European Journal of Chemistry 2017, 8(1), 15-17 | doi: https://doi.org/10.5155/eurjchem.8.1.15-17.1521 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis and X-ray crystallography of N,N'-di(2-hydroxybenzylidene)hydrazine


Sohail Saeed (1,*) , Naghmana Rashid (2) , Shaaban Kamel Mohamed (3)

(1) Department of Chemistry, Research Complex, Allama Iqbal Open University, Islamabad-44000, Pakistan
(2) Department of Chemistry, Research Complex, Allama Iqbal Open University, Islamabad-44000, Pakistan
(3) Division of Chemistry and The Environmental Science, School of Science and The Environment, Manchester Metropolitan University, M15GD, England
(*) Corresponding Author

Received: 18 Dec 2016 | Revised: 07 Jan 2017 | Accepted: 08 Jan 2017 | Published: 31 Mar 2017 | Issue Date: March 2017

Abstract


The biologically active N,N'-di(2-hydroxybenzylidene)hydrazine has been synthesized and specifically characterized by X-ray crystallography. There are two molecules of N,N'-di(2-hydroxybenzylidene)hydrazine, C14H12N2O2, in the unit cell. The N,N'-di(2-hydroxy benzylidene)hydrazine molecule is planar, with maximum deviation from the mean plane being less than 0.028(2) Å. Intramolecular O-H···N hydrogen bonding interactions were observed in the crystal lattice which connected the molecules into chain running along b-axis.


Keywords


Synthesis; Hydrazine; Schiff base; Crystal lattice; Hydroxybenzylidene; X-ray crystallography

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.8.1.15-17.1521

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 630 times | PDF Article downloaded 251 times

Funding information


The National Engineering and Scientific Commission (NESCOM), Islamabad, Pakistan

Citations

/


[1]. Ikram Saadaoui, Fatma Krichen, Bochra Ben Salah, Riadh Ben Mansour, Nabil Miled, Ali Bougatef, Mohamed Kossentini
Design, synthesis and biological evaluation of Schiff bases of 4-amino-1,2,4-triazole derivatives as potent angiotensin converting enzyme inhibitors and antioxidant activities
Journal of Molecular Structure  1180, 344, 2019
DOI: 10.1016/j.molstruc.2018.12.008
/


[2]. Praveen Singh, Ranjeet Kumar, Ashish Kumar Tewari
Hydrogen bonding framework in imidazole derivatives: Crystal structure and Hirshfeld surface analysis
European Journal of Chemistry  11(1), 50, 2020
DOI: 10.5155/eurjchem.11.1.50-59.1945
/


[3]. Manish Kumar Dixit, Mrigendra Dubey
Li+-Induced fluorescent metallogel: a case of ESIPT-CHEF and ICT phenomenon
Physical Chemistry Chemical Physics  20(36), 23762, 2018
DOI: 10.1039/C8CP04579H
/


References

[1]. Rajavel, P.; Senthil, M. S; Anitha, C. E-Journal Chem. 2008, 5(3), 620-626.
https://doi.org/10.1155/2008/583487

[2]. Ugras, H. I.; Basaran, I.; Kilic. T.; Cakir, U. J. Heterocyclic Chem. 2006, 43, 1679-1684.
https://doi.org/10.1002/jhet.5570430639

[3]. Wadher, S. J.; Puranik, M. P.; Karande, N. A.; Yeole, P. G. Int. J. Pharm. Tech. Res. 2009, 1, 22-33.

[4]. Elena, E. F.; Torres, L.; Antonia, M.; Mendialoey, M. A.; Sevela, M. T. Polyhedron 2000, 19, 441-451.
https://doi.org/10.1016/S0277-5387(99)00383-6

[5]. Mohamed, G. G.; Omar, M. M.; Hindy, A. M. Turk. J. Chem. 2006, 30, 361-382.

[6]. Siddiqui, H. L.; Iqbal, A.; Ahmad, S.; Weaver, G. W. Molecules 2006, 11, 206-211.
https://doi.org/10.3390/11020206

[7]. Oxford Diffraction, CrysAlis PRO and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, Oxfordshire, England, 2010.

[8]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Saeed, S.; Rashid, N.; Mohamed, S. Eur. J. Chem. 2017, 8(1), 15-17. doi:10.5155/eurjchem.8.1.15-17.1521
Saeed, S.; Rashid, N.; Mohamed, S. Synthesis and X-ray crystallography of N,N'-di(2-hydroxybenzylidene)hydrazine. Eur. J. Chem. 2017, 8(1), 15-17. doi:10.5155/eurjchem.8.1.15-17.1521
Saeed, S., Rashid, N., & Mohamed, S. (2017). Synthesis and X-ray crystallography of N,N'-di(2-hydroxybenzylidene)hydrazine. European Journal of Chemistry, 8(1), 15-17. doi:10.5155/eurjchem.8.1.15-17.1521
Saeed, Sohail, Naghmana Rashid, & Shaaban Kamel Mohamed. "Synthesis and X-ray crystallography of N,N'-di(2-hydroxybenzylidene)hydrazine." European Journal of Chemistry [Online], 8.1 (2017): 15-17. Web. 26 Oct. 2020
Saeed, Sohail, Rashid, Naghmana, AND Mohamed, Shaaban. "Synthesis and X-ray crystallography of N,N'-di(2-hydroxybenzylidene)hydrazine" European Journal of Chemistry [Online], Volume 8 Number 1 (31 March 2017)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.8.1.15-17.1521

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2017, 8(1), 15-17 | doi: https://doi.org/10.5155/eurjchem.8.1.15-17.1521 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.