European Journal of Chemistry

A dimeric oxidovanadium(V) complex derived from a hydrazonate ligand with an unusual asymmetrically bridged μ-(oxido)μ-(H2O){oxidovanadium(V)}2 core

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Published: Mar 31, 2020
DOI: https://doi.org/10.5155/eurjchem.11.1.1-5.1948
Keywords:
Vanadyl, Hydrazones, Insulin mimesis, Crystal structure, Vanadium complexes, Coordination chemistry
Section
Research Article
Issue
Vol. 11 No. 1 (2020): March 2020
Dates
Received 2019-12-15
Accepted 2020-01-17
Published 2020-03-31
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Main Article Content

Alice Prudente Borges
Departamento de Quimica, Universidade Federal do Triangulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440, Uberaba, MG, Brazil
http://orcid.org/0000-0002-6525-1260
Claudia Cristina Gatto
Instituto de Quimica, Universidade de Brasilia, Brasilia, Distrito Federal, Brazil
http://orcid.org/0000-0002-3736-6861
Victor Marcelo Deflon
Instituto de Quimica de Sao Carlos, Universidade de Sao Paulo, Av. Trabalhador Sao Carlense, 400, 13566-590, Sao Carlos, SP, Brazil
http://orcid.org/0000-0002-5368-6486
Pedro Ivo da Silva Maia
Departamento de Quimica, Universidade Federal do Triangulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440, Uberaba, MG, Brazil
http://orcid.org/0000-0003-4699-9481

Abstract

The binuclear oxidovanadium(V) complex [{VO(L)}2(μ-O)(μ-H2O)]∙2CH3CN (1), where L2– is the dianion of the Schiff base 2-salicylaldehyde-2-hydroxybenzoylhydrazone, were prepared and characterized by elemental analysis, FTIR, 1H, 13C and 51V NMR. Furthermore, the crystal structure of the compound 1 was determined by single crystal X-ray diffractometry revealing a distorted octahedral O5N-coordination geometry around the V(V) acceptor centers. The vanadium ions are connected by the μ-O2– and the μ-H2O asymmetric bridges located in the edge between the two octahedrons which keeps a distance of 3.194 Å between the two vanadium centers. Crystal data for C32H28N6O10V2 (M =758.48 g/mol): orthorhombic, space group P212121 (no. 19), a = 12.9655(8) Å, b = 14.1902(9) Å, c = 18.4379(10) Å, V = 3392.3(4) Å3, Z = 4, T = 293(2) K, μ(MoKα) = 0.616 mm-1, Dcalc = 1.485 g/cm3, 18803 reflections measured (3.622° ≤ 2Θ ≤ 56.704°), 8263 unique (Rint = 0.0473, Rsigma = 0.1020) which were used in all calculations. The final R1 was 0.0509 (I > 2σ(I)) and wR2 was 0.1531 (all data). The (VO)2(μ-O)(μ-H2O) core in compound 1 represents a rare case and few examples of similar type have been structurally characterized.


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Borges, A. P.; Gatto, C. C.; Deflon, V. M.; Maia, P. I. da S. A Dimeric oxidovanadium(V) Complex Derived from a Hydrazonate Ligand With an Unusual Asymmetrically Bridged μ-(oxido)μ-(H2O){oxidovanadium(V)}2 Core. Eur. J. Chem. 2020, 11, 1-5.

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Supporting Agencies

Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Fundacao de Amparo a Pesquisa do Estado de Minas Gerais (FAPEMIG) and Fundacao de Amparo a Pesquisa de Sso Paulo (FAPESP).
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