European Journal of Chemistry

Kinetic modeling of the biodiesel production process using neem seed oil: An alternative to petroleum-diesel

Crossmark


Main Article Content

Toyese Oyegoke
Kazeem Ajadi Ibraheem

Abstract

Promoting the green technology campaign that would actualize a biorefinery establishment and would promote cleaner fuel production and air in our environment. This study carried out kinetics studies of biodiesel production over a mixed oxide, Ca-Mg-O catalyst, providing relevant kinetics parameters. This study indicated that biodiesel production is a zero-order reaction, a process independent of the concentration. The results obtained from this study confirm the activation energy, Ea, of the reaction to be 406.53 J/mol, while the pre-exponential factor A was found to be 0.01618 1/min (or 0.9 1/h). Other are kinetics models that were developed for the prediction of the reaction kinetics for the production process is also reported in this study. The findings reported in this study would go a long way to facilitate the modeling, simulation, and design of the biodiesel production process.


icon graph This Abstract was viewed 853 times | icon graph Article PDF downloaded 415 times

How to Cite
(1)
Oyegoke, T.; Ibraheem, K. A. Kinetic Modeling of the Biodiesel Production Process Using Neem Seed Oil: An Alternative to Petroleum-Diesel. Eur. J. Chem. 2021, 12, 242-247.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Oyegoke, T.; Dabai, F. Niger. J. Technol. 2018, 37 (4), 913-920.
https://doi.org/10.4314/njt.v37i4.8

[2]. Ajayi, O. O.; Onifade, K. R.; Onadeji, A.; Oyegoke, T. J. Eng. Stud. Res. 2020, 26, 154-164. http://jesr.ub.ro/1/article/view/219/204 (accessed April 8, 2021).

[3]. Ogbonna, C. N.; Okoli, E. C. Afr. J. Biotechnol. 2013, 12 (37), 5618-5626. https://academicjournals.org/journal/AJB/article-full-text-pdf/BD0978826379 (accessed April 8, 2021).

[4]. Abemi, A.; Oyegoke, T.; Dabai, F. N.; Jibril, B. Y. Technical and Economic Feasibility of Transforming Molasses into Bioethanol in Nigeria. Faculty of Engineering National Engineering Conference, Zaria: Ahmadu Bello University; 2018, p. 145.

[5]. Oyegoke, T.; Dabai, F. Niger. J. Technol. 2018, 37 (4), 921-926.
https://doi.org/10.4314/njt.v37i4.9

[6]. Banik, S. K.; Rouf, M. A.; Rabeya, T.; Khanam, M.; Sajal, S. I.; Sabur, S. B.; Islam, M. R. J. Sci. Ind. Res. 2018, 53 (3), 211-218.
https://doi.org/10.3329/bjsir.v53i3.38268

[7]. Umaru, M.; Aberuagba, F. Res. J. Chem. Sci. 2012, 2 (10), 7-12. http://www.isca.in/rjcs/Archives/v2/i10/1.ISCA-RJCS-2012-060.pdf (accessed April 8, 2021).

[8]. Abebe, D. Transesterfication of Neem Seed Oil into Fatty Acid Methyl Ester Using Na2O/CaO Catalyst, Addis Ababa University, 2015. http://etd.aau.edu.et/handle/123456789/10206 (accessed April 8, 2021).

[9]. Athar, M.; Zaidi, S. A. J. Environ. Chem. Eng. 2020, 8 (6), 104523.
https://doi.org/10.1016/j.jece.2020.104523

[10]. Ali, R. F. M. Eur. J. Chem. 2013, 4 (2), 85-91.
https://doi.org/10.5155/eurjchem.4.2.85-91.710

[11]. Krawczyk, T. Inform 1996, 7, 801-829. https://repositorio.fedepalma.org/handle/123456789/82192 (accessed April 8, 2021).

[12]. Muazu, M.; Rabi'u, I.; Issa, S. B. UMYU J. Microbiol. Res. 2020, 5 (1), 86-92. https://www.umyu.edu.ng/ujmr/umyuJV5/14_86%20-%2092_009%20Muhiydeen.pdf (accessed April 8, 2021).

[13]. Oyegoke, T.; Obadiah, E.; Mohammed, Y. S. S.; Bamigbala, O. A.; Owolabi, O. A. O.; Geoffrey, T. T.; Oyegoke, A.; Onadeji, A. Renew. Energ. Res. Appl. 2020. http://rera.shahroodut.ac.ir/article_1921.html (accessed April 8, 2021).

[14]. Oyegoke, T.; Sardauna, M. Y.; Abubakar, H. A.; Obadiah, E. Renew. Energ. Res. Appl. 2020. http://rera.shahroodut.ac.ir/article_1917.html (accessed April 8, 2021).

[15]. Menetrez, M. Y. Environ. Sci. Technol. 2012, 46 (13), 7073-7085.
https://doi.org/10.1021/es300917r

[16]. Shay, E. G. Biomass Bioenergy 1993, 4 (4), 227-242.
https://doi.org/10.1016/0961-9534(93)90080-N

[17]. Ma, F.; Hanna, M. A. Bioresour. Technol. 1999, 70 (1), 1-15.
https://doi.org/10.1016/S0960-8524(99)00025-5

[18]. Oyegoke, A.; Jacob, J. O.; Oyegoke, T. Computational Screening of Selected Metallic Oxides for Carbon Monoxide Capture in Our Environment. International e-Conference on "Sustainability Challenges & Transforming Opportunities: Amidst Covid19" held at S S Khanna Girls College Prayagraj, India, 2020.

[19]. Ibraheem, K. A.; Oyegoke, T.; Geoffrey, T. T.; Abubakar, H. A.; Fasanya, O.; Ojetunde, A. O. Biodiesel production from neem seed oil: catalyst synthesis, the effect of time, and temperature on biodiesel yield. 19th Congress NIMACON: "Innovative Development of Materials For Economic Diversification" held at OAU Ife, Ife: 2020.

[20]. Oyegoke. A.; Jacob, J. O.; Oyegoke, T. Computational study of CO adsorption potential of MgO, SiO2, Al2O3, and Y2O3 using a semi-empirical quantum calculation method. 19th Congress NIMACON: "Innovative Development of Materials For Economic Diversification" held at OAU Ife, Ife: OAU; 2020.

[21]. Živković, S. B.; Veljković, M. V.; Banković-Ilić, I. B.; Krstić, I. M.; Konstantinović, S. S.; Ilić, S. B.; Avramović, J. M.; Stamenković, O. S.; Veljković, V. B. Renew. Sustain. Energy Rev. 2017, 79, 222-247.
https://doi.org/10.1016/j.rser.2017.05.048

[22]. Narasimhan, M.; Chandrasekaran, M.; Govindasamy, S.; Aravamudhan, A. J. Environ. Chem. Eng. 2021, 9 (1), 104876.
https://doi.org/10.1016/j.jece.2020.104876

[23]. Abbah, E. C.; Nwandikom, G. I.; Egwuonwu, C. C.; Nwakuba N. R. Amer. J. Energ. Sci. 2016, 3 (3), 16-20. http://www.openscienceonline.com/journal/archive2?journalId=745&paperId=3402 (accessed April 8, 2021).

[24]. Dianursanti; Delaamira, M.; Bismo, S.; Muharam, Y. IOP Conf. Ser. Earth Environ. Sci. 2017, 55, 012033.
https://doi.org/10.1088/1755-1315/55/1/012033

[25]. Abdulrahman, R. K. Int. J. Eng. Trends Technol. 2017, 44 (4), 186-188.
https://doi.org/10.14445/22315381/IJETT-V44P237

[26]. Toledo Arana, J.; Torres, J. J.; Acevedo, D. F.; Illanes, C. O.; Ochoa, N. A.; Pagliero, C. L. Int. J. Chem. Eng. 2019, 2019, 1806017, 1-7.
https://doi.org/10.1155/2019/1806017

[27]. Ajala, E. O.; Ajala, M. A.; Odetoye, T. E.; Okunlola, A. T. Braz. J. Chem. Eng. 2019, 36 (2), 979-994.
https://doi.org/10.1590/0104-6632.20190362s20180516

[28]. Istiningrum, R. B.; Aprianto, T.; Pamungkas, F. L. U. Effect of Reaction Temperature on Biodiesel Production from Waste Cooking Oil Using Lipase as Biocatalyst. AIP Conference Proceedings, 2017, 1911.
https://doi.org/10.1063/1.5016024

[29]. Bello, E. I.; Daniyan, I. A.; Akinola, A. O.; Ogedengbe, I. T. Res. J. Eng. Appl. Sci. 2013, 2, 182-186. https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.675.1387&rep=rep1&type=pdf (accessed April 8, 2021).

[30]. Yusuf, J. Assessment of pumpkin and balsam apple seed oils as Feedstock for Biodiesel Production. Master Thesis, Ahmadu Bello University Zaria, 2017.

[31]. Oladipo, B.; Ojumu, T. V.; Latinwo, L. M.; Betiku, E. Energies 2020, 13 (21), 5834.
https://doi.org/10.3390/en13215834

[32]. Triyono, T. Indones. J. Chem. 2010, 4 (1), 1-5.
https://doi.org/10.22146/ijc.21867

[33]. Nishiyama, M.; Kleijn, S.; Aquilanti, V.; Kasai, T. Chem. Phys. Lett. 2009, 482 (4-6), 325-329.
https://doi.org/10.1016/j.cplett.2009.10.005

[34]. Vasilopoulos, Y.; Skořepová, E.; Šoóš, M. Crystals (Basel) 2020, 10 (2), 139.
https://doi.org/10.3390/cryst10020139

[35]. Mamat, F. M. B.; Yacob, A. R. Kinetic study of biodiesel using egg shell for base transesterification reaction, eProceedings Chemistry, 2015, 133-139. http://161.139.21.153/index.php/FYP/article/viewFile/24/pdf (accessed Apr 8, 2021).

[36]. Valenga, M. G. P.; Boschen, N. L.; Rodrigues, P. R. P.; Maia, G. A. R. Ind. Crops Prod. 2019, 128, 331-337.
https://doi.org/10.1016/j.indcrop.2018.11.031

[37]. Callistus, U. N.; Ndidi, A. F.; Okechukwu, O. D.; Patrick, A. E. Int. J. Chem. Mol. Eng. 2016, 10 (6), 739-742.

[38]. Yunus, M. M.; Zuru, A. A. Niger. J. Chem. Res. 2017, 22 (1), 9-19.

Supporting Agencies

Chemical Engineering Department, Faculty of Engineering, Ahmadu Bello University, Zaria 234, Nigeria.
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).