European Journal of Chemistry

Development of a new highly sensitive and selective spectrophotometric method for the determination of selenium at nano-trace levels in various complex matrices using salicylaldehyde-orthoaminophenol

Article Sidebar

PDF
Published: Dec 31, 2021
DOI: https://doi.org/10.5155/eurjchem.12.4.469-481.2137
Keywords:
Soil samples, Biological samples, Environmental samples, Pharmaceutical samples, Selenium determination, Salicylaldehyde-orthoaminophenol
Section
Research Article
Issue
Vol. 12 No. 4 (2021): December 2021
Dates
Received 2021-07-06
Accepted 2021-08-07
Published 2021-12-31
Crossmark


Main Article Content

Muhammad Jamaluddin Ahmed
Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
https://orcid.org/0000-0002-3765-066X
Muhammad Jihan Uddin
Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
https://orcid.org/0000-0001-8929-8971
Muhammad Emdadul Hoque
Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
https://orcid.org/0000-0003-1207-7083

Abstract

A new spectrophotometric reagent, salicylaldehyde-orthoaminophenol (Sal-OAP) has been synthesized and characterized for the determination of selenium through novel reaction techniques. Also, a new highly selective, and sensitive spectrophotometric method for the nano-trace determination of selenium using salicylaldehyde-orthoaminophenol (Sal-OAP) has been developed. Sal-OAP undergoes reaction in a slightly acidic solution (0.0001-0.0002 M H2S04) with selenium (IV) to give an orange-red chelate, which has an absorption maximum at 379 nm. The reaction is instantaneous and absorbance remains stable for over 24 h. The average molar absorption co-efficient and Sandell’s sensitivity were found to be 6.4×105 L/mol.cm and 1.0 ng/cm2 of, respectively. Linear calibration graphs were obtained for 0.001-40.000 mg/Lof Se having detection limit of 0.1 µg/L and RSD 0-2 %. The stoichiometric composition of the chelate is 1:2 (Se:Sal-OAP). A large excess of over 60 cations, anions and some common complexing agents, such as chloride, azide, tartrate, EDTA, SCN¯etc., do not interfere in the determination. The developed method was successfully used in the determination of selenium in several Certified Reference Materials (Alloys, steels, human urine, bovine liver, drinking water, tea, milk, soil, and sediments) as well as in some environmental waters (Potable and polluted), biological fluids (Human blood, urine, hair, and milk), soil samples, food samples (Vegetables, rice, and wheat) and pharmaceutical samples (Tablet and syrup) and solutions containing both selenium (IV) and selenium (VI) as well as complex synthetic mixtures. The results of the proposed method for assessing biological, food and vegetables and soil samples were comparable with ICP-OES and AAS were found to be in excellent agreement. The method has high precision and accuracy (s = ±0.01 for 0.5 mg/L).


icon graph This Abstract was viewed 657 times | icon graph Article PDF downloaded 150 times

How to Cite
(1)
Ahmed, M. J.; Uddin, M. J.; Hoque, M. E. Development of a New Highly Sensitive and Selective Spectrophotometric Method for the Determination of Selenium at Nano-Trace Levels in Various Complex Matrices Using Salicylaldehyde-Orthoaminophenol. Eur. J. Chem. 2021, 12, 469-481.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. U.S. Environmental Protection Agency, Ambient Water Quality Criteria for Selenium. Report No. EPA-440/5-80-070, Criteria and Standards Division, Office of Water Regulations and Standards, Washington, 1980.

[2]. Biochemistry of the Essential Ultratrace Elements; Frieden, E., Ed.; Springer: New York, NY, 2012. https://doi.org/10.1007/978-1-4684-4775-0.
https://doi.org/10.1007/978-1-4684-4775-0

[3]. Selenium http://www.scientificlib.com/en/Chemistry/Elements/Selenium.html (accessed Oct 9, 2021).

[4]. Sacconi, L. J. Am. Chem. Soc. 1953, 75 (21), 5434-5435.
https://doi.org/10.1021/ja01117a519

[5]. Uddin, M. N.; Salam, M. A.; Chowdhury, D. A.; Sultana, J.; Halim, M. E. Inter. J. Adv. Res. Chem. Sci. 2014, 1 (6), 47-56.

[6]. Gudzenko, L. V.; Pantaler, R. P.; Blank, A. B. J. Anal. Chem. 2004, 59 (10), 935-938.
https://doi.org/10.1023/B:JANC.0000043908.94548.0d

[7]. Kartal, S.; Oymak, T.; Tokalioglu, S. J. Anal. Chem. 2010, 65 (12), 1221-1227.
https://doi.org/10.1134/S106193481012004X

[8]. Changjiu, L.; Xiqun, Y.; Jisheng, L. Chinese J. Anal. Chem. 2001, 29 (9), 10-30.

[9]. Ramachandran, K. N.; Kaveeshwar, R.; Gupta, V. K. Talanta 1993, 40 (6), 781-784.
https://doi.org/10.1016/0039-9140(93)80030-U

[10]. Balogh, I. S.; Andruch, V. Chemical Papers 2005, 59 (5), 347-349. https://www.chemicalpapers.com/file_access.php?file=595a347.pdf (accessed Oct 10, 2021).

[11]. Yasser, O. M.; Hamad, A. S.; Ali, M. D. M. J. Appl. Chem. 2013, 2 (5), 1347-1354, http://www.joac.info/ContentPaper/2013/2-36.pdf (accessed Nov 26, 2021).

[12]. Chiranjeevi, P.; Reddy Prasad, P.; Rekha, D.; Dilip Kumar, J.; Krishnapriya, B.; Subramanyam, P. Anal. Chem.: An Indian J. 2007, 3 (4-6), 133-139.

[13]. Aznarez, J.; Castillo, J. R.; Bonilla, A.; Tejedor, J. L. Anales de la Estacion Experimental de Aula Dei 1980, 15 (1-2), 194-203.

[14]. Langmyhr, F. J.; Omang, S. H. Anal. Chim. Acta 1960, 23, 565-568.
https://doi.org/10.1016/S0003-2670(01)81379-9

[15]. Afkhami, A.; Safavi, A.; Massoumi, A. Talanta 1992, 39 (8), 993-996.
https://doi.org/10.1016/0039-9140(92)80284-K

[16]. Chand, V.; Prasad, S. J. Hazard. Mater. 2009, 165 (1-3), 780-788.
https://doi.org/10.1016/j.jhazmat.2008.10.076

[17]. Pathare, M. N.; Sawant, A. D. Anal. Lett. 1995, 28 (2), 317-334.
https://doi.org/10.1080/00032719508000325

[18]. Liu, W.-J.; Yang, G.-T.; Wang, S.-L.; Li, X.-L. Yao Wu Fen Xi Za Zhi 2012, 32 (7), 1179-1182.

[19]. Ahmed, M. D. F. A.; Lingappa, Y. Int. J. Chem. Res. 2011, 46-48.

[20]. Revanasiddappa, H. D.; Kumar, T. N. Anal. Sci. 2001, 17 (11), 1309-1312.
https://doi.org/10.2116/analsci.17.1309

[21]. Dinesh, M.; Naveen, K. G. S.; Harish, K. H.; Prasad, G.; Joshi, H. Unique Res. J. Chem. 2013, 1 (1), 57-58. http://ujconline.net/wp-content/uploads/2013/09/9-URJC-1318-Rs.pdf (accessed Oct 9, 2021).

[22]. Narayana, B.; Mathew, M.; Gopalakrishna Bhat, N.; Sreekumar, N. V. Mikrochim. Acta 2003, 141 (3-4), 175-178.
https://doi.org/10.1007/s00604-002-0936-2

[23]. Li, H.; Zhai, D.; Fan, Y. Rare Metals 2006, 25 (3), 281-286.
https://doi.org/10.1016/S1001-0521(06)60054-5

[24]. Zhengjun, G.; Xinshen, Z.; Guohe, C.; Xinfeng, X. Talanta 2005, 66 (4), 1012-1017.
https://doi.org/10.1016/j.talanta.2005.01.029

[25]. Revanasiddappa, H. D.; Kiran Kumar, T. N. Anal. Bioanal. Chem. 2002, 374 (6), 1121-1124.

[26]. Oktariza, Y.; Putra, O. D.; Insanu, M.; Miftah, A. M. Inter. J. Pharm. Pharma. Sci. 2013, 5 (4), 498-503.

https://innovareacademics.in/journal/ijpps/Vol5Issue4/7731.pdf (accessed Oct 9, 2021).

[27]. Zhou, Z. R.; Zhang, L. Z. Adv. Mat. Res. 2012, 538-541, 2358-2363.
https://doi.org/10.4028/www.scientific.net/AMR.538-541.2358

[28]. Matamoros, A.; Benning, L. G. Mineral. Mag. 2008, 72 (1), 451-454.
https://doi.org/10.1180/minmag.2008.072.1.451

[29]. Songsasen, A.; Aukkarayunyong, P.; Bangkedphol, S.; Sasomsap, W. Agric. Nat. Resour. 2002, 36 (1), 103-109.

[30]. Soruraddin, M. H.; Heydari, R.; Puladvand, M.; Zahedi, M. M. Int. J. Anal. Chem. 2011, 2011, 729651.
https://doi.org/10.1155/2011/729651

[31]. Safavi, A.; Afkhami, A. Anal. Lett. 1995, 28 (6), 1095-1105.
https://doi.org/10.1080/00032719508002681

[32]. Khajehsharifi, H.; Mousavi, M. F.; Ghasemi, J.; Shamsipur, M.. Chim. Acta 2004, 512 (2), 369-373.
https://doi.org/10.1016/j.aca.2004.03.017

[33]. Deepa, K.; Lingappa, Y. Der Pharma Chemica 2014, 6 (1), 52-60.

[34]. Campbell, A. D.; Yahaya, A. H. Anal. Chim. Acta 1980, 119 (1), 171-174.
https://doi.org/10.1016/S0003-2670(00)00045-3

[35]. Bera, B. C.; Chakrabartty, M. M. Analyst 1968, 93, 50-55.
https://doi.org/10.1039/an9689300050

[36]. Kumar, K.; Suvardhan, K.; Krishnaiah, L.; Chiranjeevi, P. Helv. Chim. Acta 2005, 88 (2), 343-348.
https://doi.org/10.1002/hlca.200590018

[37]. Suchocki, P.; Jakoniuk, D.; Fitak, B. A. J. Pharm. Biomed. Anal. 2003, 32 (4-5), 1029-1036.
https://doi.org/10.1016/S0731-7085(03)00205-X

[38]. Melwanki, M. B.; Seetharamappa, J. Turk. J. Chem. 2000, 24 (3), 287-290.

[39]. Bodini, M. E.; Pardo, J.; Arancibia, V. Talanta 1990, 37 (4), 439-442.
https://doi.org/10.1016/0039-9140(90)80237-A

[40]. Rekha, D.; Suvardhan, K.; Kumar, K. S.; Naidu, G. R. K.; Chiranjeevi, P. J. Anal. Chem. 2006, 61 (12), 1177-1182.,
https://doi.org/10.1134/S1061934806120094

[41]. Sharma, R. D.; Amlathe, S. J. Chem. Pharma. Res. 2012, 4 (2), 1097-1105.

[42]. Revanasiddappa, H.; Dayananda, B. Cent. Eur. J. Chem. 2006, 4, 592-603.
https://doi.org/10.2478/s11532-006-0027-z

[43]. Bodini, M. E.; Alzamora, O. E. Talanta 1983, 30 (6), 409-412.
https://doi.org/10.1016/0039-9140(83)80096-4

[44]. Mousavi, M. F.; Ghiasvand, A. R.; Jahanshahi, A. R. Talanta 1998, 46 (5), 1011-1017.
https://doi.org/10.1016/S0039-9140(97)00370-6

[45]. Mathew, M.; Narayana, B. Indian J. Chem. Technol. 2006, 13, 455-462.

[46]. Ensafi, A. A.; Bagherian Dehaghi, G. Anal. Lett. 1995, 28 (2), 335-347.
https://doi.org/10.1080/00032719508000326

[47]. Donaldson, E. Talanta 1977, 24 (7), 441-445.
https://doi.org/10.1016/0039-9140(77)80126-4

[48]. Gürkan, R.; Akçay, M. Microchem. J. 2003, 75 (1), 39-49.
https://doi.org/10.1016/S0026-265X(03)00049-3

[49]. Afsar, H.; Apak, R.; Tor, I. Analyst 1989, 114 (10), 1319-1321.
https://doi.org/10.1039/AN9891401319

[50]. Chan, F. L. Talanta 1964, 11 (7), 1019-1029.
https://doi.org/10.1016/0039-9140(64)80145-4

[51]. Pyrzynska, K. Anal. Sci. 1997, 13 (4), 629-632.
https://doi.org/10.2116/analsci.13.629

[52]. Ahmed, M. J.; Islam, M. T.; Nime, M. J. Anal. Methods 2015, 7 (18), 7811-7823.
https://doi.org/10.1039/C5AY01311A

[53]. Mendham, J.; Denney, R. C.; Barnes, J. D.; Thomas, M. J. K. Vogel's Quantitative Chemical Analysis, 6th ed.; Longman: London, England, 1999.

[54]. Mukherji, A. K. Analytical Chemistry of Zirconium and Hafnium; Pergamon: Oxford, New Zealand, 1970.

[55]. Pal, B. K.; Choudhury, B. Mikrochim. Acta 1984, 83 (1-2), 121-131.
https://doi.org/10.1007/BF01237266

[56]. Busev, A. I. Analytical Chemistry of Rare Elements; Rosinkin, A., Translator; Central Books: London, England, 1982.

[57]. Ashley, S. E. Q. J. Phys. Chem. 1945, 49 (3), 263-264.
https://doi.org/10.1021/j150441a012

[58]. Ojeda, C. B.; de Torres, A. G.; Rojas, F. S.; Pavón, J. M. C. Analyst 1987, 112 (11), 1499-1501.
https://doi.org/10.1039/AN9871201499

[59]. Job, P. Ann. Chim. 1928, 9, 113-203.

[60]. Yoe, J. H.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16 (2), 111-115.
https://doi.org/10.1021/i560126a015

[61]. Sample Preparation Techniques in Analytical Chemistry: Mitra/Sample Prep in Analytical Chemistry; Mitra, S., Ed.; John Wiley & Sons: Nashville, TN, 2003.
https://doi.org/10.1002/0471457817.ch6

[62]. Sun, Y. C.; Yang, J. Y.; Tzeng, S. R. Analyst 1999, 124 (3), 421-424.
https://doi.org/10.1039/a809596e

[63]. American Public Health Association; American Water Works Association (AWWA); Water Environment Federation. Standard Methods for the Examination of Water and Wastewater, 18th ed.; American Public Health Association: Washington, D.C., DC, 1992.

[64]. Water; Sanitation; Hygiene; Health. Guidelines for drinking-water quality, 4th edition, incorporating the 1st addendum

https://www.who.int/publications/i/item/9789241549950 (accessed Oct 9, 2021).

[65]. Khayatian, G.; Hassanpoor, S.; Azar, A. R. J.; Mohebbi, S. J. Braz. Chem. Soc. 2013, 24 (11), 1808-1817.

[66]. Stahr, H. M. Analytical Methods in Toxicology; John Wiley & Sons: Nashville, TN, 1991.

[67]. Vercruysse. Hazardous Metals in Human Toxicology; Vercruysse, A., Ed.; Elsevier Science & Technology, 2000.

[68]. Rathje. Jackson, M. L.: Soil Chemical Analysis. Verlag: Prentice Hall, Inc., Englewood Cliffs, NJ. 1958.

[69]. Hutchinson, T. C.; Meema, K. M. Lead, Mercury, Selenium, Cadmium, Manganese and Arsenic in the Environment; John Wiley & Sons: Chichester, England, 1987.

[70]. Ahmed, M. J.; Hoque, M. R.; Khan, A. S. M. S. H.; Bhattacharjee, S. C. Eurasian J. Anal. Chem. 2010, 5 (1), 1-15.

[71]. Abrarin, S.; Ahmed, M. J. Eur. J. Chem. 2020, 11 (4), 385-395.
https://doi.org/10.5155/eurjchem.11.4.385-395.2030

[72]. Ahmed, M. J.; Stalikas, C. D.; Veltsistas, P. G.; Tzouwara-Karayanni, S. M.; Karayannis, M. I. Analyst 1997, 122 (3), 221-226.
https://doi.org/10.1039/a606357h

[73]. Zannat, T.; Ahmed, M. J. Eur. J. Chem. 2015, 6 (2), 141-150.
https://doi.org/10.5155/eurjchem.6.2.141-150.1193

[74]. Ahmed, M. J.; Islam, M. T.; Farhana, F. RSC Adv. 2019, 9 (44), 25609-25626.
https://doi.org/10.1039/C9RA02850A

[75]. Ahmed, M. J.; Afrin, A.; Uddin, M. O. Eur. J. Chem. 2020, 11 (1), 37-49.
https://doi.org/10.5155/eurjchem.11.1.37-49.1923

[76]. Ahmed, M. J.; Afrin, A.; Akhtar, Y. Am. J. Analyt. Chem. 2019, 10 (11), 528-561.
https://doi.org/10.4236/ajac.2019.1011038

[77]. Tazul Islam, M.; Jamaluddin Ahmed, M. Pak. J. Anal. Environ. Chem. 2013, 14 (1), 1-15.

[78]. Ahmed, M. J.; Afrin, A.; Haque, M. E. Eur. J. Chem. 2021, 12 (1), 1-12.
https://doi.org/10.5155/eurjchem.12.1.1-12.2031

[79]. Ahmed, M. J.; Islam, M. T.; Hossain, F. RSC Adv. 2018, 8 (10), 5509-5522.
https://doi.org/10.1039/C7RA12762F

[80]. Ahmed, M. J.; Afrin, A.; Rashid, M. Am. J. Analyt. Chem. 2019, 10 (08), 316-347.
https://doi.org/10.4236/ajac.2019.108023

[81]. Reddy, P. N. K.; Reddy, G. T.; Sangita, K. M.; Reddy, A. V. R.; Parveen, S. N.; Reddy, N. G. Der Pharmacia Letter 2015, 7 (1), 292-302.

[82]. Wikipedia contributors. Selenium

https://en.wikipedia.org/w/index.php?title=Selenium&oldid=1048104284 (accessed Oct 9, 2021).

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).