Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand

Mamour Sarr; Mayoro Diop; Ibrahima Elhadj Thiam; Mohamed Gaye; Aliou Hamady Barry; Natalia Alvarez; Javier Ellena

doi:10.5155/eurjchem.9.2.67-73.1688

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Published: Jun 30, 2018

DOI: https://doi.org/10.5155/eurjchem.9.2.67-73.1688

Keywords:

Complex, Antiprism, Co-crystal, Schiff base, Thiocyanate, Heteronuclear

Section

Research Article

Issue

Vol. 9 No. 2 (2018): June 2018

Dates

Received 2018-02-26
Accepted 2018-04-04
Published 2018-06-30

Mamour Sarr

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

http://orcid.org/0000-0003-1736-951X

Mayoro Diop

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

http://orcid.org/0000-0003-3594-4901

Ibrahima Elhadj Thiam

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

http://orcid.org/0000-0002-4595-8445

Mohamed Gaye

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

http://orcid.org/0000-0001-8989-1548

Aliou Hamady Barry

Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania

http://orcid.org/0000-0003-4869-2993

Natalia Alvarez

Facultad de Química, General Flores 2124, UdelaR, Montevideo, 11800, Uruguay

http://orcid.org/0000-0002-6974-2569

Javier Ellena

Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13.560-970, São Carlos, SP, Brazil

http://orcid.org/0000-0002-0676-3098

Abstract

The present investigation describes the synthesis and structural study of a metal-zinc ligand [ZnL.H₂O], which was used to generate three dimensional supramolecular complex formulated as [Y{Zn(L)(SCN)}(SCN)₂].[Y{Zn(L)(SCN)}₂(DMF)₂].(NO₃). The title compound crystallizes in the triclinic space group P-1 with the following unit cell parameters: a = 14.8987(7) Å, b = 15.6725(8) Å, c = 19.2339(10) Å, a = 94.610(4)°, β = 103.857(4)°, γ = 101.473(4)°, V = 4234.4(4) Å³, Z = 2, R₁ = 0.063 and wR₂ = 0.96. For this compound, the structure reveals that one heterodinuclear unit [Y{Zn(L)(SCN)}(SCN)₂] is co-crystallized with a heterotrinuclear unit [Y{Zn(L)(SCN)}₂(DMF)₂].(NO₃). In the dinuclear moiety, the organic molecule acts as a hexadentate ligand and in the trinuclear unit, it acts as a pentadentate ligand with one of the oxygen methoxy group remaining uncoordinated. In both units the coordination environment of the zinc metal can be described as distorted square pyramidal. In the dinuclear unit the Y(III) is hexacoordinated while it is octacoordinated in the trinuclear unit. The environment of the Y(III) can be described as a distorted octahedral geometry in the dinuclear and as a distorted square antiprism in the trinuclear units respectively.

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Sarr, M.; Diop, M.; Thiam, I. E.; Gaye, M.; Barry, A. H.; Alvarez, N.; Ellena, J. Co-Crystal Structure of a Dinuclear (Zn-Y) and a Trinuclear (Zn-Y-Zn) Complexes Derived from a Schiff Base Ligand. Eur. J. Chem. 2018, 9, 67-73.

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Supporting Agencies

The FONDATION SONATEL, Senegal

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