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Study of expired Fuclo 500 drug as an environmentally sustainable corrosion inhibitor
Aphouet Aurelie Koffi (1)
, N'guadi Blaise Allou (2,*) , Mougo Andre Tigori (3) , Teminfolo Yaya Soro (4) , Albert Trokourey (5) , Paulin Marius Niamien (6) (1) Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
(2) Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
(3) Laboratoire des Sciences et Technologies de l’Environnement, Unité de Formation et de Recherche Environnement, Université Jean Lorougnon Guédé, Daloa, Côte d’Ivoire
(4) Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
(5) Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
(6) Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
(*) Corresponding Author
Received: 25 Apr 2023 | Revised: 28 May 2023 | Accepted: 04 Jun 2023 | Published: 30 Sep 2023 | Issue Date: September 2023
Abstract
This work deals with aluminium corrosion inhibition by expired drugs containing flucloxacillin in 1 M hydrochloric acid medium, using the gravimetric method and density functional theory. Weight loss results showed that the inhibitory efficiency of this compound increases with concentration and decreases with increasing temperature. The study also indicates that this molecule is adsorbed according to the modified Langmuir model (Villamil model). Furthermore, the thermodynamic parameters of adsorption (∆Goads, ∆Hoads, ∆Soads) and activation (Ea*, ΔHa*, ΔSa*) show that the adsorption is mixed type (chemisorption and physisorption). In addition, density functional theory provides access to the quantum chemical parameters of the molecule such as the lowest vacant orbital energy (ELUMO), the highest occupied orbital energy (EHOMO), the absolute electronegativity (χ), the global hardness (η), the global softness (S), the fraction of transferred electrons (ΔN) as well as the electrophilicity index (ω) for finding correlation between the inhibitor structure and the experimental data.
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DOI: 10.5155/eurjchem.14.3.353-361.2443
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