European Journal of Chemistry

X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide

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Published: Sep 30, 2022
DOI: https://doi.org/10.5155/eurjchem.13.3.253-258.2235
Keywords:
Disorder, Hydrazones, Single-crystal, X-ray diffraction, Hirshfeld surface, Hydrogen bonding
Section
Research Article
Issue
Vol. 13 No. 3 (2022): September 2022
Dates
Received 2022-03-02
Accepted 2022-04-03
Published 2022-09-30
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Varun Sharma
Department of Physics, University of Jammu, Jammu Tawi-180006, India
https://orcid.org/0000-0003-2866-8638
Indrajit Karmakar
Laboratory of Natural Products and Organic Synthesis, Department of Chemistry, Visva-Bharati (A Central University), Santiniketan-731235, West Bengal, India
https://orcid.org/0000-0002-2713-8080
Goutam Brahmachari
Laboratory of Natural Products and Organic Synthesis, Department of Chemistry, Visva-Bharati (A Central University), Santiniketan-731235, West Bengal, India
https://orcid.org/0000-0001-9925-6281
Vivek Kumar Gupta
Department of Physics, University of Jammu, Jammu Tawi-180006, India
https://orcid.org/0000-0003-2471-5943

Abstract

N'-Acetyl-N'-phenyl-2-naphthohydrazide, a biologically relevant organic molecule, was synthesized following a reported method and characterized based on its single X-ray crystallographic studies. The present manuscript deals with its detailed molecular interactions and X-ray crystal structure. Its space group is P-1 with the following unit cell parameters: a = 8.9164(7), b = 9.7058(9), c = 17.7384(12) Å, α = 88.308(7)°, β = 89.744(6)°, γ = 86.744(7)° and Z = 2. Crystal structure was solved by direct method and refined by full matrix least squares procedure to a final R value of 0.0580 and to a GOOF value of 1.066. The X-ray diffraction analyses showed that the asymmetric unit contains two crystallographically independent molecules. The crystal structure is stabilized by elaborate network of N-H···O and C-H···O hydrogen bonds along with C-H···π and π···π interactions to form supramolecular structures.


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Sharma, V.; Karmakar, I.; Brahmachari, G.; Gupta, V. K. X-Ray Crystal Structure Analysis of N’-Acetyl-N’-Phenyl-2-Naphthohydrazide. Eur. J. Chem. 2022, 13, 253-258.

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