Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex

Gun Binzet; Ulrich Flörke; Nevzat Külcü; Hakan Arslan

doi:10.5155/eurjchem.3.2.211-213.594

PDF CIF FILE

Published: Jun 30, 2012

DOI: https://doi.org/10.5155/eurjchem.3.2.211-213.594

Keywords:

Thiourea, Benzamide, Copper complex, Benzoylthiourea, Crystal structure, Single crystal X‐ray diffraction

Section

Research Article

Issue

Vol. 3 No. 2 (2012): June 2012

Dates

Received 2012-02-06
Accepted 2012-02-13
Published 2012-06-30

Gun Binzet

Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey

Ulrich Flörke

Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany

Nevzat Külcü

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Hakan Arslan

Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey

Abstract

The title compound, C₃₂H₄₄Br₂CuN₄O₂S₂, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)^o, β = 85.59(3)^o, γ = 89.46(2)^o , Z = 4 and V = 795.8(6) Å³. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.

This Abstract was viewed 3228 times |

Article PDF downloaded 886 times

Article CIF FILE downloaded 0 times

How to Cite

(1)

Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and Molecular Structure of bis(4-Bromo-N-(di-N-butylcarbamothioyl)benzamido) copper(II) Complex. Eur. J. Chem. 2012, 3, 211-213.

Links for Article

Crossref - Scopus - Google - European PMC

References

[1]. Ilis, M.; Bucos, M.; Dumirtrascu, F.; Circu, V. J. Mol. Struc. 2011, 987, 1-6.
http://dx.doi.org/10.1016/j.molstruc.2010.11.037

[2]. Beyer, L.; Hoyer, J.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21(3), 81-91.

[3]. Muhl, P.; Gloe, K.; Dietze, F.; Hoyer, E.; Beyer, L. Z. Chem. 1986, 26(3), 81-94.

[4]. Koch, K. R. Coord. Chem. Rev. 2001, 216, 473-488.
http://dx.doi.org/10.1016/S0010-8545(01)00337-X

[5]. Mansuroglu, D. S.; Arslan, H.; VanDerveer, D.; Binzet G. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(12), 3221-3230.
http://dx.doi.org/10.1080/10426500902979743

[6]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[7]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14(1), 519-527.
http://dx.doi.org/10.3390/molecules14010519
PMid:19169199

[8]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120

[9]. Campo, R. D.; Criado, J. J.; Garcia, E.; Hermosa, M. R.; Jimenez-Sanchez, A.; Manzano, J. L.; Monte, E. Rodriguez-Fernandez, E.; Sanz, F. J. Inorg. Biochem. 2002, 89(1-2), 74-82.
PMid:11931966

[10]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1(3), 221-227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124

[11]. Abdel, H. M. H.; Gad-Elkareem, M. A. M. G. E.; El-Adasy, A. B. A. E. A. A. M.; Othman, I. M. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(9), 2263-2280.
http://dx.doi.org/10.1080/10426500802453658

[12]. Khan, M. H.; Bano, Q.; Nızamuddin. J. Agr. Food Chem. 1995, 43(10), 2719-2721.
http://dx.doi.org/10.1021/jf00058a032

[13]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt. A. J. Chem. Soc. Dalton Trans. 2000, 24, 4579-4585.
http://dx.doi.org/10.1039/b007589m

[14]. Fuks, L.; Anuszewska, E.; Kruszewska, H.; Krowczynski, A.; Dudek, J.; Sadlej-Sosnowska, N. Trans. Metal Chem. 2010, 35(6), 639-647.
http://dx.doi.org/10.1007/s11243-010-9375-9

[15]. Khan, H.; Ahmed, M. J.; Branger, M. I. Anal. Sci. 2005, 21(5), 507-512.
http://dx.doi.org/10.2116/analsci.21.507
PMid:15913137

[16]. Saeed, A.; Khera, R. A.; Abbas, N.; Latif, M.; Sajıd, I.; Flörke, U. Turk. J. Chem. 2010, 34, 335-345.

[17]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[18]. Mansuroglu, D. S.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[19]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2009, 62(21), 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[20]. Ugur, D.; Arslan, H.; Kulcu, N. Russ. J. Coord. Chem. 2006, 32, 669-675.
http://dx.doi.org/10.1134/S1070328406090089

[21]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Kulcu, N. Molecules 2009, 14(2), 655-666.
http://dx.doi.org/10.3390/molecules14020655
PMid:19214154

[22]. Avsar, G.; Arslan, H.; Haupt, H. J.; Kulcu, N. Turk. J. Chem. 2003, 27, 281-285.

[23]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[24]. Arslan, H.; Kulcu, N.; Florke, U. Transit. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[25]. Arslan, H.; Florke, U.; Kulcu, N. J. Chem. Crystallogr. 2003, 33, 919-924.
http://dx.doi.org/10.1023/A:1027429814989

[26]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o452-u1183.
http://dx.doi.org/10.1107/S1600536809003511
PMid:21582125 PMCid:2968555

[27]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o427-u306.
http://dx.doi.org/10.1107/S1600536809003183
PMid:21582014 PMCid:2968358

[28]. Yesilkaynak, T.; Binzet, G.; Emen, F. M.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3

[29]. Avsar, G.; Kulcu, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607-615.

[30]. Ozpozan, N.; Ozpozan, T.; Arslan, H.; Karipcin, F.; Kulcu, N. Thermochim. Acta 1999, 336, 97-103.
http://dx.doi.org/10.1016/S0040-6031(99)00208-7

[31]. Ozpozan, N.; Arslan, H.; Ozpozan, T.; Merdivan, M.; Kulcu, N. J. Therm. Anal. Calorim. 2000, 61, 955-965.
http://dx.doi.org/10.1023/A:1010171230450

[32]. Bruker. SMART (Version 5. 62), SHELXTL (Version 6. 10) and SADABS (Version 2. 03), Bruker AXS Inc., Madison, Wisconsin, USA (2002).

[33]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930
PMid:18156677

[34]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. Appl. Cryst. J. 2009, 42, 339-341.
http://dx.doi.org/10.1107/S0021889808042726

[35]. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.,; Taylor, R.; Towler, M.; Van de Streek, J. J. Appl. Cryst. 2006, 39, 453-457.
http://dx.doi.org/10.1107/S002188980600731X

[36]. Saeed, S.; Rashid, N.; Jones, P.; Hussain, R. Eur. J. Chem. 2011, 2(1), 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[37]. Saeed, A.; Mumtaz, A.; Florke, U. Eur. J. Chem. 2010, 1(2), 73-75.
http://dx.doi.org/10.5155/eurjchem.1.2.73-75.34

[38]. Arslan, H.; Flörke, U.; Mansuroglu, D. S. E-J. Chem. 2011, 8(S1), S455-S461.

[39]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39.
http://dx.doi.org/10.5155/eurjchem.3.1.37-39.591

[40]. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor. R. J. Chem. Soc. Perkin Trans. 1987, 2, S1-19.
http://dx.doi.org/10.1039/p298700000s1

Supporting Agencies

Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).

Most read articles by the same author(s)

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)

Downloads

Metrics