Application of calixpyrrole modified silica for the removal of 4-chlorophenol from aqueous media

Ismail Ibrahim Abbas; Bassem Mohamad Riad El Hamaoui; Hilal Mohamad Jamal Najmeddine

doi:10.5155/eurjchem.10.2.156-165.1846

PDF

Published: Jun 30, 2019

DOI: https://doi.org/10.5155/eurjchem.10.2.156-165.1846

Keywords:

Kinetics, Extraction, Chlorophenol, Column studies, Thermodynamics, Calixpyrrole modified silica

Section

Research Article

Issue

Vol. 10 No. 2 (2019): June 2019

Dates

Received 2019-03-09
Accepted 2019-05-15
Published 2019-06-30

Ismail Ibrahim Abbas

Laboratory of Analysis of Organic Compounds, Faculty of Sciences I, Lebanese University, Hadath, Beirut, 1500, Lebanon

http://orcid.org/0000-0002-7591-2296

Bassem Mohamad Riad El Hamaoui

Laboratory of Applied Chemistry, Faculty of Science III, Lebanese University, Tripoli, 1300, Lebanon

http://orcid.org/0000-0002-4680-7227

Hilal Mohamad Jamal Najmeddine

Department of Chemistry, Faculty of Science, Beirut Arab University, Tripoli, 1300, Lebanon

http://orcid.org/0000-0002-1676-9370

Abstract

In this research, calixpyrrole modified silica (III) was synthesized and characterized by Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) techniques. The synthesized material was used as an extractant for the removal of 4-chlorophenol from aqueous solution. Its efficiency was examined through both batch and column extraction methods. The effects of temperature, pH, initial chlorophenol concentration and mass of the adsorbent were examined using removal efficiencies. Initial concentration and quantity of adsorbent show a noticeable influence on the uptake capacity of the adsorbent. The kinetics and thermodynamics of chlorophenol removal from aqueous media were also investigated. Kinetic studies indicated that the extraction data can be best represented by pseudo second order model. Column extraction data were analyzed through Thomas, Yoon-Nelson and Yan et al. models to calculate kinetic coefficients and maximum sorption capacity of the modified silica (III). The adsorbent silica was regenerated by acid treatment without changing its properties.

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(1)

Abbas, I. I.; El Hamaoui, B. M. R.; Najmeddine, H. M. J. Application of Calixpyrrole Modified Silica for the Removal of 4-Chlorophenol from Aqueous Media. Eur. J. Chem. 2019, 10, 156-165.

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