Synthesis, characterization and antibacterial activity of nickel (II) and        copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide

Sohail Saeed; Naghmana Rashid; Muhammad Ali; Rizwan Hussain

doi:10.5155/eurjchem.1.3.200-205.120

European Journal of Chemistry 2010, 1(3), 200-205 | doi: https://doi.org/10.5155/eurjchem.1.3.200-205.120 | Get rights and content

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Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide

Sohail Saeed ^(1,*)

, Naghmana Rashid ⁽²⁾

, Muhammad Ali ⁽³⁾

, Rizwan Hussain ⁽⁴⁾

⁽¹⁾ Department of Chemistry, Research Complex, Allama Iqbal Open University, Islamabad, 44000, Pakistan
⁽²⁾ Department of Chemistry, Research Complex, Allama Iqbal Open University, Islamabad, 44000, Pakistan
⁽³⁾ Department of Pharmacy, University of The Punjab, Lahore, 54590, Pakistan
⁽⁴⁾ National Engineering & Scientific Commission, P.O. Box 2801, Islamabad, Pakistan
^(*) Corresponding Author

Received: 21 May 2010 | Revised: 26 Aug 2010 | Accepted: 22 Jul 2010 | Published: 29 Sep 2010 | Issue Date: September 2010

Abstract

Nickel and copper metal complexes of N-(R-carbamothioyl)-4-nitrobenzamide (R = diphenyl and ethylbutyl) were synthesized and characterized by IR, ¹H NMR, mass spectrometry and elemental analysis. The spectroscopic data are consistent with the ligand and the metal complexes containing two O and S chelated ligands. N-(diphenylcarbamothioyl)-4-nitrobenzamide, HL¹, was characterized by a single crystal X-ray diffraction study. It crystallizes in the triclinic space group P with unit cell dimensions of a = 6.8044(4) Å, b = 10.0113(6) Å, c = 13.2365(8) Å, α = 6.8044(4) °, β = 78.171(4) °, γ = 13.2365(8)°, V = 882.43(9) Å³. The ligands coordinate as bidentates yielding essentially neutral complexes of the type [ML₂]. The ligands and complexes were screened for their in vitro antibacterial activities and comparatively the complexes showed greater antibacterial efficacy than the thiourea derivative ligands.

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Editor-in-Chief
European Journal of Chemistry

Keywords

Thiourea derivatives; Transition metal complexes; X-ray structure determination; Phase-transfer catalyst; Antibacterial activity

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DOI: 10.5155/eurjchem.1.3.200-205.120

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How to cite

Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205. doi:10.5155/eurjchem.1.3.200-205.120

Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide. Eur. J. Chem. 2010, 1(3), 200-205. doi:10.5155/eurjchem.1.3.200-205.120

Saeed, S., Rashid, N., Ali, M., & Hussain, R. (2010). Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide. European Journal of Chemistry, 1(3), 200-205. doi:10.5155/eurjchem.1.3.200-205.120

Saeed, Sohail, Naghmana Rashid, Muhammad Ali, & Rizwan Hussain. "Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide." European Journal of Chemistry [Online], 1.3 (2010): 200-205. Web. 3 Oct. 2023

Saeed, Sohail, Rashid, Naghmana, Ali, Muhammad, AND Hussain, Rizwan. "Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamide" European Journal of Chemistry [Online], Volume 1 Number 3 (29 September 2010)

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DOI Link: https://doi.org/10.5155/eurjchem.1.3.200-205.120

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