European Journal of Chemistry 2022, 13(3), 273-278 | doi: https://doi.org/10.5155/eurjchem.13.3.273-278.2273 | Get rights and content

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Liquid-liquid extraction of zirconium(IV) from sulphuric acid medium using a binary mixture of tri-n-octylamine and Cyanex923 in kerosene


Amit Sahoo (1) orcid , Jaykishon Swain (2) orcid , Bhikari Charana Bhatta (3,*) orcid

(1) Department of Chemistry, Odisha University of Technology and Research, Techno Campus, Mahalaxmivihar, Bhubaneswar-751029, Odisha, India
(2) Department of Chemistry, Odisha University of Technology and Research, Techno Campus, Mahalaxmivihar, Bhubaneswar-751029, Odisha, India
(3) Department of Chemistry, Odisha University of Technology and Research, Techno Campus, Mahalaxmivihar, Bhubaneswar-751029, Odisha, India
(*) Corresponding Author

Received: 11 Mar 2022 | Revised: 04 May 2022 | Accepted: 07 May 2022 | Published: 30 Sep 2022 | Issue Date: September 2022

Abstract


The extraction behaviour of zirconium(IV) from sulfuric acid medium has been studied with a binary mixture of tri-n-octyl amine (TOA) and Cyanex923 (a mixture of four trialkyl phosphine oxides) in kerosene using a novel liquid-liquid extraction method. Quantitative extraction of zirconium(IV) with binary mixture of Cyanex923 and TOA in kerosene was studied by changing different parameters such as acid variation, extractant variation, effect of chloride ion concentration, effect of temperature, metal concentration variation, diluent effect, and pH effect. The percentage of extraction of zirconium(IV) decreased when the concentration of Cyanex923 and TOA increased. The percentage of zirconium(IV) was observed as  97.56% in a binary mixture of 0.007 M Cyanex923 and 0.06 M TOA. Kerosene was found to be an effective diluent for the extraction of zirconium(IV) with 97.56% extraction using a binary mixture of Cyanex923 and TOA. In addition, the stripping of the zirconium(IV) metal ion in the organic phase was also examined.


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Keywords


TOA; Kerosene; Cyanex923; Zirconium(IV); Sulphuric acid; Solvent extraction

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DOI: 10.5155/eurjchem.13.3.273-278.2273

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Funding information


Odisha University of Technology and Research, Techno Campus, Mahalaxmivihar, Bhubaneswar-751029, Odisha, India.

References


[1]. Emsley, J. Nature's building blocks: An A-Z guide to the elements; Oxford University Press: London, England, 2011.

[2]. CRC handbook of chemistry and physics, Zirconium, 90th edition; Lide, D. R., Ed.; 90th ed.; CRC Press: Boca Raton, FL, 2009.

[3]. Stwertka, A. A guide to the elements; 4th ed.; Oxford University Press: New York, NY, 2018.

[4]. Nielsen, R. Zirconium and Zirconium Compounds. Ullmann's Encyclopedia of Industrial Chemistry 2000.
https://doi.org/10.1002/14356007.a28_543

[5]. Lee, D. B. N.; Roberts, M.; Bluchel, C. G.; Odell, R. A. Zirconium: Biomedical and nephrological applications. ASAIO J. 2010, 56, 550-556.
https://doi.org/10.1097/MAT.0b013e3181e73f20

[6]. Reddy, B. R.; Kumar, J. R.; Reddy, A. V. Solvent extraction of zirconium(IV) from acid chloride solutions using LIX 84-IC. Hydrometallurgy 2004, 74, 173-177.
https://doi.org/10.1016/j.hydromet.2004.02.001

[7]. Ma, S.; Yang, F.; Tan, F.; Xie, M.; Yu, S.; Xue, L.; Li, Z.; Hu, T. Highly efficient and selective solvent extraction of zirconium and hafnium from chloride acid solution including amic acid extractant. Sep. Purif. Technol. 2021, 279, 119779.
https://doi.org/10.1016/j.seppur.2021.119779

[8]. El-Yamani, I. Co-extraction and separation of zirconium and hafnium by long-chain amines from sulphate media. Talanta 1978, 25, 523-525.
https://doi.org/10.1016/0039-9140(78)80088-5

[9]. Sato, T.; Watanabe, H. The extraction of zirconium(IV) from sulphuric acid solutions by long-chain aliphatic amines. J. Inorg. Nucl. Chem. 1974, 36, 2585-2589.
https://doi.org/10.1016/0022-1902(74)80476-8

[10]. Sato, T.; Watanabe, H. The extraction of zirconium(IV) from sulfuric acid solutions by long-chain alkyl Quaternary ammonium compound. Sep. Sci. Technol. 1982, 17, 625-634.
https://doi.org/10.1080/01496398208060262

[11]. Chen, S.; Zhang, Z.; Kuang, S.; Li, Y.; Huang, X.; Liao, W. Separation of zirconium from hafnium in sulfate medium using solvent extraction with a new reagent BEAP. Hydrometallurgy 2017, 169, 607-611.
https://doi.org/10.1016/j.hydromet.2017.04.001

[12]. Juang, R.-S.; Lo, R.-H. Equilibrium studies of the extraction of zirconium(IV) from sulfuric acid solutions with Di(2-ethylhexyl) phosphoric acid. J. Chem. Technol. Biotechnol. 2007, 58, 261-269.
https://doi.org/10.1002/jctb.280580309

[13]. Botelho Junior, A. B.; Espinosa, D. C. R.; Tenório, J. A. S. Selective separation of Sc(III) and Zr(IV) from the leaching of bauxite residue using trialkylphosphine acids, tertiary amine, tri-butyl phosphate and their mixtures. Sep. Purif. Technol. 2021, 279, 119798.
https://doi.org/10.1016/j.seppur.2021.119798

[14]. Schrötterová, D.; Nekovář, P.; Mrnka, M. Extraction of zirconium(IV) from sulfuric acid solutions with amines and mathematical simulation of extraction processes. J. Radioanal. Nucl. Chem. 1991, 150, 325-333.
https://doi.org/10.1007/BF02035319

[15]. Wang, L. Y.; Lee, M. S. Separation of Zr and Hf from sulfuric acid solutions with amine-based extractants by solvent extraction. Sep. Purif. Technol. 2015, 142, 83-89.
https://doi.org/10.1016/j.seppur.2015.01.001

[16]. Das, N. R.; Lahiri, S. Liquid-liquid extraction of trace level zirconium and hafnium with trioctylamine. J. Radioanal. Nucl. Chem. 1994, 181, 157-164.
https://doi.org/10.1007/BF02037556

[17]. Onishi, H. Spectrophotometric determination of zirconium, uranium, thorium and rare earths with arsenazo III after extractions with thenoyltrifluoroacetone and tri-n-octylamine. Talanta 1972, 19, 473-478.
https://doi.org/10.1016/0039-9140(72)80108-5

[18]. Wu, M.; Xu, F.; Dong, P.; Wu, H.; Zhao, Z.; Wu, C.; Chi, R.; Xu, Z. Process for synergistic extraction of Hf(IV) over Zr(IV) from thiocyanic acid solution with TOPO and N1923. Chem. Eng. Process. 2022, 170, 108673.
https://doi.org/10.1016/j.cep.2021.108673

[19]. Das, N. R.; Lahiri, S. Liquid-liquid extraction of trace level niobium and tantalum by trioctylamine. Anal. Sci. 1992, 8, 317-322.
https://doi.org/10.2116/analsci.8.317

[20]. Patkar, S. N.; Patil, R. J. Liquid-liquid extraction and separation of bismuth (iii) with synergistic mixture of N-N-octylaniline and trioctylamine as an extractant from thiocyanate media. Inter. J. Pharma. Chem. Sci. 2012, 1 (2), 747-755. https://ijpcsonline.com/files/files/36-116.pdf (accessed May 1, 2022).

[21]. Ejaz, M. N-Oxides of 4-(5-nonyl)pyridine and trioctylamine as extractants for zirconium from uranium and fission product nuclides. Anal. Chem. 1976, 48, 1158-1161.
https://doi.org/10.1021/ac50002a024

[22]. Nayl, A. A.; El-Nadi, Y. A.; Daoud, J. A. Extraction and separation of Zr(IV) and Hf(IV) from nitrate medium by some CYANEX extractants. Sep. Sci. Technol. 2009, 44, 2956-2970.
https://doi.org/10.1080/01496390903014169

[23]. Conradie, E. W.; Westhuizen, D. J. V. D.; Nel, J. T.; Krieg, H. M. The hafnium-selective extraction fom a zirconium(hafnium) heptafluoride ammonium solution using organophosphorus-based extractants. Solvent Extr. Ion Exch. 2018, 36, 658-673.
https://doi.org/10.1080/07366299.2018.1510812

[24]. Taghizadeh, M.; Ghanadi, M.; Zolfonoun, E. Separation of zirconium and hafnium by solvent extraction using mixture of TBP and Cyanex 923. J. Nucl. Mater. 2011, 412, 334-337.
https://doi.org/10.1016/j.jnucmat.2011.03.033

[25]. Gupta, B.; Malik, P.; Mudhar, N. Extraction and recovery of zirconium from zircon using cyanex 923. Solvent Extr. Ion Exch. 2005, 23, 345-357.
https://doi.org/10.1081/SEI-200050005


How to cite


Sahoo, A.; Swain, J.; Bhatta, B. Eur. J. Chem. 2022, 13(3), 273-278. doi:10.5155/eurjchem.13.3.273-278.2273
Sahoo, A.; Swain, J.; Bhatta, B. Liquid-liquid extraction of zirconium(IV) from sulphuric acid medium using a binary mixture of tri-n-octylamine and Cyanex923 in kerosene. Eur. J. Chem. 2022, 13(3), 273-278. doi:10.5155/eurjchem.13.3.273-278.2273
Sahoo, A., Swain, J., & Bhatta, B. (2022). Liquid-liquid extraction of zirconium(IV) from sulphuric acid medium using a binary mixture of tri-n-octylamine and Cyanex923 in kerosene. European Journal of Chemistry, 13(3), 273-278. doi:10.5155/eurjchem.13.3.273-278.2273
Sahoo, Amit, Jaykishon Swain, & Bhikari Charana Bhatta. "Liquid-liquid extraction of zirconium(IV) from sulphuric acid medium using a binary mixture of tri-n-octylamine and Cyanex923 in kerosene." European Journal of Chemistry [Online], 13.3 (2022): 273-278. Web. 3 Dec. 2022
Sahoo, Amit, Swain, Jaykishon, AND Bhatta, Bhikari. "Liquid-liquid extraction of zirconium(IV) from sulphuric acid medium using a binary mixture of tri-n-octylamine and Cyanex923 in kerosene" European Journal of Chemistry [Online], Volume 13 Number 3 (30 September 2022)

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European Journal of Chemistry 2022, 13(3), 273-278 | doi: https://doi.org/10.5155/eurjchem.13.3.273-278.2273 | Get rights and content

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