European Journal of Chemistry

Synthesis, structure and hydrogen sorption properties of a pyrazine-bridged copper(I) nitrate metal-organic framework

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Published: Sep 30, 2019
DOI: https://doi.org/10.5155/eurjchem.10.3.195-200.1888
Keywords:
Copper, Pyrazine, Hydrogen sorption, X-ray crystallography, Single crystal structure, Metal-organic framework
Section
Research Article
Issue
Vol. 10 No. 3 (2019): September 2019
Dates
Received 2019-05-06
Accepted 2019-06-14
Published 2019-09-30
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Main Article Content

Emmanuel Ngwang Nfor
Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
http://orcid.org/0000-0003-4941-3917
Andrew David Burrows
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom
http://orcid.org/0000-0002-9268-4408
Bridget Ndoye Ndosiri
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0001-7969-8963
Luke Lawrence Keenan
Diamond Light Source, Didcot, Oxfordshire, OX11 0DE, United Kingdom
http://orcid.org/0000-0001-9892-7864
Offiong Efanga Offiong
Department of Pure and Applied Chemistry, University of Calabar, PMB 1115, Calabar, CRS, Nigeria
http://orcid.org/0000-0002-7784-4821

Abstract

A new copper(I) pyrazine-bridged coordination polymer [Cu2(pyz)3(NO3)2]·2DMF] (pyz = pyrazine) (1) has been synthesized and characterized by FT-IR, TG/DTG, DSC and single crystal X-ray diffraction techniques. The X-ray crystallographic result reveals a two-dimensional network structure containing hexagonal pores. Thermal analysis of compound 1 reveals it is stable to 380 °C, and gas sorption studies showed that it adsorbs 1.04 wt% hydrogen at 1 atm and 77 K. Compound 1 crystallizes in a triclinic system, space group P-1 (no. 2), a = 7.9550(2) Å, b = 7.9810(2) Å, c = 11.0660(3) Å, α = 76.328(1)°, β = 71.115(1)°, γ = 84.577(1)°, V = 645.79(3) Å3, Z = 2, T = 150(2) K, μ(MoKα) = 1.709 mm-1, Dcalc = 1.639 g/cm3, 11111 reflections measured (7° ≤ 2Θ ≤ 54.96°), 2951 unique (Rint = 0.0539) which were used in all calculations. The final R1 was 0.0346 (>2σ(I)) and wR2 was 0.0727 (all data).


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Nfor, E. N.; Burrows, A. D.; Ndosiri, B. N.; Keenan, L. L.; Offiong, O. E. Synthesis, Structure and Hydrogen Sorption Properties of a Pyrazine-Bridged copper(I) Nitrate Metal-Organic Framework. Eur. J. Chem. 2019, 10, 195-200.

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Commonwealth Scholarship Commission (CSC) for Research Fellowship and Department of Chemistry, University of Bath, United Kingdom.
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