European Journal of Chemistry

One-pot method of synthesis and supercritical carbon dioxide drying of PVdF-HFP composite membranes

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Published: Mar 31, 2016
DOI: https://doi.org/10.5155/eurjchem.7.1.121-127.1361
Keywords:
Li-ion battery, Inorganic fillers, Synthesis design, Sol-gel processes, Supercritical CO2 drying, Composite gel electrolytes
Section
Research Article
Issue
Vol. 7 No. 1 (2016): March 2016
Dates
Received 2015-11-10
Accepted 2015-12-19
Published 2016-03-31


Main Article Content

Agnieszka Martyla
Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
Robert Przekop
Center of Advanced Technologies Adam Mickiewicz University, 89c Umultowska St., 61-614 Poznan, Poland
Monika Osinska-Broniarz
Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
Mariusz Walkowiak
Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
Maciej Kopczyk
Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland

Abstract

This paper describes one-pot method of the synthesis and properties of composite polymer gel electrolytes based on poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-HFP). As the precursor of the inorganic filler tetraethyl orthosilicate (TEOS) and titanium tetra-n-butoxide (Ti(OC4H9)4) were used. The drying of membranes with fillers was carried out with supercritical CO2. The membranes and gel electrolytes have been examined structurally and electrochemically, showing favorable properties in terms of electrolyte uptake and electrochemical characteristics in Li-ion cells.


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Martyla, A.; Przekop, R.; Osinska-Broniarz, M.; Walkowiak, M.; Kopczyk, M. One-Pot Method of Synthesis and Supercritical Carbon Dioxide Drying of PVdF-HFP Composite Membranes. Eur. J. Chem. 2016, 7, 121-127.

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Supporting Agencies

the European Regional Development Fund, project No POIG.01.01.02-00-015/09.
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