European Journal of Chemistry 2022, 13(2), 196-205 | doi: https://doi.org/10.5155/eurjchem.13.2.196-205.2253 | Get rights and content

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Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)


Cheikh Ndoye (1) orcid , Gregory Excoffier (2) orcid , Gorgui Awa Seck (3) orcid , Ousmane Diouf (4) orcid , IbraIbrahima Elhadji Thiam (5) orcid , Mamadou Sidibe (6) orcid , Mohamed Gaye (7,*) orcid

(1) Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(2) Spectropole, Fédération des Sciences Chimiques de Marseille, Aix-Marseille Université, Marseille, 13397, France
(3) Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(4) Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(5) Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(6) Spectropole, Fédération des Sciences Chimiques de Marseille, Aix-Marseille Université, Marseille, 13397, France
(7) Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(*) Corresponding Author

Received: 09 Mar 2022 | Revised: 08 Apr 2022 | Accepted: 26 Apr 2022 | Published: 30 Jun 2022 | Issue Date: June 2022

Abstract


The reactions of Schiff base 1-(1-hydroxypropan-2-ylidene)thiosemicarbazide (H2L), with salt of thiocyanate metal (II) (Co, Ni, or Zn), provided one dinuclear and two new mononuclear complexes, formulated respectively as {[Co(LH)2]2·[Co(NCS)4] ·2(MeOH)} (1), {[Ni(H2L)2]·[(NCS)2]} (2) and [Zn(H2L)(NCS)2] (3). These compounds have been studied and characterized by elemental analysis, infrared, and ultraviolet-visible (UV-vis) spectroscopies. The structures of the three complexes have been resolved by X-ray crystallography technique. The dinuclear complex 1 crystallizes in the orthorhombic space group Fdd2 with the following unit cell parameters a = 33.1524 (3) Å, b = 19.3780 (2) Å, c = 13.2533 (2) Å, V = 8514.28 (17) Å3, Z = 16, R1 = 0.025 and wR2 = 0.063, the mononuclear complex 2 crystallizes in the monoclinic space group P21/n with the following unit cell parameters a = 11.5752 (1) Å, b = 12.3253 (1) Å, c = 14.2257 (2) Å, β = 106.855 (1)°, V = 1942 (4) Å3, Z = 4, R1 = 0.038 and wR2 = 0.106 and  the mononuclear complex 3 crystallizes in the monoclinic space group P21/c with the following unit cell parameters a = 6.1121 (2) Å, b = 26.8272 (7)  Å, c = 8.0292 (2) Å, β = 99.876 (3)°, V = 1297.04 (6) Å3, Z = 4, R1 = 0.026 and wR2 = 0.057. The asymmetric unit of Complex 1 contains one cationic unit in which the ligand acts in its monodeprotonated form in tridentate fashion and one half of the anionic unit containing two thiocyanate co-ligands. In complexes 2 and 3, the ligand acts in its neutral form in a tridentate manner. In complex 2, two ligand molecules coordinate the Ni(II) center, and the thiocyanate moieties remains uncoordinated. In complex 3, the Zn(II) is coordinated by one ligand molecule and two thiocyanate groups through their nitrogen atoms. Numerous hydrogen bonds consolidated the structures of complexes 1, 2, and 3 in a three-dimensional network.


Keywords


Complex; Schiff base; Octahedral; Thiocyanate; X-ray diffraction; Square pyramidal

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DOI: 10.5155/eurjchem.13.2.196-205.2253

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Ndoye, C.; Excoffier, G.; Seck, G.; Diouf, O.; Thiam, I.; Sidibe, M.; Gaye, M. Eur. J. Chem. 2022, 13(2), 196-205. doi:10.5155/eurjchem.13.2.196-205.2253
Ndoye, C.; Excoffier, G.; Seck, G.; Diouf, O.; Thiam, I.; Sidibe, M.; Gaye, M. Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II). Eur. J. Chem. 2022, 13(2), 196-205. doi:10.5155/eurjchem.13.2.196-205.2253
Ndoye, C., Excoffier, G., Seck, G., Diouf, O., Thiam, I., Sidibe, M., & Gaye, M. (2022). Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II). European Journal of Chemistry, 13(2), 196-205. doi:10.5155/eurjchem.13.2.196-205.2253
Ndoye, Cheikh, Gregory Excoffier, Gorgui Awa Seck, Ousmane Diouf, IbraIbrahima Elhadji Thiam, Mamadou Sidibe, & Mohamed Gaye. "Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)." European Journal of Chemistry [Online], 13.2 (2022): 196-205. Web. 19 Aug. 2022
Ndoye, Cheikh, Excoffier, Gregory, Seck, Gorgui, Diouf, Ousmane, Thiam, IbraIbrahima, Sidibe, Mamadou, AND Gaye, Mohamed. "Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)" European Journal of Chemistry [Online], Volume 13 Number 2 (30 June 2022)

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