European Journal of Chemistry

Synthesis of coumarin-3-carboxylic acids in waste curd water: A green approach

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Published: Dec 31, 2023
DOI: https://doi.org/10.5155/eurjchem.14.4.439-444.2471
Keywords:
Sonication, Curd water, Green synthesis, Catalytic solvent, 3-Carboxycoumarins, Coumarin-3-carboxylic acid
Section
Research Article
Issue
Vol. 14 No. 4 (2023): December 2023
Dates
Received 2023-07-30
Accepted 2023-09-17
Published 2023-12-31
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Nitin Bhaidas Sonawane
Department of Chemistry, Bahujan Samaj Shikshan Prasarak Mandal’s Arts, Commerce and Science College, Songir, Dhule, 424309, Maharashtra, India
https://orcid.org/0009-0001-0483-4649
Jamatsing Dabarsing Rajput
Department of Chemistry, Bhagirathibai Purnapatre Arts, Sitabai Mangilal Agrawal Science, Kasturbai Khandu Chaudhari Commerce College, Chalisgaon, Jalgaon, 424101, Maharashtra, India
https://orcid.org/0000-0002-4588-1345
Dilip Ramsing Patil
Department of Chemistry, Rasiklal Chunilal Patel Education Trust’s Rasiklal Chunilal Patel Arts, Commerce & Science College, Shirpur, Dhule, 425405, Maharashtra, India
https://orcid.org/0009-0000-9446-1657

Abstract

An efficient and green protocol has been developed for the synthesis of derivatives of coumarin-3-carboxylic acid using waste curd water as a catalytic solvent. Curd water successfully catalyzes the reaction of 2-hydroxybenzaldehydes with dimethyl malonate under ultrasonic irradiation (40 °C) to construct different scaffolds of coumarin-3-carboxylic acid, with good to outstanding yields. The use of biodegradable solvents, sustainability, low reaction duration, mild reaction conditions without metals and Lewis acids, excellent yields, and compatibility with a wide range of electronically diverse substrates are all advantages of this synthesis process. Acidic curd water, which acts as a biological catalyst as well as a solvent for the reaction under ultrasonic irradiation, may be a better green alternative to some standard methods for synthesizing coumarin-3-carboxylic acids.


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Sonawane, N. B.; Rajput, J. D.; Patil, D. R. Synthesis of Coumarin-3-Carboxylic Acids in Waste Curd Water: A Green Approach. Eur. J. Chem. 2023, 14, 439-444.

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