European Journal of Chemistry 2012, 3(2), 211-213 | doi: https://doi.org/10.5155/eurjchem.3.2.211-213.594 | Get rights and content

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Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex


Gun Binzet (1,*) , Ulrich Flörke (2) , Nevzat Külcü (3) , Hakan Arslan (4)

(1) Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author

Received: 06 Feb 2012 | Accepted: 13 Feb 2012 | Published: 30 Jun 2012 | Issue Date: June 2012

Abstract


The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o , Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.


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European Journal of Chemistry

Keywords


Thiourea; Benzamide; Copper complex; Benzoylthiourea; Crystal structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.3.2.211-213.594

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Funding information


Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).

Citations

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[1]. Lan‐Xin Peng, Dan Wang, De‐Xiang Zhang, Zhi‐Jiao Zhang, Qi Zhou, Hai‐Pu Li, Ying Yang
Synthesis and Characterization of Copper(I) Halide Complexes Prepared with Bipodal Diacylthioureas
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DOI: 10.1002/ejic.202000312
/

[2]. Sajjad H. Sumrra, Muhammad Hanif, Zahid H. Chohan, Muhammad Safwan Akram, Javeed Akhtar, Saad M. Al-Shehri
Metal based drugs: design, synthesis and in-vitro antimicrobial screening of Co(II), Ni(II), Cu(II) and Zn(II) complexes with some new carboxamide derived compounds: crystal structures of N-[ethyl(propan-2-yl)carbamothioyl]thiophene-2-carboxamide and its copper(II) complex
Journal of Enzyme Inhibition and Medicinal Chemistry  31(4), 590, 2016
DOI: 10.3109/14756366.2015.1050011
/

[3]. Xianhui Hou, Fanfan Wang, Li Han, Xia Pan, Haipu Li, Ying Yang, Herbert W. Roesky
Self‐Assembly of Discrete Copper(I)‐Halide Complexes with Diacylthioureas
Zeitschrift für anorganische und allgemeine Chemie  644(3), 142, 2018
DOI: 10.1002/zaac.201700430
/

[4]. Cemal Koray Ozer, Gun Binzet, Hakan Arslan
Crystal and molecular structure of bis(N-(diethylcarbamothioyl)cyclohexane carboxamido)copper(II) complex
European Journal of Chemistry  11(4), 319, 2020
DOI: 10.5155/eurjchem.11.4.319-323.2047
/

[5]. Ebru Keskin, Ummuhan Solmaz, Gun Binzet, Ilkay Gumus, Hakan Arslan
Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands
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DOI: 10.5155/eurjchem.9.4.360-368.1774
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[6]. Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
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DOI: 10.1155/2013/536562
/

[7]. Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
A review on the chemistry, coordination, structure and biological properties of 1-(acyl/aroyl)-3-(substituted) thioureas
Journal of Sulfur Chemistry  35(3), 318, 2014
DOI: 10.1080/17415993.2013.834904
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[8]. Su-Yun Wu, Xiao-Ya Zhao, Hai-Pu Li, Ying Yang, Herbert W. Roesky
Synthesis and Characterization ofN,N-Di-substituted Acylthiourea Copper(II) Complexes
Zeitschrift für anorganische und allgemeine Chemie  641(5), 883, 2015
DOI: 10.1002/zaac.201400605
/

[9]. Rodrigo S. Correa, Katia M. Oliveira, Hiram Pérez, Ana M. Plutín, Raúl Ramos, Raúl Mocelo, Eduardo E. Castellano, Alzir A. Batista
cis-bis(N-benzoyl-N′,N′-dibenzylthioureido)platinum(II): Synthesis, molecular structure and its interaction with human and bovine serum albumin
Arabian Journal of Chemistry  12(8), 3454, 2019
DOI: 10.1016/j.arabjc.2015.10.006
/

[10]. Ilkay Gumus, Serpil Gonca, Birdal Arslan, Ebru Keskin, Ummuhan Solmaz, Hakan Arslan
N-(Dibenzylcarbamothioyl)-3-methylbutanamide: Crystal structure, Hirshfeld surfaces and antimicrobial activity
European Journal of Chemistry  8(4), 410, 2017
DOI: 10.5155/eurjchem.8.4.410-416.1650
/

[11]. Ramakrishnan Elancheran, Balakrishnan Karthikeyan, Subramanian Srinivasan, Kuppusamy Krishnasamy, Senthamaraikannan Kabilan
Synthesis, crystal structure, DFT and Hirshfeld surface analysis of 4-fluoro-N-(1,3-dioxoisoindolin-2-yl)benzamide
European Journal of Chemistry  14(1), 1, 2023
DOI: 10.5155/eurjchem.14.1.1-8.2335
/

[12]. Dan Wang, Su‐Yun Wu, Hai‐Pu Li, Ying Yang, Herbert W. Roesky
Synthesis and Characterization of Copper Complexes with the N ‐(2,6‐Diisopropylphenyl)‐ N′ ‐acylthiourea Ligands
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DOI: 10.1002/ejic.201601451
/

References


[1]. Ilis, M.; Bucos, M.; Dumirtrascu, F.; Circu, V. J. Mol. Struc. 2011, 987, 1-6.
http://dx.doi.org/10.1016/j.molstruc.2010.11.037

[2]. Beyer, L.; Hoyer, J.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21(3), 81-91.

[3]. Muhl, P.; Gloe, K.; Dietze, F.; Hoyer, E.; Beyer, L. Z. Chem. 1986, 26(3), 81-94.

[4]. Koch, K. R. Coord. Chem. Rev. 2001, 216, 473-488.
http://dx.doi.org/10.1016/S0010-8545(01)00337-X

[5]. Mansuroglu, D. S.; Arslan, H.; VanDerveer, D.; Binzet G. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(12), 3221-3230.
http://dx.doi.org/10.1080/10426500902979743

[6]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[7]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14(1), 519-527.
http://dx.doi.org/10.3390/molecules14010519
PMid:19169199

[8]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120

[9]. Campo, R. D.; Criado, J. J.; Garcia, E.; Hermosa, M. R.; Jimenez-Sanchez, A.; Manzano, J. L.; Monte, E. Rodriguez-Fernandez, E.; Sanz, F. J. Inorg. Biochem. 2002, 89(1-2), 74-82.
PMid:11931966

[10]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1(3), 221-227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124

[11]. Abdel, H. M. H.; Gad-Elkareem, M. A. M. G. E.; El-Adasy, A. B. A. E. A. A. M.; Othman, I. M. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(9), 2263-2280.
http://dx.doi.org/10.1080/10426500802453658

[12]. Khan, M. H.; Bano, Q.; Nızamuddin. J. Agr. Food Chem. 1995, 43(10), 2719-2721.
http://dx.doi.org/10.1021/jf00058a032

[13]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt. A. J. Chem. Soc. Dalton Trans. 2000, 24, 4579-4585.
http://dx.doi.org/10.1039/b007589m

[14]. Fuks, L.; Anuszewska, E.; Kruszewska, H.; Krowczynski, A.; Dudek, J.; Sadlej-Sosnowska, N. Trans. Metal Chem. 2010, 35(6), 639-647.
http://dx.doi.org/10.1007/s11243-010-9375-9

[15]. Khan, H.; Ahmed, M. J.; Branger, M. I. Anal. Sci. 2005, 21(5), 507-512.
http://dx.doi.org/10.2116/analsci.21.507
PMid:15913137

[16]. Saeed, A.; Khera, R. A.; Abbas, N.; Latif, M.; Sajıd, I.; Flörke, U. Turk. J. Chem. 2010, 34, 335-345.

[17]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[18]. Mansuroglu, D. S.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[19]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2009, 62(21), 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[20]. Ugur, D.; Arslan, H.; Kulcu, N. Russ. J. Coord. Chem. 2006, 32, 669-675.
http://dx.doi.org/10.1134/S1070328406090089

[21]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Kulcu, N. Molecules 2009, 14(2), 655-666.
http://dx.doi.org/10.3390/molecules14020655
PMid:19214154

[22]. Avsar, G.; Arslan, H.; Haupt, H. J.; Kulcu, N. Turk. J. Chem. 2003, 27, 281-285.

[23]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[24]. Arslan, H.; Kulcu, N.; Florke, U. Transit. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[25]. Arslan, H.; Florke, U.; Kulcu, N. J. Chem. Crystallogr. 2003, 33, 919-924.
http://dx.doi.org/10.1023/A:1027429814989

[26]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o452-u1183.
http://dx.doi.org/10.1107/S1600536809003511
PMid:21582125 PMCid:2968555

[27]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o427-u306.
http://dx.doi.org/10.1107/S1600536809003183
PMid:21582014 PMCid:2968358

[28]. Yesilkaynak, T.; Binzet, G.; Emen, F. M.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3

[29]. Avsar, G.; Kulcu, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607-615.

[30]. Ozpozan, N.; Ozpozan, T.; Arslan, H.; Karipcin, F.; Kulcu, N. Thermochim. Acta 1999, 336, 97-103.
http://dx.doi.org/10.1016/S0040-6031(99)00208-7

[31]. Ozpozan, N.; Arslan, H.; Ozpozan, T.; Merdivan, M.; Kulcu, N. J. Therm. Anal. Calorim. 2000, 61, 955-965.
http://dx.doi.org/10.1023/A:1010171230450

[32]. Bruker. SMART (Version 5. 62), SHELXTL (Version 6. 10) and SADABS (Version 2. 03), Bruker AXS Inc., Madison, Wisconsin, USA (2002).

[33]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930
PMid:18156677

[34]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. Appl. Cryst. J. 2009, 42, 339-341.
http://dx.doi.org/10.1107/S0021889808042726

[35]. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.,; Taylor, R.; Towler, M.; Van de Streek, J. J. Appl. Cryst. 2006, 39, 453-457.
http://dx.doi.org/10.1107/S002188980600731X

[36]. Saeed, S.; Rashid, N.; Jones, P.; Hussain, R. Eur. J. Chem. 2011, 2(1), 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[37]. Saeed, A.; Mumtaz, A.; Florke, U. Eur. J. Chem. 2010, 1(2), 73-75.
http://dx.doi.org/10.5155/eurjchem.1.2.73-75.34

[38]. Arslan, H.; Flörke, U.; Mansuroglu, D. S. E-J. Chem. 2011, 8(S1), S455-S461.

[39]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39.
http://dx.doi.org/10.5155/eurjchem.3.1.37-39.591

[40]. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor. R. J. Chem. Soc. Perkin Trans. 1987, 2, S1-19.
http://dx.doi.org/10.1039/p298700000s1


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex. Eur. J. Chem. 2012, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, G., Flörke, U., Külcü, N., & Arslan, H. (2012). Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex. European Journal of Chemistry, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, Gun, Ulrich Flörke, Nevzat Külcü, & Hakan Arslan. "Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex." European Journal of Chemistry [Online], 3.2 (2012): 211-213. Web. 30 Sep. 2023
Binzet, Gun, Flörke, Ulrich, Külcü, Nevzat, AND Arslan, Hakan. "Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex" European Journal of Chemistry [Online], Volume 3 Number 2 (30 June 2012)

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