

A simple and rapid spectrophotometric method for the determination of iron in environmental, biological, pharmaceutical, food and soil samples using 1,2-dihydroxybenzene-3,5-disulfonic acid
Tasnima Zannat (1)


(1) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong, 4331, Bangladesh
(2) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong, 4331, Bangladesh
(*) Corresponding Author
Received: 18 Jul 2013 | Accepted: 07 Sep 2013 | Published: 31 Mar 2014 | Issue Date: March 2014
Abstract
An ultra-sensitive and highly selective non-extractive spectrophotometric method is presented for the rapid determination of iron (III) at trace levels using 1,2-dihydroxybenzene-3,5-disulfonic acid (Tiron) as a new spectrophotometric reagent (lmax = 665 nm) in slightly acidic aqueous (2×10-6 - 2×10-5 mol/L H2SO4) solution. The reaction is instantaneous and absorbance remains stable for over 24 h. The average molar absorption coefficient and Sandell’s sensitivity and detection limit were found to be 6.0×105 L/mol.cm, 10 ng/cm2, and 1 µg/L, respectively. Linear calibration graphs were obtained for 0.02-70.00 mg/L of Fe(III). The stoichiometric composition of the chelate is 2:3 (Fe(III):Tiron). Large excesses of over 50 cations, anions and complexing agents (e.g. Tartrate, oxalate, citrate, phosphate, thiourea, and thiocyanate) do not interfere in the determination. The method was successfully used in the determination of iron in several standard reference materials (Alloys and steels) as well as in some environmental waters (portable and polluted), biological samples (Human blood and urine), food, pharmaceutical and soil samples, solution containing iron (II) and iron (III) and some complex synthetic mixtures. The method has high precision and accuracy (s = ±0.01 for 0.5 mg/L).
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European Journal of Chemistry
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DOI: 10.5155/eurjchem.5.1.101-110.882
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Chittagong Medical College Hospital, Chittagong, 4331, Bangladesh
Citations
[1]. M. K. Das, V. V. Raut, S. B. Deb, S. Jeyakumar, M. K. Saxena, B. S. Tomar
Determination of calcium and iron in silicon and uranium silicide using ion chromatography
Journal of Radioanalytical and Nuclear Chemistry 302(3), 1385, 2014
DOI: 10.1007/s10967-014-3551-x

[2]. Tasnima Zannat, Mohammad Jamaluddin Ahmed
Highly sensitive spectrophotometric method for the determination of vanadium in environmental, biological, food and soil samples using orthoaminophenol
European Journal of Chemistry 6(2), 141, 2015
DOI: 10.5155/eurjchem.6.2.141-150.1193

[3]. Mohammed Jamaluddin Ahmed, Faisal Hossain, Esham Mahmood
A Highly Selective and Simple Spectrophotometric Method for the Determination of Zinc at Nano-trace Levels in Some Environmental, Biological, Food, and Pharmaceutical Samples Using 2-hydroxynaphthaldehydebenzoylhydrazone
European Journal of Chemistry 11(2), 160, 2020
DOI: 10.5155/eurjchem.11.2.160-167.1987

References
[1]. Barceloux, D. G. J. Clin. Toxicol. 1999, 37(2), 173-194.
http://dx.doi.org/10.1081/CLT-100102418
[2]. Clayton, G. D.; Clayton, F. E. (eds.) Pathy's Industrial Hygiene and Toxicology, 3rd edition, Wiley, New York, 1981, pp. 1658.
[3]. Herney, L. H. Trace Element Analytical Chemistry in Medicine and Biology, Pratter P. and Scharmel, P. (eds.), Vol. 3, Walter de Gruyter, Berlin, 1984, pp. 375.
[4]. Goyter, R. A.; Clarkson, T. W. Casarette and Doull's Toxicology: The Basic Science of Poisons, C. D. Klaassen (ed.), 6th edition, Macmillan Publishing Company, 2001, pp. 827.
[5]. Beecks, L. R. Anal. Chem. 1986, 58(9), 975A-978A
http://dx.doi.org/10.1021/ac00122a721
[6]. Key, M. M.; Henschel, A. F.; Butter, J.; Ligo, R. N.; Tebershed, I. R. Occupational Diseases : A Guide to their recognition, US Department of Health, Education and Welfare, U. S. Govt. Printing, Washington, D. C. 1977.
[7]. Venugopal, B.; Luckey, T. D. Metal Toxicity in Mammals-2, Plenum Press, New York, 1979, pp. 275.
[8]. Clayton, G. D.; Clayton, F. E. (eds.), Patty's Industrial Hygiene and Toxicology, Wiley, New York, Vol. 2, 3rd edition, 1981, pp. 1662.
[9]. Institute of Medicine, Food and Nutrition Board, Dietary Reference Intakes for vit. A, vit. K, Arsenic, Chromium, Copper, Iodine, Iron, Manganese, Molybdenum, Nickel, Silicon, Vanadium and Zinc, Washington National Academy Press, 2001.
[10]. Dallman, P. R. Annu. Rev. Nutr. 1986, 6, 13-40.
http://dx.doi.org/10.1146/annurev.nu.06.070186.000305
[11]. Andrews, N. C. New Engl. J. Med. 1999, 341(26), 1986-1995.
http://dx.doi.org/10.1056/NEJM199912233412607
[12]. Corbett, J. V. MCN Am. J. Matern. Child. Nurs. 1995, 20(4), 234-239
http://dx.doi.org/10.1097/00005721-199507000-00023
[13]. Abdollahia, H.; Shariat, P. M.; Khoshayand, M. R. Iranian J. Pharm. Res. 2003, 2(4), 207-212.
[14]. Jankiewicz, B.; Ptaszynsky, B.; Turek A. Pol. J. Environ. Stud. 2002, 11(6), 745-749.
[15]. Malik, A. K.; Bansal, S.; Aluakh, J. S. Anal. Bioanal. Chem. 2003, 375(8), 1250-1253.
[16]. Chen, Y.; Ding, C. M.; Zhou, T. Z.; Qi, D. Y. Fresen. J. Anal. Chem. 1999, 363(1), 119-120.
http://dx.doi.org/10.1007/s002160051152
[17]. Demirhan, N.; Elmali, F. T. Turk. J. Chem. 2003, 27(3), 315-322.
[18]. Stalikas, C. D.; Pappas, A. C.; Karayannis, M. I.; Veltsistas, P. G. Microchim. Acta 2003, 142(1-2), 43-48.
http://dx.doi.org/10.1007/s00604-002-0950-4
[19]. Vogel, A. I. Quantitative Inorganic Analysis, 3rd edition, The English Language Book of Society and Longman, London, 1961, pp. 309.
[20]. Mukharjee, A. K. Analytical Chemistry of Zirconium and Hafnium, 1st edition, Pergamon Press, New York, 1970, pp. 385.
[21]. Pal, B. K.; Chowdhury, B. Microchim. Acta 1984, 83(1-2) 121-131.
http://dx.doi.org/10.1007/BF01237266
[22]. Busev, A. I.; Tiptsova, V. G.; Ivanov, V. M. (eds.), Analytical Chemistry of Rare Elements, Mir Publishers, Moscow, 1981. pp. 386.
[23]. Sandell, E. B. Colorimetric Determination of Traces of Metals, 3rd edition, InterScience, New York, 1965, pp. 269.
[24]. Ojeda, C. B.; Torres, A. G. Rojas, F. S.; Pavon, J. M. C. Analyst 1987, 112, 1499-1502.
http://dx.doi.org/10.1039/an9871201499
[25]. Job, P. Anm. Chim. (Paris) 1928, 9, 113-116.
[26]. You, J. A.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16, 11-16.
[27]. Parker, G. A. Analytical Chemistry of Molybdenum, Springer Verlag Berlin, 1983.
http://dx.doi.org/10.1007/978-3-642-68992-5
[28]. Greenberg, A. E.; Clesceri, L. S.; Trussell, R. R. (eds.), Standard Methods for the Examination of Water and Waste Water, 18th edition, American Public Health Association, Washington DC. 1992. pp. 3-53.
[29]. Ali, A. M.; Mori, Y.; Sawada, K. Anal. Sci. 2006, 22(9), 1169-1172.
http://dx.doi.org/10.2116/analsci.22.1169
[30]. Fifield, F. W.; Haines, P. J. (Eds.), Environmental Chemistry, 2nd edition, Blackwell Science, London, 2000, pp. 420.
[31]. Stahr, H. M. Analytical Methods in Toxicology, 3rdedition, John Wiley and Sons, New York, 1991, pp. 75.
[32]. Hesse, P. R. A. Text Book of Soil Chemical Analysis, Chemical Publishing Co. Inc. New York, 1972, pp. 332.
[33]. Ahmed, M. J.; Roy, U. K. Turk. J. Chem. 2009, 33, 709-726.
[34]. Ahmed, M. J.; Mamun M. A. Talanta 2001, 55(1), 43-55.
http://dx.doi.org/10.1016/S0039-9140(01)00389-7
[35]. Ahmed, M. J.; Hoque, M. R.; Khan A. S. M. S. H.; Bhattacharjee, S. C. Eurasian J. Anal. Chem. 2010, 5(1), 1-15.
[36]. Ahmed, M. J.;Hossan, K. J. J. Iran. Chem. Soc. 2008, 5(4), 677-688
[37]. Ahmed, M. J.; Tasnima, Z. Pakistan J. Anal. Environ. Chem. 2012, 13(1), 22-35.
[38]. Ahmed, M. J.; Zannat, T.; Saifuddin, M.; Bhattacharjee, S. C. The Global Directory for Environmental Technology (Green Pages) 2010, URL: http://www.eco-web.com/edi/100412.html, ID:100412.
[39]. Soomro, R.; Ahmed, M. J.; Najma, M. Turk. J. Chem. 2011, 35(11), 155-170.
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