Crystal and molecular structure of  bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II)  complex

Gun Binzet; Ulrich Flörke; Nevzat Külcü; Hakan Arslan

doi:10.5155/eurjchem.3.1.37-39.591

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Published: Mar 31, 2012

DOI: https://doi.org/10.5155/eurjchem.3.1.37-39.591

Keywords:

Thiourea, Benzamide, Nickel complex, Benzoylthiourea, Crystal structure, Single crystal X‐ray diffraction

Section

Research Article

Issue

Vol. 3 No. 1 (2012): March 2012

Dates

Received 2012-01-31
Accepted 2012-02-06
Published 2012-03-31

Gun Binzet

Science Education, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey

Ulrich Flörke

Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany

Nevzat Külcü

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Hakan Arslan

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Abstract

We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C₂₄H₂₈Br₂NiN₄O₂S_2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P2₁/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)^o and V = 2762.5(6) Å³. In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

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(1)

Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and Molecular Structure of bis(4-Bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) Complex. Eur. J. Chem. 2012, 3, 37-39.

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Supporting Agencies

Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).

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