Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex

Gun Binzet; Ulrich Flörke; Nevzat Külcü; Hakan Arslan

doi:10.5155/eurjchem.3.2.211-213.594

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Published: Jun 30, 2012

DOI: https://doi.org/10.5155/eurjchem.3.2.211-213.594

Keywords:

Thiourea, Benzamide, Copper complex, Benzoylthiourea, Crystal structure, Single crystal X‐ray diffraction

Section

Research Article

Issue

Vol. 3 No. 2 (2012): June 2012

Dates

Received 2012-02-06
Accepted 2012-02-13
Published 2012-06-30

Gun Binzet

Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey

Ulrich Flörke

Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany

Nevzat Külcü

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Hakan Arslan

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Abstract

The title compound, C₃₂H₄₄Br₂CuN₄O₂S₂, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)^o, β = 85.59(3)^o, γ = 89.46(2)^o , Z = 4 and V = 795.8(6) Å³. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.

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Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and Molecular Structure of bis(4-Bromo-N-(di-N-butylcarbamothioyl)benzamido) copper(II) Complex. Eur. J. Chem. 2012, 3, 211-213.

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Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).

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