European Journal of Chemistry

The supramolecular structures of oximes: an update and the crystal structure of 1,3-diphenyl-propan-2-one oxime



Main Article Content

John Nicolson Low
Luís M. N. B. F. Santos
Carlos F. R. A. C. Lima
Paula Brandão
Lígia R. Gomes

Abstract

The crystal structure of 1,3-diphenyl-propan-2-one oxime, C15H15NO, is described. The compound crystallises in the monoclinic space group C2/c. Centrosymmetrically related molecules are linked to form R22 (6) dimers. An update, since 2003, of a systematic analysis of the hydrogen bonding patterns in oxime structures with and without competitive O-H...A type acceptors (an acceptor other than the nitrogen of the oxime) functional group is made, taking into account their moieties. The majority of these oximes form dimeric, R22 (6), structures but R33 (8) and R44 (12) were also found. C3 chains which were classically claimed as the usual oxime H-bond pattern were rarely observed. They are mostly found in aldoxime structures.

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(1)
Low, J. N.; Santos, L. M. N. B. F.; Lima, C. F. R. A. C.; Brandão, P.; Gomes, L. R. The Supramolecular Structures of Oximes: An Update and the Crystal Structure of 1,3-Diphenyl-Propan-2-One Oxime. Eur. J. Chem. 2010, 1, 61-66.

Article Details

Author Biography

John Nicolson Low, Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen, AB24 3UE, Scotland.

Honorary Research Fellow

Department of Chemistry

University of Aberdeen

 

Scotland

 

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