European Journal of Chemistry

Binding properties of coumarin phthalonitrile derivatives in methanol

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Published: Sep 30, 2015
DOI: https://doi.org/10.5155/eurjchem.6.3.337-341.1271
Keywords:
Selectivity, Stoichiometry, 4-Hydroxycoumarine, Host-Guest Chemistry, Cation binding properties, Coumarin phthalonitriles
Section
Research Article
Issue
Vol. 6 No. 3 (2015): September 2015
Dates
Received 2015-05-13
Accepted 2015-06-20
Published 2015-09-30


Main Article Content

Olfa Naouali
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna-Bizerta, 7021, Tunisia
Besma Mellah
Centre National de Recherches en Sciences des Matériaux Technopôle Borj-Cédria, Soliman, BP73 8020, Tunisie
Rawdha Medyouni
Heterocyclic and Organometallic Chemistry Laboratory, Higher Institute of Environmental Sciences and Technology, University of Carthage, Hammam-Lif, 2050, Tunisia
Naceur Hamdi
Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, 58883, Kingdom of Saudi Arabia
Lassaad Baklouti
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna-Bizerta, 7021, Tunisia

Abstract

The complexation properties of coumarin phthalonitrile derivatives 1-3, towards some transition, heavy and lanthanide metal cations have been investigated in methanol by means of UV spectrophotometry and conductivity experiments. The stoichiometries of the complexes formed and their stability constants were resolved by digital processing of data. A binuclear M2L (M = Metal, L = Ligand) species were formed and the profiles of affinity of ligands 1-3 towards transition metal cations illustrate their selectivity towards Cu2+.


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Naouali, O.; Mellah, B.; Medyouni, R.; Hamdi, N.; Baklouti, L. Binding Properties of Coumarin Phthalonitrile Derivatives in Methanol. Eur. J. Chem. 2015, 6, 337-341.

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