SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water

Vijay Manneganti; Badari Narayana Prasad Rachapudi; Lakshmi Anu Prabhavathi Devi Bethala

doi:10.5155/eurjchem.5.1.167-170.917

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Published: Mar 31, 2014

DOI: https://doi.org/10.5155/eurjchem.5.1.167-170.917

Keywords:

Water, Oxiranes, Azidolysis, Sodium azide, Azidohydrins, Carbon acid catalyst

Section

Research Article

Issue

Vol. 5 No. 1 (2014): March 2014

Dates

Received 2013-09-05
Accepted 2013-11-02
Published 2014-03-31

Vijay Manneganti

Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India

Badari Narayana Prasad Rachapudi

Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India

Lakshmi Anu Prabhavathi Devi Bethala

Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India

Abstract

A series of β-hydroxyazides were effectively synthesized from the regioselective ring opening of oxiranes by azide anion in presence of glycerol-based sulfonic acid functionalized carbon as a novel reusable heterogeneous catalyst in H₂O achieving good yields (80-98%). The workup procedure was simple, and the catalyst could be reused over five times without losing its catalytic activity and selectivity.

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Manneganti, V.; Rachapudi, B. N. P.; Bethala, L. A. P. D. SO3H-Carbon Derived from Glycerol: An Efficient and Recyclable Catalyst for Smooth and Regioselective Azidolysis of Oxiranes in Water. Eur. J. Chem. 2014, 5, 167-170.

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Supporting Agencies

Council of Scientific and Industrial Research (CSIR), New Delhi, India

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