Calix[4]pyrrole macrocycle: Extraction of fluoride anions from aqueous media

Ismail Ibrahim Abbas; Hassan Hasan Hammud; Hasan Shamsaldeen

doi:10.5155/eurjchem.3.2.156-162.542

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Published: Jun 30, 2012

DOI: https://doi.org/10.5155/eurjchem.3.2.156-162.542

Keywords:

Langmuir, Freundlich, Extraction, Fluoride anion, Calix[4]pyrrole, Dubbin-Redushkevich isotherm

Section

Research Article

Issue

Vol. 3 No. 2 (2012): June 2012

Dates

Received 2011-11-01
Accepted 2012-01-04
Published 2012-06-30

Ismail Ibrahim Abbas

Department of Chemistry, Faculty of Science, Beirut Arab University, Beirut, 115020, Lebanon

Hassan Hasan Hammud

Department of Chemistry, Faculty of Science, Beirut Arab University, Beirut, 115020, Lebanon

Hasan Shamsaldeen

Department of Chemistry, Faculty of Science, Beirut Arab University, Beirut, 115020, Lebanon

Abstract

Solid-phase extraction of fluoride anions by calixpyrrole macrocycle (CP) from aqueous media has been studied using the batch method. Various significant extraction parameters like initial concentration of the anion, extraction time, concentration of the calixpyrrole, pH and temperature were evaluated. Langmuir, Freundlichand, Dubinin-Redushkevish (D-R) isotherms and coefficients were used to analyze the equilibrium data. The amount of fluoride anion extracted per unit of the CP was found to be 0.40 mg/g at 298 K from 19 mg/L aqueous solution of fluoride anions. The mean free energy calculated from D-R model for the removal of fluoride anions by the CP was found to be 10.0 kJ/mol, indicating that chemisorption is involved in the extraction process. The data were also fitted to kinetic models such as pseudo first order and pseudo second order. The removal of fluoride anions increased with increasing temperature indicating the endothermic nature of the extraction process. The present method has been compared with the previous methods.

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Abbas, I. I.; Hammud, H. H.; Shamsaldeen, H. Calix[4]pyrrole Macrocycle: Extraction of Fluoride Anions from Aqueous Media. Eur. J. Chem. 2012, 3, 156-162.

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