European Journal of Chemistry

Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand

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Published: Dec 31, 2016
DOI: https://doi.org/10.5155/eurjchem.7.4.416-420.1503
Keywords:
Thioureas, Cis-complex, Copper complex, Single crystal structure, Carboxamide derivatives, Cyclohexanecarboxamide
Section
Research Article
Issue
Vol. 7 No. 4 (2016): December 2016
Dates
Received 2016-10-29
Accepted 2016-11-28
Published 2016-12-31


Main Article Content

Ilkay Gumus
Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
Cemal Koray Ozer
Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
Don Vanderveer
Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
Hakan Arslan
Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey

Abstract

Copper(II) complex, cis-[Cu(L-κ2S,O)2] of N-(di-n-propylcarbamothioyl)cyclohexane carboxamide ligands (HL) has been synthesized and structurally characterized by various spectroscopic techniques and single crystal X-ray diffraction crystallography. The cis-[Cu(L-κ2S,O)2], C28H50CuN4O2S2: Monoclinic, space group P21/n (no. 14), a = 10.025(2) Å, b = 21.724(4) Å, c = 14.848(3) Å, β = 100.60(3)°, Z = 4, Dcalc = 1.259 g/cm3, 22069 reflections measured (5.88° ≤ 2Θ ≤ 50.2°), 5639 unique (Rint = 0.0630, Rsigma = 0.0678) which were used in all calculations. The final R1 was 0.0488 (≥2σ(I)) and wR2 was 0.1277 (all data). Single crystal analysis revealed that a square-planar coordination geometry is formed around the copper atom by two sulphur and two oxygen atoms of the related ligand, which are in a cis configuration.


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Gumus, I.; Ozer, C. K.; Vanderveer, D.; Arslan, H. Crystal Structure of Cis-copper(II) Complex With N-(di-N-propylcarbamothioyl)cyclohexanecarboxamide Ligand. Eur. J. Chem. 2016, 7, 416-420.

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References

[1]. Neucki, E. Ber. Dtsch. Chem. Ges., 1873, 6, 598-600.
https://doi.org/10.1002/cber.187300601186

[2]. Hope G. A.; Woods, R.; Boyd, S. E.; Watling, K. Colloids Surf. A, 2004, 232, 129-137.
https://doi.org/10.1016/j.colsurfa.2003.10.011

[3]. Guang-yi, L.; Hong, Z.; Liu-yin, X.; Shuai, W.; Zheng-He, X.; Miner. Eng. 2011, 24, 817-824.
https://doi.org/10.1016/j.mineng.2011.01.009

[4]. Otazo-Sanchez, E.; Perez-Marin, L.; Estevez-Hernandez, O.; Rojas-Lima, S.; Alonso-Chamarro, J. J. Chem. Soc., Perkin Trans. 2001, 2, 2211-2218.

[5]. Wilson, D.; Arada, M. A.; Alegret, S.; DelValle, M.; J. Hazard. Mater. 2010, 181, 140-146.
https://doi.org/10.1016/j.jhazmat.2010.04.107

[6]. Daud, A. I.; Khairul, W. M.; Mohamed, Z. H.; KuBulat, K. J. Sulfur Chem. 2014, 35, 691-699.
https://doi.org/10.1080/17415993.2014.954248

[7]. Yuan, Y. F.; Wang, J. T.; Gimeno, M. C.; Laguna, A.; Jones, P. G. Inorg. Chim. Acta 2001, 324, 309-317.
https://doi.org/10.1016/S0020-1693(01)00661-2

[8]. Zhang, Y. M.; Wei, T. B.; Xian, L.; Gao, L. M. Phosphorus Sulfur Silicon Relat. Elem. 2004, 179, 2007-2013.
https://doi.org/10.1080/10426500490473456

[9]. Zhang, Y. M.; Wei, T. B.; Wang, X. C.; Yang, S. Y. Indian J. Chem. Sect B 1998, 37, 604-606.

[10]. Zhou, W. Q.; Li, B. L.; Zhu, L. M.; Ding, J. G.; Yong, Z.; Lu, L.; Yang, X. J. J. Mol. Struct. 2004, 690, 145-150.
https://doi.org/10.1016/j.theochem.2004.02.011

[11]. Henderson, W.; Nicholson, B. K.; Dinger, M. B.; Bennett, R.L. Inorg. Chim. Acta 2002, 338, 210-218.
https://doi.org/10.1016/S0020-1693(02)01017-4

[12]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A. J. Chem. Soc., Dalton Trans. 2000, 24, 4579-4586.
https://doi.org/10.1039/b007589m

[13]. Lipowska, M.; Hayes, B. L.; Hansen, L.; Taylor, A.; Marzilli, L.G. Inorg. Chem. 1996, 35, 4227-4231.
https://doi.org/10.1021/ic9514657

[14]. Beyer, L.; Hoyer, E.; Hennig, H.; Kirmse, R.; Hartmann, H.; Liebscher, J. J. Prakt. Chem. 1975, 317, 829-839.
https://doi.org/10.1002/prac.19753170518

[15]. Beyer, L.; Hoyer, E.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21, 81-91.

[16]. Beyer, L.; Richter, R.; Seidelmann, O.; J. Prakt. Chem. Chem. Ztg. 1999, 341, 704.
https://doi.org/10.1002/(SICI)1521-3897(199911)341:8<704::AID-PRAC704>3.0.CO;2-E

[17]. Richter, R.; Beyer, L.; Kaiser, J.; Z. Anorg. Allg. Chem. 1980, 461, 67-73.
https://doi.org/10.1002/zaac.19804610111

[18]. Flores-Centurion, R.; Richter, R.; Angulo-Cornejo, J.; Beyer, L. Bol. Soc. Quim. Peru 1999, 65, 211-215.

[19]. Gomes, J. R. B.; Ribeiro da Silva, M. A. V. Inorg. Chem. Commun. 2003, 6, 149-153.
https://doi.org/10.1016/S1387-7003(02)00704-9

[20]. Schroder, U.; Richter, R.; Beyer, L.; Angulo-Cornejo, J.; Lino-Pacheco, M.; Guillen, A.; Z. Anorg. Allg. Chem. 2003, 629, 1051-1058.
https://doi.org/10.1002/zaac.200300019

[21]. Bruker, SADABS, Bruker AXS Inc., USA, 2007.

[22]. Sheldrick, G. M. Acta Crystr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[23]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[24]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Binzet, G. J. Coord. Chem. 2009, 62, 266-276.
https://doi.org/10.1080/00958970802209623

[25]. Arslan, H.; Kulcu, N.; Florke. U. Transition Met. Chem. 2003, 28, 816-819.
https://doi.org/10.1023/A:1026064232260

[26]. Ozer, C. K., MSc thesis, Mersin University, Mersin, Turkey, 2008.

[27]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14, 519-527.
https://doi.org/10.3390/molecules14010519

[28]. Al-abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, o1891- o1891.
https://doi.org/10.1107/S1600536811025013

[29]. Rauf, M. K.; Ebihara, M.; Badshah, A. Acta Crystallogr. E 2012, 68, o119- o119.
https://doi.org/10.1107/S1600536811052780

[30]. Yamin, B. M.; Osman, U. M. Acta Crystallogr. E 2011, 67, o1286-o1286.
https://doi.org/10.1107/S1600536811014954

[31]. Yang, W.; Zhou, W.Q.; Zhang, Z. J. J. Mol. Struct. 2007, 828, 46-53.
https://doi.org/10.1016/j.molstruc.2006.05.033

[32]. Arslan, H.; Florke, U.; Kulcu, N.; Binzet, G. Spectrochim. Acta A 2007, 68, 1347-1355.
https://doi.org/10.1016/j.saa.2007.02.015

[33]. Yusof, M. S.; Jusoh, R. H.; Khairul, W. M.; Bohari, M.Y. J. Mol. Struct. 2010, 975, 280-284.
https://doi.org/10.1016/j.molstruc.2010.04.037

[34]. Al-Abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, 1891-1894.
https://doi.org/10.1107/S1600536811025013

[35]. Mohamadou, A.; Dechamps-Olivier, I.; Barbier, J. P. Polyhedron 1994, 13, 1363-1370.
https://doi.org/10.1016/S0277-5387(00)81702-7

[36]. Arslan, H.; Florke, U.; Kulcu. N. Acta Chim. Slov. 2004, 51, 787-792.

[37]. Dragojlovic, V. Chem Texts 2015, 1-14, DOI: 10.1007/s40828-015-0014-0.
https://doi.org/10.1007/s40828-015-0014-0

Supporting Agencies

This study was supported by the Research Fund of Mersin University in Turkey with Project Number, BAP-SBE TB (CKÖ) 2007-1 YL.
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