

Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex
Gun Binzet (1,*)




(1) Science Education, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author
Received: 31 Jan 2012 | Accepted: 06 Feb 2012 | Published: 31 Mar 2012 | Issue Date: March 2012
Abstract
We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3. In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.
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DOI: 10.5155/eurjchem.3.1.37-39.591
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Funding information
Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).
Citations
[1]. Ilkay Gumus, Serpil Gonca, Birdal Arslan, Ebru Keskin, Ummuhan Solmaz, Hakan Arslan
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[3]. Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
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Journal of Chemistry 2013, 1, 2013
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[4]. Rodrigo S. Correa, Katia M. Oliveira, Hiram Pérez, Ana M. Plutín, Raúl Ramos, Raúl Mocelo, Eduardo E. Castellano, Alzir A. Batista
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Arabian Journal of Chemistry 12(8), 3454, 2019
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[5]. Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
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