European Journal of Chemistry

The supramolecular structures of oximes: an update and the crystal structure of 1,3-diphenyl-propan-2-one oxime

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Published: Jun 15, 2010
DOI: https://doi.org/10.5155/eurjchem.1.2.61-66.76
Keywords:
H-bonding, Oximes, 1, 3-Diphenyl-propan-2-one oxime, X-ray diffraction, Crystal structure
Section
Research Article
Issue
Vol. 1 No. 2 (2010): June 2010
Dates
Received 2010-04-27
Accepted 2010-05-21
Published 2010-06-15


Main Article Content

John Nicolson Low
Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen, AB24 3UE, Scotland.
Luís M. N. B. F. Santos
Centro de Investigação em Química, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto, Portugal
Carlos F. R. A. C. Lima
Centro de Investigação em Química, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto, Portugal
Paula Brandão
CICECO, Departamento de Química, Faculdade de Ciências, Universidade de Aveiro, 3810-193, Aveiro, Portugal
Lígia R. Gomes
REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, P-4169-007, Porto, Portugal CIAGEB-Faculdade de Ciências de Saúde, Escola Superior de Saúde da UFP, Universidade Fernando Pessoa, Rua C

Abstract

The crystal structure of 1,3-diphenyl-propan-2-one oxime, C15H15NO, is described. The compound crystallises in the monoclinic space group C2/c. Centrosymmetrically related molecules are linked to form R22 (6) dimers. An update, since 2003, of a systematic analysis of the hydrogen bonding patterns in oxime structures with and without competitive O-H...A type acceptors (an acceptor other than the nitrogen of the oxime) functional group is made, taking into account their moieties. The majority of these oximes form dimeric, R22 (6), structures but R33 (8) and R44 (12) were also found. C3 chains which were classically claimed as the usual oxime H-bond pattern were rarely observed. They are mostly found in aldoxime structures.

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(1)
Low, J. N.; Santos, L. M. N. B. F.; Lima, C. F. R. A. C.; Brandão, P.; Gomes, L. R. The Supramolecular Structures of Oximes: An Update and the Crystal Structure of 1,3-Diphenyl-Propan-2-One Oxime. Eur. J. Chem. 2010, 1, 61-66.

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Author Biography

John Nicolson Low, Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen, AB24 3UE, Scotland.

Honorary Research Fellow

Department of Chemistry

University of Aberdeen

 

Scotland

 

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