European Journal of Chemistry

A dimeric oxidovanadium(V) complex derived from a hydrazonate ligand with an unusual asymmetrically bridged μ-(oxido)μ-(H2O){oxidovanadium(V)}2 core

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Published: Mar 31, 2020
DOI: https://doi.org/10.5155/eurjchem.11.1.1-5.1948
Keywords:
Vanadyl, Hydrazones, Insulin mimesis, Crystal structure, Vanadium complexes, Coordination chemistry
Section
Research Article
Issue
Vol. 11 No. 1 (2020): March 2020
Dates
Received 2019-12-15
Accepted 2020-01-17
Published 2020-03-31
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Main Article Content

Alice Prudente Borges
Departamento de Quimica, Universidade Federal do Triangulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440, Uberaba, MG, Brazil
http://orcid.org/0000-0002-6525-1260
Claudia Cristina Gatto
Instituto de Quimica, Universidade de Brasilia, Brasilia, Distrito Federal, Brazil
http://orcid.org/0000-0002-3736-6861
Victor Marcelo Deflon
Instituto de Quimica de Sao Carlos, Universidade de Sao Paulo, Av. Trabalhador Sao Carlense, 400, 13566-590, Sao Carlos, SP, Brazil
http://orcid.org/0000-0002-5368-6486
Pedro Ivo da Silva Maia
Departamento de Quimica, Universidade Federal do Triangulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440, Uberaba, MG, Brazil
http://orcid.org/0000-0003-4699-9481

Abstract

The binuclear oxidovanadium(V) complex [{VO(L)}2(μ-O)(μ-H2O)]∙2CH3CN (1), where L2– is the dianion of the Schiff base 2-salicylaldehyde-2-hydroxybenzoylhydrazone, were prepared and characterized by elemental analysis, FTIR, 1H, 13C and 51V NMR. Furthermore, the crystal structure of the compound 1 was determined by single crystal X-ray diffractometry revealing a distorted octahedral O5N-coordination geometry around the V(V) acceptor centers. The vanadium ions are connected by the μ-O2– and the μ-H2O asymmetric bridges located in the edge between the two octahedrons which keeps a distance of 3.194 Å between the two vanadium centers. Crystal data for C32H28N6O10V2 (M =758.48 g/mol): orthorhombic, space group P212121 (no. 19), a = 12.9655(8) Å, b = 14.1902(9) Å, c = 18.4379(10) Å, V = 3392.3(4) Å3, Z = 4, T = 293(2) K, μ(MoKα) = 0.616 mm-1, Dcalc = 1.485 g/cm3, 18803 reflections measured (3.622° ≤ 2Θ ≤ 56.704°), 8263 unique (Rint = 0.0473, Rsigma = 0.1020) which were used in all calculations. The final R1 was 0.0509 (I > 2σ(I)) and wR2 was 0.1531 (all data). The (VO)2(μ-O)(μ-H2O) core in compound 1 represents a rare case and few examples of similar type have been structurally characterized.


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Borges, A. P.; Gatto, C. C.; Deflon, V. M.; Maia, P. I. da S. A Dimeric oxidovanadium(V) Complex Derived from a Hydrazonate Ligand With an Unusual Asymmetrically Bridged μ-(oxido)μ-(H2O){oxidovanadium(V)}2 Core. Eur. J. Chem. 2020, 11, 1-5.

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References

[1]. Belokon, Y. N.; Clegg, W.; Harrington, R. W.; Young, C.; North, M. Tetrahedron 2007, 63, 5287-5299.
https://doi.org/10.1016/j.tet.2007.03.140

[2]. Kwiatkowski, E.; Romanowski, G.; Nowicki, W.; Kwiatkowski, M.; Suwinska, K. Polyhedron 2007, 26, 2559-2568.
https://doi.org/10.1016/j.poly.2006.12.032

[3]. Alvarez, H. M.; Andrade, J. L.; Pereira, N.; Muri, E. M. F.; Horn, A.; Barbosa, D. P.; Antunes, O. A. C. Catal. Commun. 2007, 8, 1336-1340.
https://doi.org/10.1016/j.catcom.2006.11.021

[4]. Langeslay, R. R.; Kaphan, D. M.; Marshall, C. L.; Stair, P. C.; Sattelberger, A. P.; Delferro, M. Chem. Rev. 2019, 119, 2128-2191.
https://doi.org/10.1021/acs.chemrev.8b00245

[5]. Sundararajan, M.; Park, B.; Baik. M. H. Inorg. Chem. 2019, 58, 16250-16255.
https://doi.org/10.1021/acs.inorgchem.9b02803

[6]. Adao, P.; Pessoa, J. C.; Henriques, R. T.; Kuznetsov, M. L.; Avecilla, F.; Maurya, M. R.; Kumar, U.; Correia, I. Inorg. Chem. 2009, 48, 3542-3561.
https://doi.org/10.1021/ic8017985

[7]. Thakur, S.; Banerjee, S.; Das, S.; Chattopadhyay, S. New J. Chem. 2019, 43, 18747-18759.
https://doi.org/10.1039/C9NJ04672K

[8]. Maurya, M. R.; Agarwal, S.; Bader, C.; Ebel, M.; Rehder, D. Dalton Trans. 2005, 537-544.
https://doi.org/10.1039/b416292g

[9]. Crans, D. C.; Smee, J. J.; Gaidamauskas, E.; Yang, L. Chem. Rev. 2004, 104, 849-902.
https://doi.org/10.1021/cr020607t

[10]. Rehder, D. Inorg. Chem. Commun. 2003, 6, 604-617.
https://doi.org/10.1016/S1387-7003(03)00050-9

[11]. Sakurai, H.; Kojima, Y.; Yoshikawa, Y.; Kawabe, K.; Yasui, H. Coord. Chem. Rev. 2002, 226, 187-198.
https://doi.org/10.1016/S0010-8545(01)00447-7

[12]. Maia, P. I. S.; Deflon, V. M.; Sousa, G. F.; Lemos, S. S.; Batista, A. A.; Nascimento, O. R.; Niquet, E.; Anorg, Z. Allg. Chem. 2007, 633, 783-789.
https://doi.org/10.1002/zaac.200600396

[13]. Bastos, A. M. B.; Silva, J. G.; Maia, P. I. S.; Deflon, V. M.; Batista, A. A.; Ferreira, A. V. M.; Botion, L. M.; Niquet, E.; Beraldo, H. Polyhedron 2008, 27, 1787-1794.
https://doi.org/10.1016/j.poly.2008.02.014

[14]. Crans, D. C.; Gambino, D.; Etcheverryc, S. B. New J. Chem. 2019, 43, 17535-17537.
https://doi.org/10.1039/C9NJ90156F

[15]. Maia, P. I. S.; Pavan, F. R.; Leite, C. Q. F.; Lemos, S. S.; de Sousa, G. F.; Batista, A. A.; Nascimento, O. R.; Ellena, J.; Castellano, E. E.; Niquet, E.; Deflon, V. M. Polyhedron 2009, 28, 398-406.
https://doi.org/10.1016/j.poly.2008.11.017

[16]. Zabin, S. A.; Abdelbaset, M. Eur. J. Chem. 2016, 7(3), 322‐328.
https://doi.org/10.5155/eurjchem.7.3.322-328.1444

[17]. Sutradhar, M.; Mukherjee, G.; Drew, M. G. B.; Ghosh, S. Inorg. Chem. 2006, 45, 5150-5161.
https://doi.org/10.1021/ic051120g

[18]. Pohlmann, A.; Nica, S.; Luong, T. K. K.; Plass, W. Inorg. Chem. Commun. 2005, 8, 289-292.
https://doi.org/10.1016/j.inoche.2004.12.028

[19]. Maurya, M. R.; Agarwal, S.; Abid, M.; Azam, A.; Bader, C.; Ebel, M.; Rehder, D. Dalton Trans. 2006, 937-947.
https://doi.org/10.1039/B512326G

[20]. Maia, P. I. S.; Deflon, V. M.; Souza, E. J.; Garcia, E.; Sousa, G. F.; Batista, A. A.; Figueiredo, A. T.; Niquet, E. Transit. Met. Chem. 2005, 30, 404-410.
https://doi.org/10.1007/s11243-004-6972-5

[21]. Datta, R.; Vittalacharya, R.; Gudennavar, B. S. Eur. J. Chem. 2014, 5(3), 394‐396.
https://doi.org/10.5155/eurjchem.5.3.394-396.1043

[22]. Rahman, V. P. M.; Mukhtar, S.; Ansari, W. H.; Lemiere, G. Eur. J. Med. Chem. 2005, 40, 173-184.
https://doi.org/10.1016/j.ejmech.2004.10.003

[23]. Dinda, R.; Sengupta, P.; Ghosh, S.; Mak, T. C. W. Inorg. Chem. 2002, 41, 1684-1688.
https://doi.org/10.1021/ic010865t

[24]. Gruning, C.; Schmidt, H.; Rehder, D. Inorg. Chem. Commun. 1999, 2, 57-59.
https://doi.org/10.1016/S1387-7003(99)00009-X

[25]. Schmidt, H.; Bashirpoor, M.; Rehder, D. J. Chem. Soc., Dalton Trans. 1996, 3865-3870.
https://doi.org/10.1039/dt9960003865

[26]. Maurya, M. R.; Kumar, A.; Abid, M.; Azam, A. Inorg. Chim. Acta. 2006, 359, 2439-2447.
https://doi.org/10.1016/j.ica.2006.02.032

[27]. Deflon, V. M.; Oliveira, D. M.; Sousa, G. F.; Batista, A. A.; Dinelli, L. R.; Castellano, E. Anorg. Z. Allg. Chem. 2002, 628, 1140-1144.

[28]. Xu, G.; Xia, Q. H.; Lu, X. H.; Zhang, Q.; Zhan, H. J. J. Mol. Catal. A: Chem. 2007, 266, 180-187.
https://doi.org/10.1016/j.molcata.2006.10.052

[29]. Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.

[30]. Sheldrick, G. M. SHELXL-2016, Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 2016.

[31]. Vijayan, J. G. Eur. J. Chem. 2017, 8(4), 328‐332.
https://doi.org/10.5155/eurjchem.8.4.328-332.1571

[32]. Souza, P. C.; Maia, P. I. S.; Barros, H. B.; Leite, C. Q. F.; Deflon, V. M.; Pavan, F. R. Curr. Clin. Pharmacol. 2015, 10(1), 66-72.
https://doi.org/10.2174/1574884708666131229124748

Supporting Agencies

Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Fundacao de Amparo a Pesquisa do Estado de Minas Gerais (FAPEMIG) and Fundacao de Amparo a Pesquisa de Sso Paulo (FAPESP).
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