European Journal of Chemistry 2017, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557

Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine


Mbosse Ndiaye Gueye (1) , Moussa Dieng (2) , Djiby Lo (3) , Ibrahima Elhadji Thiam (4) , Aliou Hamady Barry (5) , Mohamed Gaye (6,*) , Abdou Salam Sall (7) , Pascal Retailleau (8)

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(5) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(6) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(7) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(8) Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS-UPR2301, Gif sur Yvette, 91198, France
(*) Corresponding Author

Received: 22 Feb 2017, Accepted: 01 Apr 2017, Published: 30 Jun 2017

Abstract


Two isotype mononuclear yttrium(III) and erbium(III) complexes, {[Y(HL)(OAc)2(H2O)2]. (H2O)∙(NO3)} (1) and {[Er(HL) (OAc)2(H2O)2].(H2O)∙(NO3)} (2), where HL is the neutral Schiff base ligand 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine, and OAc is the acetate anion, have been synthesized and characterized by physicochemical methods and single crystal X-ray determination. Both complexes crystallizes in the triclinic space group Pī with unit cell dimensions for complex of Y(III) a = 7.909 (2) Å, b = 11.718 (4) Å, c = 12.497 (3) Å,    α = 78.907 (3)°, b = 73.840 (3)°, γ = 72.074 (3)°, V = 1051.26 (6) Å3, Z = 2, R1 = 0.051 and    wR2 = 0.112 and for complex of Er(III)a = 7.913 (1) Å, b = 11.719 (2) Å, c = 12.487 (2) Å,          α = 78.832 (1)°, α = 73.674 (1)°, γ = 72.012 (1)°, V = 1049.64 (3) Å3, Z = 2, R1 = 0.028, and   wR2 = 0.062. In both complexes, the coordination polyhedra around Ln(III) atoms are best described as a distorted tricapped trigonal prism. Antioxidant activities of the ligand and its Y(III) and Er(III) complexes are studied.


Keywords


Complex; Schiff base; Crystal structure; NMR spectroscopy; Antioxidant activity; Magnetic properties

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.8.2.137-143.1557

Article Metrics


This Abstract was viewed 481 times | PDF Article downloaded 145 times

Citations

/


[1]. Mamour Sarr, Mayoro Diop, Elhadj Ibrahima Thiam, Aliou Hamady Barry, Mohamed Gaye, Pascal Retailleau
Crystal structure of aquachlorido(nitrato-κ2 O,O′)[1-(pyridin-2-yl-κN)-2-(pyridin-2-ylmethylidene-κN)hydrazine-κN 2]manganase(II)
Acta Crystallographica Section E Crystallographic Communications  74(4), 450, 2018
DOI: 10.1107/S2056989018003493
/


References

[1]. Biswas, S.; Diaz, C.; Ghosh, A. Polyhedron 2013, 51, 96-101.
https://doi.org/10.1016/j.poly.2012.12.019

[2]. Kaabi, I.; Sibous, L.; Douadi, T.; Chafaa, S. J. Mol. Struct. 2015, 1084, 216-222.
https://doi.org/10.1016/j.molstruc.2014.12.023

[3]. Bhattacharjee, C. R.; Goswami, P.; Mondal, P. Inorg. Chim. Acta 2012, 387, 86-92.
https://doi.org/10.1016/j.ica.2011.12.056

[4]. Wang, W. M.; Ren, Y. H.; Wang, S.; Zhang, C. F.; Wu, Z. L.; Zhang, H.; Fang, M. Inorg. Chim. Acta 2016, 453, 452-456.
https://doi.org/10.1016/j.ica.2016.09.002

[5]. Gu, Z. G.; Pang, C. Y.; Qiu, D.; Zhang, J.; Huang, J. L.; Qin, L. F.; Sun, A. Q.; Li, Z. Inorg. Chem. Commun. 2013, 35, 164-168.
https://doi.org/10.1016/j.inoche.2013.06.025

[6]. Gorczynski, A.; Zaranek, M.; Witomska, S.; Bocian, A.; Stefankiewicz, A. R.; Kubicki, M.; Patroniak, V.; Pawluc, P. Catal. Commun. 2016, 78, 71-74.
https://doi.org/10.1016/j.catcom.2016.02.009

[7]. Al Zoubi, W.; Ko, Y. G. J. Organomet. Chem. 2016, 822, 173-188.
https://doi.org/10.1016/j.jorganchem.2016.08.023

[8]. Sarıoglu, A. O.; Ceylan, U.; Yalcin, S. P.; Sonmez, M.; Ceyhan, G.; Aygun, M. J. Lumin. 2016, 176, 193-201.
https://doi.org/10.1016/j.jlumin.2016.03.021

[9]. Hui, Y.; Feng, W.; Wei, T.; Lu, X.; Song, J.; Zhao, S.; Wong, W. K.; Jones, R. A. Inorg. Chem. Commun. 2011, 14, 200-204.
https://doi.org/10.1016/j.inoche.2010.10.022

[10]. Cristovao, B.; Hnatejko, Z. J. Mol. Struct. 2015, 1088, 50-55.
https://doi.org/10.1016/j.molstruc.2015.01.032

[11]. Cristovao, B.; Klak, J.; Pelka, R.; Miroslaw, B.; Hnatejko, Z. Polyhedron 2014, 68, 180-190.
https://doi.org/10.1016/j.poly.2013.10.019

[12]. Anacona, J. R.; Rincones, M. Spectrochim. Acta A 2015, 141, 169-175.
https://doi.org/10.1016/j.saa.2015.01.009

[13]. Soliman, A. A.; Amin, M. A.; El-Sherif, A. A.; Ozdemir, S.; Varlikli, C.; Zafer, C. Dyes Pigm. 2013, 99, 1056-1064.
https://doi.org/10.1016/j.dyepig.2013.08.007

[14]. Sarkar, A.; Pal, S. Polyhedron 2006, 25, 1689-1694.
https://doi.org/10.1016/j.poly.2005.11.009

[15]. Meng, Z.; Liu, J. L.; Leng, J. D.; Guo, F. S.; Tong, M. L. Polyhedron 2011, 30, 3095-3099.
https://doi.org/10.1016/j.poly.2011.02.043

[16]. Baraniak, E.; Bruce, R. S. L.; Freeman, H. C.; Hair, N. J.; James, J. Inorg. Chem. 1976, 15, 2226-2228.
https://doi.org/10.1021/ic50163a046

[17]. Ito, M.; Hamada, D.; Ono, H.; Matsumoto, N.; Sunatsuki, Y.; Re, N. Inorg. Chim. Acta, 2016, 443, 274-278.
https://doi.org/10.1016/j.ica.2015.12.029

[18]. Kaczmarek, M. T.; Jastrząb, R.; Kubicki, M.; Gierszewski, M.; Sikorski, M. Inorg. Chim. Acta 2015, 430, 108-113.
https://doi.org/10.1016/j.ica.2015.02.026

[19]. Sheldrick, G. M. SHELXTL Version 5. 10, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.

[20]. Sheldrick, G. M. SHELXTL-97, University of Göttingen, Göttingen, Germany, 1997.

[21]. Farrugia, L. J. J. Appl. Cryst. 1997, 30, 565.
https://doi.org/10.1107/S0021889897003117

[22]. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
https://doi.org/10.1016/S0010-8545(00)80009-0

[23]. Vleck, J. H. V.; Frank, A. Phys. Rev. 1929, 34(11), 1494-1496.
https://doi.org/10.1103/PhysRev.34.1494

[24]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed., Wiley-Interscience, New York, 1978.

[25]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
https://doi.org/10.1016/S0010-8545(00)80455-5

[26]. Xie, Q. L.; Li, S. H.; Zhang, D. K.; Zhang, Z. G.; Hu, J. M. Acta Chim. Sin. 1991, 49, 723-728.

[27]. Sonmez, M.; Levent, A.; Sekerci, M. Russ. J. Coord. Chem. 2004, 30, 655-660.
https://doi.org/10.1023/B:RUCO.0000040726.57728.a3

[28]. Fomina, I. G.; Dobrokhotova, Z. V.; Ilyukhin, A. B.; Aleksandrov, G. G.; Kazak, V. O.; Gehman, A. E.; Efimov, N. N.; Bogomyakov, A. S.; Zavorotny, Y. S.; Gerasimova, V. I.; Novotortsev, V. M.; Eremenko, I. L. Polyhedron 2013, 65, 152-160.
https://doi.org/10.1016/j.poly.2013.08.017

[29]. Oliveira, C. A. F.; Silva, F. F.; Malvestiti, I.; S. Malta, V. R.; Dutra, J. D. L.; Costa, N. B.; Freire, R. O.; Alves, S. J. Mol. Struct. 2013, 1041, 61-67.

[30]. Tamboura, F. B.; Haba, P. M.; Gaye, M.; Sall, A. S.; Barry, A. H.; Jouini, T. Polyhedron 2004, 23, 1191-1197.
https://doi.org/10.1016/j.poly.2004.01.014

[31]. Ajlouni, A. M.; Taha, Z. A.; Al-Hassan, K. A.; Anzeh, A. M. A. J. Lumin. 2012, 132, 1357-1363.
https://doi.org/10.1016/j.jlumin.2012.01.013


How to cite


Gueye, M.; Dieng, M.; Lo, D.; Thiam, I.; Barry, A.; Gaye, M.; Sall, A.; Retailleau, P. Eur. J. Chem. 2017, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, M.; Dieng, M.; Lo, D.; Thiam, I.; Barry, A.; Gaye, M.; Sall, A.; Retailleau, P. Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine. Eur. J. Chem. 2017, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, M., Dieng, M., Lo, D., Thiam, I., Barry, A., Gaye, M., Sall, A., & Retailleau, P. (2017). Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine. European Journal of Chemistry, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, Mbosse, Moussa Dieng, Djiby Lo, Ibrahima Elhadji Thiam, Aliou Hamady Barry, Mohamed Gaye, Abdou Salam Sall, & Pascal Retailleau. "Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine." European Journal of Chemistry [Online], 8.2 (2017): 137-143. Web. 13 Nov. 2019
Gueye, Mbosse, Dieng, Moussa, Lo, Djiby, Thiam, Ibrahima, Barry, Aliou, Gaye, Mohamed, Sall, Abdou, AND Retailleau, Pascal. "Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

DOI Link: https://doi.org/10.5155/eurjchem.8.2.137-143.1557

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2019  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.