

Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex
Gun Binzet (1,*)




(1) Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author
Received: 06 Feb 2012 | Accepted: 13 Feb 2012 | Published: 30 Jun 2012 | Issue Date: June 2012
Abstract
The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o , Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.
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DOI: 10.5155/eurjchem.3.2.211-213.594
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Funding information
Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).
Citations
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