1084.
http://dx.doi.org/10.1002/cjoc.201090189

[7]. Ragunatharaddi, R. H.; Nagaraj, P. S.; Sharanappa, T. N. J. Phys. Org. Chem. 2009, 22(3), 234-240.
http://dx.doi.org/10.1002/poc.1460

[8]. Jayant, I. G.; Sanjeevaraddi, R. S.; Sharanappa, T. N. Catal. Sci. Technol. 2012, 2, 2549-2557.
http://dx.doi.org/10.1039/c2cy20336g

[9]. Shan, J. H.; Liu, H. M.; Huo, S. Y.; Fan, Y.; Shen, S. G. Trans. Met. Chem. 2006, 31, 999-1002.
http://dx.doi.org/10.1007/s11243-006-0099-9

[10]. Shan, J. H.; Shen, H. X.; Song, C. Y.; Wang, H. Y.; Wang, X. Q. Chem. J. Inter. 2009, 11(3),10

[11]. Shan, J. H.; Wei, H. Y.; Wang, L.; Liu, B. S.; Shen, S. G.; Sun, H. W. Indian J. Chem. 2001, 40(A), 865-869.

[12]. Shan, J. H.; Shen, H. X.; Wang, H. Y.; Wang, X. Q. Oxid. Commun. 2012, 35(3), 583-390.

[13]. Yang, C. Y.; Zhang, Z. J.; Wang, J. L. Microchim. Acta 2009, 167, 91-96.
http://dx.doi.org/10.1007/s00604-009-0223-6

[14]. Chandraiah, U.; Murthy, C. P.; Sushama, Indian J. Chem. 1989, 28(A), 162-164.

[15]. Murthy, C. P.; Sethuram, B.; Rao, T. N. Z. Phys. Chem. (Leipzig) 1986, 267, 1212-1218.

[16]. Mahesh, R. T.; Pol, P. D.; Nandibewoor, S. T. Monatsh. Chem. 2003, 134, 1341-1352.
http://dx.doi.org/10.1007/s00706-003-0608-x

[17]. Aveston, J. J. Chem. Soc. 1969, A, 273-275.

[18]. Crouthamel, C. E.; Meek, H. V.; Martin, D. S. J. Am. Chem. Soc. 1949, 71, 3031-3035
http://dx.doi.org/10.1021/ja01177a026

[19]. Crouthamel, C. E.; Hayes, A. M.; Martin, D. S. J. Am. Chem. Soc. 1951, 73, 82-87
http://dx.doi.org/10.1021/ja01145a030

[20]. Mukherjee, H. G.; Mandal, B.; De, S. Indian J. Chem. 1984, 23(A), 426-428.

[21]. Shan, J. H.; Liu, T. Y. Acta Chim. Sinica 1994, 52, 114.

[22]. Keerti, M. N.; Sharanappa, T. N. J. Sulfur. Chem. 2011, 32(2), 123-136.
http://dx.doi.org/10.1080/17415993.2011.554836

[23]. Feigl, F. Spot Tests in organic analysis, Elsevier Publishing Co., New York, NY, USA, 1956.


How to cite


Shan, J.; Zhang, Z. Eur. J. Chem. 2014, 5(2), 237-240. doi:10.5155/eurjchem.5.2.237-240.981
Shan, J.; Zhang, Z. The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study. Eur. J. Chem. 2014, 5(2), 237-240. doi:10.5155/eurjchem.5.2.237-240.981
Shan, J., & Zhang, Z. (2014). The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study. European Journal of Chemistry, 5(2), 237-240. doi:10.5155/eurjchem.5.2.237-240.981
Shan, Jinhuan, & Ziwei Zhang. "The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study." European Journal of Chemistry [Online], 5.2 (2014): 237-240. Web. 21 Nov. 2019
Shan, Jinhuan, AND Zhang, Ziwei. "The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study" European Journal of Chemistry [Online], Volume 5 Number 2 (30 June 2014)

DOI Link: https://doi.org/10.5155/eurjchem.5.2.237-240.981

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