Crystal and molecular structure of  bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II)  complex

Gun Binzet; Ulrich Flörke; Nevzat Külcü; Hakan Arslan

doi:10.5155/eurjchem.3.1.37-39.591

European Journal of Chemistry 2012, 3(1), 37-39 | doi: https://doi.org/10.5155/eurjchem.3.1.37-39.591 | Get rights and content

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Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex

Gun Binzet ^(1,*)

, Ulrich Flörke ⁽²⁾

, Nevzat Külcü ⁽³⁾

, Hakan Arslan ⁽⁴⁾

⁽¹⁾ Science Education, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
⁽²⁾ Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
⁽³⁾ Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
⁽⁴⁾ Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
^(*) Corresponding Author

Received: 31 Jan 2012 | Accepted: 06 Feb 2012 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract

We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C₂₄H₂₈Br₂NiN₄O₂S_2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P2₁/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)^o and V = 2762.5(6) Å³. In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

3_1_37_39_800

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Editor-in-Chief
European Journal of Chemistry

Keywords

Thiourea; Benzamide; Nickel complex; Benzoylthiourea; Crystal structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.3.1.37-39.591

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Funding information

Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).

Citations

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[3]. Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Journal of Chemistry 2013, 1, 2013
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[4]. Rodrigo S. Correa, Katia M. Oliveira, Hiram Pérez, Ana M. Plutín, Raúl Ramos, Raúl Mocelo, Eduardo E. Castellano, Alzir A. Batista
cis-bis(N-benzoyl-N′,N′-dibenzylthioureido)platinum(II): Synthesis, molecular structure and its interaction with human and bovine serum albumin
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[5]. Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
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[6]. K.H. Kumar Naik, B. Ashok, Nagaraja Naik, Jameel Ahmed S. Mulla, Avinash Prakasha
DNA binding, anti-inflammatory and analgesic evaluation of metal complexes of N/S/O donor ligands; Synthesis, spectral characterization
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[10]. Gun Binzet, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
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European Journal of Chemistry 3(2), 211, 2012
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Supporting information

The Supplementary Material for this article can be found online at: Supplementary files

How to cite

Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591

Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591

Binzet, G., Flörke, U., Külcü, N., & Arslan, H. (2012). Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. European Journal of Chemistry, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591

Binzet, Gun, Ulrich Flörke, Nevzat Külcü, & Hakan Arslan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex." European Journal of Chemistry [Online], 3.1 (2012): 37-39. Web. 4 Oct. 2023

Binzet, Gun, Flörke, Ulrich, Külcü, Nevzat, AND Arslan, Hakan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

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