European Journal of Chemistry 2012, 3(1), 37-39 | doi: https://doi.org/10.5155/eurjchem.3.1.37-39.591 | Get rights and content

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Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex


Gun Binzet (1,*) , Ulrich Flörke (2) , Nevzat Külcü (3) , Hakan Arslan (4)

(1) Science Education, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author

Received: 31 Jan 2012 | Accepted: 06 Feb 2012 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract


We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3.  In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

3_1_37_39_800


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Editor-in-Chief
European Journal of Chemistry

Keywords


Thiourea; Benzamide; Nickel complex; Benzoylthiourea; Crystal structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.3.1.37-39.591

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Funding information


Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).

Citations

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[1]. Ilkay Gumus, Serpil Gonca, Birdal Arslan, Ebru Keskin, Ummuhan Solmaz, Hakan Arslan
N-(Dibenzylcarbamothioyl)-3-methylbutanamide: Crystal structure, Hirshfeld surfaces and antimicrobial activity
European Journal of Chemistry  8(4), 410, 2017
DOI: 10.5155/eurjchem.8.4.410-416.1650
/


[2]. B. Schmitt, T.I.A. Gerber, E. Hosten, R. Betz
Monomeric/dimeric complexes of fac-[Re(CO)3]+ with benzoylthiourea derivatives
Inorganic Chemistry Communications  24, 136, 2012
DOI: 10.1016/j.inoche.2012.08.008
/


[3]. Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Journal of Chemistry  2013, 1, 2013
DOI: 10.1155/2013/536562
/


[4]. Rodrigo S. Correa, Katia M. Oliveira, Hiram Pérez, Ana M. Plutín, Raúl Ramos, Raúl Mocelo, Eduardo E. Castellano, Alzir A. Batista
cis-bis(N-benzoyl-N′,N′-dibenzylthioureido)platinum(II): Synthesis, molecular structure and its interaction with human and bovine serum albumin
Arabian Journal of Chemistry  12(8), 3454, 2019
DOI: 10.1016/j.arabjc.2015.10.006
/


[5]. Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
A review on the chemistry, coordination, structure and biological properties of 1-(acyl/aroyl)-3-(substituted) thioureas
Journal of Sulfur Chemistry  35(3), 318, 2014
DOI: 10.1080/17415993.2013.834904
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[6]. K.H. Kumar Naik, B. Ashok, Nagaraja Naik, Jameel Ahmed S. Mulla, Avinash Prakasha
DNA binding, anti-inflammatory and analgesic evaluation of metal complexes of N/S/O donor ligands; Synthesis, spectral characterization
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy  141, 88, 2015
DOI: 10.1016/j.saa.2014.11.068
/


[7]. Naushad Ahmad, Rizwan Wahab, Suliman Yousef Al Oma
Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)
European Journal of Chemistry  5(1), 155, 2014
DOI: 10.5155/eurjchem.5.1.155-161.929
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[8]. Adel Sayed Orabi, Sahar Said El-Sakka
Correlation between single crystal data and molecular mechanics calculation of 3-(2-hydroxy-phenylimino)-1,3-diphenyl-propan-1-one
European Journal of Chemistry  10(2), 139, 2019
DOI: 10.5155/eurjchem.10.2.139-145.1838
/


[9]. Ebru Keskin, Ummuhan Solmaz, Gun Binzet, Ilkay Gumus, Hakan Arslan
Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands
European Journal of Chemistry  9(4), 360, 2018
DOI: 10.5155/eurjchem.9.4.360-368.1774
/


[10]. Gun Binzet, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex
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DOI: 10.5155/eurjchem.3.2.211-213.594
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References


[1]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt. A. J. Chem. Soc. Dalton Trans. 2000, 24, 4579-4585.
http://dx.doi.org/10.1039/b007589m

[2]. Sun, C.; Huang, H.; Feng, M.; Shi, X.; Zhang, X.; Zhou, P. Bioorg. Med. Chem. Lett. 2006, 16, 162-166.
http://dx.doi.org/10.1016/j.bmcl.2005.09.033

[3]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120

[4]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1(3), 221-227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124

[5]. Chow, A. W. U. S. Patent No. 4438135. Washington, D. C., USA: U. S. Patent and Trademark Office, 1984.

[6]. Zikan, V.; Sluka, J.; Daněk, J. CS Patent No. 8800122. Prague, Czechoslovakia: Czechoslovak Office for Trademarks and Inventions, 1988.

[7]. Ke, S. Y.; Xue, S. J. Arkivoc 2006, 10, 63-68.

[8]. Ramadas, K.; Suresh, G.; Janarthanan, N.; Masilamani, S. Pestic. Sci. 1998, 52, 145-151.
http://dx.doi.org/10.1002/(SICI)1096-9063(199802)52:2<145::AID-PS677>3.0.CO;2-J

[9]. Griffith, E. A. H.; Spofford III, W. A.; Amma, E. L. Inorg. Chem. 1978, 17, 1913-1917.
http://dx.doi.org/10.1021/ic50185a043

[10]. Sinscough, E. W.; Brodie, A. M. Coord. Chem. Rev. 1978, 27, 59-86.
http://dx.doi.org/10.1016/S0010-8545(00)80353-7

[11]. Doona, C. J; Stanbury, D. M. Inorg. Chem. 1996, 35, 3210-3216.
http://dx.doi.org/10.1021/ic9502077
PMid:11666519

[12]. Wilson, D.; DeLosAngeles, M.; Arada, S.; Alegret, M.; Del Valle, M. Hazard. J. Mater. 2010, 181, 140-146.
http://dx.doi.org/10.1016/j.jhazmat.2010.04.107
PMid:20510508

[13]. Mansuroglu, D. S.; Arslan, H.; VanDerveer, D.; Binzet G. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(12), 3221-3230.
http://dx.doi.org/10.1080/10426500902979743

[14]. Arslan, H.; Flörke, U.; Külcü, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[15]. Mansuroglu, D. S.; Arslan, H.; Flörke, U.; Külcü, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[16]. Binzet, G.; Arslan, H.; Flörke, U.; Külcü, N. J. Coord. Chem. 2009, 62(21), 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[17]. Ugur, D.; Arslan, H.; Külcü, N. Russ. J. Coord. Chem. 2006, 32, 669-675.
http://dx.doi.org/10.1134/S1070328406090089

[18]. Avsar, G.; Arslan, H.; Haupt, H. J.; Külcü, N. Turk. J. Chem. 2003, 27, 281-285.

[19]. Arslan, H.; Flörke, U.; Külcü, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[20]. Arslan, H.; Külcü, N.; Flörke, U. Transit. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[21]. Arslan, H.; Flörke, U.; Külcü, N. J. Chem. Crystallogr. 2003, 33, 919-924.
http://dx.doi.org/10.1023/A:1027429814989

[22]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o452-o453.
http://dx.doi.org/10.1107/S1600536809003511
PMid:21582125 PMCid:2968555

[23]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o427-o428.
http://dx.doi.org/10.1107/S1600536809003183
PMid:21582014 PMCid:2968358

[24]. Yesilkaynak, T.; Binzet, G.; Emen, F. M.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3

[25]. Avsar, G.;Kulcu, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607-615.

[26]. Ozpozan, N.; Ozpozan, T.; Arslan, H.; Karipcin, F.; Külcü, N. Thermochim. Acta 1999, 336, 97-103.
http://dx.doi.org/10.1016/S0040-6031(99)00208-7

[27]. Ozpozan, N.; Arslan, H.; Ozpozan, T.; Merdivan, M.; Külcü, N. J. Therm. Anal. Calorim. 2000, 61, 955-965.
http://dx.doi.org/10.1023/A:1010171230450

[28]. Binzet, G.; Arslan, H.; Flörke, U.; Külcü, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[29]. Arslan, H.; Duran, N.; Borekci, G.; Ozer C. K.; Akbay, C. Molecules 2009, 14(1), 519-527.
http://dx.doi.org/10.3390/molecules14010519
PMid:19169199

[30]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930
PMid:18156677

[31]. Saeed, S.; Rashid, N.; Jones, P.; Hussain, R. Eur. J. Chem. 2011, 2(1), 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[32]. Saeed, A.; Mumtaz, A.; Flörke, U. Eur. J. Chem. 2010, 1(2), 73-75.
http://dx.doi.org/10.5155/eurjchem.1.2.73-75.34


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, G., Flörke, U., Külcü, N., & Arslan, H. (2012). Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. European Journal of Chemistry, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, Gun, Ulrich Flörke, Nevzat Külcü, & Hakan Arslan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex." European Journal of Chemistry [Online], 3.1 (2012): 37-39. Web. 4 Oct. 2023
Binzet, Gun, Flörke, Ulrich, Külcü, Nevzat, AND Arslan, Hakan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

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