Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands

Efdal Cimen; Ilkay Gumus; Omer Celik; Ebru Keskin; Hakan Arslan

doi:10.5155/eurjchem.7.4.448-453.1509

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Published: Dec 31, 2016

DOI: https://doi.org/10.5155/eurjchem.7.4.448-453.1509

Keywords:

Synthesis, Zinc complex, Zinc carboxylate, Crystal structure, Centrosymmetric, Dinuclear zinc(II) complex

Section

Research Article

Issue

Vol. 7 No. 4 (2016): December 2016

Dates

Received 2016-11-13
Accepted 2016-12-03
Published 2016-12-31

Efdal Cimen

Department of Chemistry and Chemical Process Technology, Kars Vocational School, Kafkas University, Kars, TR-36100, Turkey

Ilkay Gumus

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33344, Turkey

Omer Celik

Science and Technology Applied and Research Center, Dicle University, Sur, Diyarbakir, TR-21280, Turkey

Ebru Keskin

Advanced Technology Research and Application Center, Mersin University, Mersin, TR-33343, Turkey

Hakan Arslan

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33344, Turkey

Abstract

The centrosymmetric binuclear complex, [Zn₂(C₈H₇O₂)₄(C₇H₇NO)₂], has been synthesized and characterized by FT-IR and NMR methods. The obtained Zn(II) metal complex has been also characterized by a single crystal X-ray diffraction study. Crystal data for C₄₆H₄₂N₂O₁₀Zn₂: Monoclinic, Space group P2₁/c (no. 14), a = 10.4827(3) Å, b = 8.6141(2) Å, c = 24.7582(6) Å, β = 101.066(1) °, V = 2194.07(10) Å³, Z = 4, D_calc = 1.383 g/cm³, 22545 reflections measured (3.96° ≤ 2Θ ≤ 52.74°), 4465 unique (R_int = 0.0388, R_sigma = 0.0333) which were used in all calculations. The final R₁ was 0.0489 (I ≥ 2s(I)) and wR₂ was 0.1533 (all data). The four nearest oxygen atoms around each zinc ion form a distorted square-planar arrangement, and the distorted square-pyramidal coordination is completed by the nitrogen atom of the 1-(pyridin-4-yl)ethanone compound.

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Cimen, E.; Gumus, I.; Celik, O.; Keskin, E.; Arslan, H. Preparation, Characterization and Crystal Structure of Dinuclear zinc(II) Carboxylate Complex With 1-(pyridin-4-yl)ethanone and 4-Methylbenzoate Based Ligands. Eur. J. Chem. 2016, 7, 448-453.

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Supporting Agencies

This study was supported by the Research Fund of Mersin University in Turkey with Project Number, 2015-AP4-1162.

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