European Journal of Chemistry

Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide

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Published: Sep 30, 2019
DOI: https://doi.org/10.5155/eurjchem.10.3.267-272.1914
Keywords:
Manganese, Dicyanamide, Photoluminescent, Non-centrosymmetric, Single crystal structure, N-(2-Pyridylmethyl)-(L)-alanine)
Section
Research Article
Issue
Vol. 10 No. 3 (2019): September 2019
Dates
Received 2019-07-05
Accepted 2019-07-31
Published 2019-09-30
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Bridget Ndoye Ndosiri
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0001-7969-8963
Katia Nchimi Nono
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0002-5031-6404
Paboudam Gbambie Awawou
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0002-2194-0072
Emmanuel Ngwang Nfor
Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
http://orcid.org/0000-0003-4941-3917
Aminou Mohamadou
Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims (ICMR), CNRS UMR 7312, UFR des Sciences Exactes et Naturelles, Bâtiment 18 Europol ’Agro, BP 1039, F-51687 Reims Cedex 2, France
http://orcid.org/0000-0002-6140-4186
Jerome Marrot
Institut Lavoisier de Versailles (ILV)-UMR 8180 (CNRS/UVSQ,)45 avenue des États-Unis Bâtiment Lavoisier 78035 Versailles, Cedex, France
http://orcid.org/0000-0002-5351-4908
Peter Ndifon Teke
Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
http://orcid.org/0000-0001-9331-9034

Abstract

The dinuclear compound, [Mn2(Pyala)2(Dca)2(H2O)]n·2H2O (1) (Pyala = N-(2-pyridylmethyl)-L-alanine and Dca = dicyanamide anion) has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction techniques. The crystal data for C22H26Mn2N10O6: orthorhombic, space group P212121 (no. 19), a = 10.3728(8) Å, b = 15.9780(12) Å, c = 16.3585(13) Å, V = 2711.2(4) Å3, Z = 4, T = 198(2) K, μ(MoKα) = 0.989 mm-1, Dcalc = 1.559 g/cm3, 129607 reflections measured (3.564° ≤ 2Θ ≤ 60.046°), 7923 unique (Rint = 0.0324, Rsigma = 0.0155) which were used in all calculations. The final R1 was 0.0169 (I > 2σ(I)) and wR2 was 0.0458 (all data). The obtained non-centrosymmetric dinuclear Mn(II) complex contains two unique Mn(II) cations with similar octahedral coordination environment. Photoluminescent measurements on the complex in the solid state show that it displays strong photoluminescence at 442 nm.


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Ndosiri, B. N.; Nono, K. N.; Awawou, P. G.; Nfor, E. N.; Mohamadou, A.; Marrot, J.; Teke, P. N. Structural and Photoluminescent Studies of Non-Centrosymmetric manganese(II) N-(2-Pyridylmethyl)-(L)-Alanine) Dicyanamide. Eur. J. Chem. 2019, 10, 267-272.

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