European Journal of Chemistry

Liquid-liquid extraction of Zr(IV) from sulphuric acid medium using tri-n-octyl amine in kerosene

Article Sidebar

PDF
Published: Sep 30, 2018
DOI: https://doi.org/10.5155/eurjchem.9.3.222-227.1719
Keywords:
TOA, Stripping, Kerosene, Zirconium, Sulphuric acid, Solvent extraction
Section
Research Article
Issue
Vol. 9 No. 3 (2018): September 2018
Dates
Received 2018-04-21
Accepted 2018-06-19
Published 2018-09-30
Crossmark


Main Article Content

Jaykishon Swain
Department of Chemistry, College of Engineering and Technology, Bhubaneswar-751029, Odisha, India
http://orcid.org/0000-0002-2117-9711
Amit Sahoo
Department of Chemistry, College of Engineering and Technology, Bhubaneswar-751029, Odisha, India
http://orcid.org/0000-0002-7480-658X
Bhikari Charana Bhatta
Department of Chemistry, College of Engineering and Technology, Bhubaneswar-751029, Odisha, India
http://orcid.org/0000-0002-0630-9098

Abstract

The extraction behavior of Zr(IV) with tri-n-octyl amine (TOA) in kerosene was studied through a new method of solvent extraction. The mechanism of extraction and the species extracted were identified. Quantitative extraction of Zr(IV) with TOA in kerosene was studied by changing different parameters such as acid variation, diluent effect, metal concentration variation, extractant variation, effect of salting out reagent concentration and effect of temperature. It was observed that the percentage of extraction of Zr(IV) increased when the concentration of TOA and the percentage of extraction also increased when the metal ion concentration increased. The percentage of Zr(IV) became 97.4% with 0.1 M TOA from 3.0 M sulphuric acid. Kerosene was found to be effective diluent for the extraction of Zr(IV) with TOA.


icon graph This Abstract was viewed 2121 times | icon graph Article PDF downloaded 743 times

How to Cite
(1)
Swain, J.; Sahoo, A.; Bhatta, B. C. Liquid-Liquid Extraction of Zr(IV) from Sulphuric Acid Medium Using Tri-N-Octyl Amine in Kerosene. Eur. J. Chem. 2018, 9, 222-227.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Lide, D. R. CRC Handbook of Chemistry and Physics, 88th edition, Taylor & Francis, 2007.

[2]. Considine, G. D. Van Nostrand's Encyclopedia of Chemistry, Wiley-Interscience, 2005.

[3]. How Products Are Made, Zirconium, (http://www.madehow.com/ Volume-1/Zirconium.html), Advameg Inc., 2007, Date Accessed: 01.05.2018.

[4]. Stwertka, A. A Guide to the Elements, Oxford University Press, 1996.

[5]. Emsley, J. Nature's Building Blocks, Oxford University Press, 2001.

[6]. Lee, D. B. N.; Roberts, M.; Bluchel, C. G.; Odell, R. A. Am. Soc. Artific. Inter. Organs J. 2010, 56, 550-556.
https://doi.org/10.1097/MAT.0b013e3181e73f20

[7]. El-Yamani, I. S.; Farah, M. Y.; El-Aleim, F. A. Talanta 1978, 25, 523-525.
https://doi.org/10.1016/0039-9140(78)80088-5

[8]. Sato, T.; Watanabe, H. Separat. Sci. Tech. 1982, 17, 625-634.
https://doi.org/10.1080/01496398208060262

[9]. Sato, T.; Watanabe, H. J. Inorg. Nucl. Chem. 1974, 36, 2585-2589.
https://doi.org/10.1016/0022-1902(74)80476-8

[10]. Schrotterova, D.; Nekovar, P.; Mrnka, M. J. Radioanal. Nucl. Chem. 1991, 150, 325-333.
https://doi.org/10.1007/BF02035319

[11]. Das, N. R.; Nandi, B.; Bhattacharya, S. N. Int. J. Appl. Rad. Isot. 1981, 32, 205-209.
https://doi.org/10.1016/0020-708X(81)90050-8

[12]. Juang, R. S.; Lo, R. H. J. Chem. Tech. Biotech. 1993, 58, 261-269.
https://doi.org/10.1002/jctb.280580309

[13]. Chen, S.; Zhang, Z.; Kuang, S.; Li, Y.; Huang, X. Hydrometallurgy 2017, 169, 607-611.
https://doi.org/10.1016/j.hydromet.2017.04.001

[14]. Wang, L. Y.; Lee, M. S. Separat. Purif. Tech. 2015, 142, 83-89.
https://doi.org/10.1016/j.seppur.2015.01.001

[15]. Das, N. R.; Lahiri, S. J. Radioanal. Nucl. Chem. 1994, 181, 157-164.
https://doi.org/10.1007/BF02037556

[16]. Biswas, S.; Basu, S. J. Radioanal. Nucl. Chem. 1999, 242, 253-258.
https://doi.org/10.1007/BF02345549

[17]. Reddy, B. R.; Kumar, J. R.; Reddy, A. V. Japan Soc. Anal. Chem. 2004, 20, 501-505.

[18]. Das, N. R.; Lahiri, S. Anal. Sci. 1992, 8, 317-322.
https://doi.org/10.2116/analsci.8.317

[19]. El-Yamani, I.; Farah, M.; Aleim, F. E. J. Radioanal. Nucl. Chem. 1978, 45, 125-133.
https://doi.org/10.1007/BF02517116

[20]. Cerrai, E.; Testa, C. Energ. Nucl. 1959, 6, 768-770.

[21]. Ezaz, M. Anal. Chem. 1976, 48, 1158-1161.
https://doi.org/10.1021/ac50002a024

[22]. Reddy, B. R.; Priya, D. N.; Kumar, J. R. Hydrometallurgy 2004, 74, 277-283.
https://doi.org/10.1016/j.hydromet.2004.06.001

[23]. Huang, X.; Li, J.; Long, Z.; Zhang, Y.; Xue, X.; Zhu, Z. J. Rare Earths 2008, 26, 410-413.
https://doi.org/10.1016/S1002-0721(08)60107-6

[24]. Onishi, H.; Sekine, K. Talanta 1972, 19, 473-478.
https://doi.org/10.1016/0039-9140(72)80108-5

[25]. Taghizadeh, M.; Ghanadi, M.; Zolfonoun, E. J. Nucl. Mater. 2011, 412, 334-337.
https://doi.org/10.1016/j.jnucmat.2011.03.033

[26]. Reddy, B. R.; Kumar, J. R.; Reddy, A. V; Priya, D. N. Hydrometallurgy 2004, 72, 303-307.
https://doi.org/10.1016/j.hydromet.2003.07.002

[27]. Yamani, I. S. E.; Aleim, F. A. A. E. J. Radioanal. Nucl. Chem. 1985, 88, 201-208.
https://doi.org/10.1007/BF02036996

Supporting Agencies

College of Engineering and Technology, Bhubaneswar-751029, Odisha, India.
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).