European Journal of Chemistry

Synthesis, structure and hydrogen sorption properties of a pyrazine-bridged copper(I) nitrate metal-organic framework

Article Sidebar

PDF CIF FILE
Published: Sep 30, 2019
DOI: https://doi.org/10.5155/eurjchem.10.3.195-200.1888
Keywords:
Copper, Pyrazine, Hydrogen sorption, X-ray crystallography, Single crystal structure, Metal-organic framework
Section
Research Article
Issue
Vol. 10 No. 3 (2019): September 2019
Dates
Received 2019-05-06
Accepted 2019-06-14
Published 2019-09-30
Crossmark


Main Article Content

Emmanuel Ngwang Nfor
Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
http://orcid.org/0000-0003-4941-3917
Andrew David Burrows
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom
http://orcid.org/0000-0002-9268-4408
Bridget Ndoye Ndosiri
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0001-7969-8963
Luke Lawrence Keenan
Diamond Light Source, Didcot, Oxfordshire, OX11 0DE, United Kingdom
http://orcid.org/0000-0001-9892-7864
Offiong Efanga Offiong
Department of Pure and Applied Chemistry, University of Calabar, PMB 1115, Calabar, CRS, Nigeria
http://orcid.org/0000-0002-7784-4821

Abstract

A new copper(I) pyrazine-bridged coordination polymer [Cu2(pyz)3(NO3)2]·2DMF] (pyz = pyrazine) (1) has been synthesized and characterized by FT-IR, TG/DTG, DSC and single crystal X-ray diffraction techniques. The X-ray crystallographic result reveals a two-dimensional network structure containing hexagonal pores. Thermal analysis of compound 1 reveals it is stable to 380 °C, and gas sorption studies showed that it adsorbs 1.04 wt% hydrogen at 1 atm and 77 K. Compound 1 crystallizes in a triclinic system, space group P-1 (no. 2), a = 7.9550(2) Å, b = 7.9810(2) Å, c = 11.0660(3) Å, α = 76.328(1)°, β = 71.115(1)°, γ = 84.577(1)°, V = 645.79(3) Å3, Z = 2, T = 150(2) K, μ(MoKα) = 1.709 mm-1, Dcalc = 1.639 g/cm3, 11111 reflections measured (7° ≤ 2Θ ≤ 54.96°), 2951 unique (Rint = 0.0539) which were used in all calculations. The final R1 was 0.0346 (>2σ(I)) and wR2 was 0.0727 (all data).


icon graph This Abstract was viewed 1887 times | icon graph Article PDF downloaded 769 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Nfor, E. N.; Burrows, A. D.; Ndosiri, B. N.; Keenan, L. L.; Offiong, O. E. Synthesis, Structure and Hydrogen Sorption Properties of a Pyrazine-Bridged copper(I) Nitrate Metal-Organic Framework. Eur. J. Chem. 2019, 10, 195-200.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Batten, S. R.; Robson, R. Angew. Chem. Int. Ed. 1998, 37, 1460-1494.
https://doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z

[2]. Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; O'Keeffe, M.; Yaghi, O. M. Science 2002, 295, 469-472.

[3]. Farrusseng, D.; Aguado, S.; Pinel, C. Angew. Chem. Int. Ed. 2009, 48, 7502-7513.
https://doi.org/10.1002/anie.200806063

[4]. Rowsel, J. L. C.; Yaghi, O. M. Angew. Chem. Int. Ed. 2005, 44, 4670-4679.
https://doi.org/10.1002/anie.200462786

[5]. Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853-908.
https://doi.org/10.1021/cr9601324

[6]. Cheng, X.; Liu, T.; Duan, X.; Wang, F.; Meng, Q.; Lu, C.; Cryst. Eng. Comm. 2011, 13, 1314-1321.
https://doi.org/10.1039/C0CE00360C

[7]. Zang, S.; Su, Y.; Li, S.; Ni, Z.; Meng, Q. Inorg. Chem. 2006, 45(1), 174-180.
https://doi.org/10.1021/ic051502m

[8]. Hasegawa, S.; Horike, S.; Matsuda, R.; Furukawa, S.; Mochizuki, K.; Kinoshita, Y.; Kitagawa, S. J. Am. Chem. Soc. 2007, 129, 2607-2614.
https://doi.org/10.1021/ja067374y

[9]. Arici, M.; Yesilel, O. Z.; Keskin, S.; Tas, M. Polyhedron 2012, 45, 103-106.
https://doi.org/10.1016/j.poly.2012.07.060

[10]. Horcajada, P.; Serre, C.; Vallet-Regi, M.; Sebban, M.; Taulelle, F.; Ferey, G. Angew. Chem. Int. Ed. 2006, 118, 6120-6124.
https://doi.org/10.1002/ange.200601878

[11]. An, J.; Geib, S. J.; Rosi, N. L. J. Am. Chem. Soc. 2009, 131, 8376-8377.
https://doi.org/10.1021/ja902972w

[12]. Taylor-Pashow, K. M. L.; Rocca, J. D.; Xie, Z.; Tran, S.; Lin, W. J. Am. Chem. Soc. 2009, 131, 14261-14263.
https://doi.org/10.1021/ja906198y

[13]. Sethi, N. K. PhD Thesis, Preparation of Heterobimetallic catalyst, York University, 2013.

[14]. Wen, G. L.; Wang, Y. Y.; Zhang, W. H.; Ren, C.; Liu, R. T.; Shi, Q. Z. Cryst. Eng. Comm. 2010, 12, 1238-1251.
https://doi.org/10.1039/B919381M

[15]. Sun, D.; Luo, G. G.; Zhang, N.; Chen, J. H.; Huang, R. B.; Lin, L. R.; Zhang, L. S. Polyhedron 2009, 28, 2983-2988.
https://doi.org/10.1016/j.poly.2009.07.013

[16]. Munakata, M.; Wu, L. P.; Kuroda-Sowa, T.; Maekawa, M.; Moriwaki, K.; Kitagawa, S. Inorg. Chem. 1997, 36(23), 5416-5418.
https://doi.org/10.1021/ic970427f

[17]. Duren, T.; Bae, Y. S.; Snurr, R. Q. Chem. Soc. Rev. 2009, 38, 1237-1247.
https://doi.org/10.1039/b803498m

[18]. Han, S. S.; Mendoza-Cortes, J. L.; Goddard, W. A. Chem. Soc. Rev. 2009, 38, 1460-1476.
https://doi.org/10.1039/b802430h

[19]. Farha, O. K; Hupp. J. T. Accoun. Chem. Res. 2010, 43(8), 1166-1175.
https://doi.org/10.1021/ar1000617

[20]. Real, J. A.; Munno, G. D.; Munoz, M. C.; Julve, M. Inorg. Chem. 1991, 30, 2701-2704.
https://doi.org/10.1021/ic00012a026

[21]. Otieno, T.; Gipson, A. M.; Parkin, S. J. Chem. Crystallogr. 2002, 2(3-4), 81-85.
https://doi.org/10.1023/A:1015612810446

[22]. Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem., Int. Ed. 2004, 43(18), 2334-2375.
https://doi.org/10.1002/anie.200300610

[23]. Navarro, J. A. R.; Barea, E.; Galindo, M. A.; Salas, J. M.; Romero, M. A.; Quiros, M.; Masciocchi, N.; Galli, S.; Sironi, A.; Lippert, B. J. Solid State Chem. 2005, 178, 2436-2451.
https://doi.org/10.1016/j.jssc.2005.05.011

[24]. Ruben, M.; Rojo, J.; Romero-Salquero, F. J.; Uppadine, I. H.; Lehn, J. M. Angew. Chem. Int. Ed. 2004, 43(28), 3644-3662.
https://doi.org/10.1002/anie.200300636

[25]. Lehn, J. M. Supramolecular Chemistry. Concept and Perspectives, VCH, Weinheim, Germany, 1995.
https://doi.org/10.1002/3527607439

[26]. CrysAlis Pro: Data collection and data reduction software package, Agilent Technologies.

[27]. SCALE3 ABSPACK: Empirical absorption correction using spherical harmonics.

[28]. Sheldrick, G. M. Acta Crystallogr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[29]. Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565-565.
https://doi.org/10.1107/S0021889897003117

[30]. Macrae, C. F.; Bruno, I. J.; Chisholm, J. A.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Rodriguez-Monge, L.; Taylor, R.; Van de Streek, J.; Wood, P. A. J. Appl. Crystallogr. 2008, 411, 466-470.
https://doi.org/10.1107/S0021889807067908

[31]. Otieno, T.; Rettig, S. J.; Thompson, R. C.; Trotter, B. Can. J. Chem. 1989, 67(11), 1964-1969.
https://doi.org/10.1139/v89-306

[32]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience: New York, 1986.

[33]. Lo, S. M. F.; Chu, S. S. Y.; Shek, L. Y.; Lin, Z.; Zhang, X. X.; Wen, G. H.; Williams, I. D. J. Am. Chem. Soc. 2000, 122, 6293-6294.

[34]. Santoro, A.; Mighell, A. D.; Reimann, M. R. Acta Crystallogr. B 1970, 26, 979-984.
https://doi.org/10.1107/S056774087000345X

[35]. Kuhlman, R.; Sehimek, G. L.; Kolis, J. W. Polyhedron 1999, 18, 1379-1389.
https://doi.org/10.1016/S0277-5387(98)00425-2

[36]. Darriet, J.; Haddad, M. D.; Duesler, E. N.; Hendrickson, D. N. Inorg. Chem. 1979, 18(10), 2679-2682.
https://doi.org/10.1021/ic50200a008

[37]. Haynes, J. S.; Rettig, S. J.; Sams, J. R.; Thompson, R. C.; Trotter, J. Can. J. Chem. 1987, 65, 420-426.
https://doi.org/10.1139/v87-071

[38]. Belford, R. C. E.; Fenton, D. E.; Truter, M. R. J. Chem. Soc. Dalton Trans. 1974, 17-24.

[39]. The Cambridge Structural Database, Ref. code HUTWOJ; Groom, C. R.; Bruno, I. J.; Lightfoot, M. P.; Ward, S. C. Acta Crystallogr. B 2016, 72, 171-179.
https://doi.org/10.1107/S2052520616003954

[40]. Mohapatra, S.; Maji, T. K. Dalton Trans. 2010, 39, 3412-3419.
https://doi.org/10.1039/b922039a

[41]. Kong, X. J.; Ren, Y. P.; Zheng, P. Q.; Long, L. S.; Huang, R. B.; Zheng, L. S. Inorg. Chem. 2006, 45, 10702-10711.
https://doi.org/10.1021/ic061664y

[42]. Aghajanloo, M.; Rashidi, A. M.; Moosavian, M. A. J. Chem. Eng. Process. Technol. 2014, 5, 1-6.

[43]. Hulvey, Z.; Sava, D. A; Eckert, J.; Cheetham. A. K. Inorg. Chem. 2011, 50, 403-405.
https://doi.org/10.1021/ic101153c

Supporting Agencies

Commonwealth Scholarship Commission (CSC) for Research Fellowship and Department of Chemistry, University of Bath, United Kingdom.
Most read articles by the same author(s)

Most read articles by the same author(s)

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).