European Journal of Chemistry

Study of expired Fuclo 500 drug as an environmentally sustainable corrosion inhibitor

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Published: Sep 30, 2023
DOI: https://doi.org/10.5155/eurjchem.14.3.353-361.2443
Keywords:
DFT, Aluminium, Flucloxacillin, Hydrochloric acid, Weight loss method, Corrosion inhibition
Section
Research Article
Issue
Vol. 14 No. 3 (2023): September 2023
Dates
Received 2023-04-25
Accepted 2023-06-04
Published 2023-09-30
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Aphouet Aurelie Koffi
Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
https://orcid.org/0000-0003-2306-7593
N'guadi Blaise Allou
Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
https://orcid.org/0000-0002-4367-2128
Mougo Andre Tigori
Laboratoire des Sciences et Technologies de l’Environnement, Unité de Formation et de Recherche Environnement, Université Jean Lorougnon Guédé, Daloa, Côte d’Ivoire
https://orcid.org/0000-0002-3722-7896
Teminfolo Yaya Soro
Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
https://orcid.org/0009-0001-1494-7452
Albert Trokourey
Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
https://orcid.org/0000-0001-7139-5976
Paulin Marius Niamien
Laboratoire de Constitution et Réaction de la Matière, Unité de Formation et de Recherche des Sciences des Structures de la Matière et de Technologie, Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire
https://orcid.org/0000-0002-0744-9623

Abstract

This work deals with aluminium corrosion inhibition by expired drugs containing flucloxacillin in 1 M hydrochloric acid medium, using the gravimetric method and density functional theory. Weight loss results showed that the inhibitory efficiency of this compound increases with concentration and decreases with increasing temperature. The study also indicates that this molecule is adsorbed according to the modified Langmuir model (Villamil model). Furthermore, the thermodynamic parameters of adsorption (∆Goads, ∆Hoads, ∆Soads) and activation (Ea*, ΔHa*, ΔSa*) show that the adsorption is mixed type (chemisorption and physisorption). In addition, density functional theory provides access to the quantum chemical parameters of the molecule such as the lowest vacant orbital energy (ELUMO), the highest occupied orbital energy (EHOMO), the absolute electronegativity (χ), the global hardness (η), the global softness (S), the fraction of transferred electrons (ΔN) as well as the electrophilicity index (ω) for finding correlation between the inhibitor structure and the experimental data.


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Koffi, A. A.; Allou, N. B.; Tigori, M. A.; Soro, T. Y.; Trokourey, A.; Niamien, P. M. Study of Expired Fuclo 500 Drug As an Environmentally Sustainable Corrosion Inhibitor. Eur. J. Chem. 2023, 14, 353-361.

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