Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine | European Journal of Chemistry

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Published: Jun 30, 2017

DOI: https://doi.org/10.5155/eurjchem.8.2.137-143.1557

Keywords:

Complex, Schiff base, Crystal structure, NMR spectroscopy, Antioxidant activity, Magnetic properties

Section

Research Article

Issue

Vol. 8 No. 2 (2017): June 2017

Dates

Received 2017-02-22
Accepted 2017-04-01
Published 2017-06-30

Mbosse Ndiaye Gueye

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Moussa Dieng

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Djiby Lo

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Ibrahima Elhadji Thiam

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Aliou Hamady Barry

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Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania

Mohamed Gaye

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Abdou Salam Sall

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Pascal Retailleau

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Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS-UPR2301, Gif sur Yvette, 91198, France

Abstract

Two isotype mononuclear yttrium(III) and erbium(III) complexes, {[Y(HL)(OAc)₂(H₂O)₂]. (H₂O)∙(NO₃)} (1) and {[Er(HL) (OAc)₂(H₂O)₂].(H₂O)∙(NO₃)} (2), where HL is the neutral Schiff base ligand 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine, and OAc is the acetate anion, have been synthesized and characterized by physicochemical methods and single crystal X-ray determination. Both complexes crystallizes in the triclinic space group Pī with unit cell dimensions for complex of Y(III) a = 7.909 (2) Å, b = 11.718 (4) Å, c = 12.497 (3) Å, α = 78.907 (3)°, b = 73.840 (3)°, γ = 72.074 (3)°, V = 1051.26 (6) Å³, Z = 2, R₁ = 0.051 and wR₂ = 0.112 and for complex of Er(III)a = 7.913 (1) Å, b = 11.719 (2) Å, c = 12.487 (2) Å, α = 78.832 (1)°, α = 73.674 (1)°, γ = 72.012 (1)°, V = 1049.64 (3) Å³, Z = 2, R₁ = 0.028, and wR₂ = 0.062. In both complexes, the coordination polyhedra around Ln(III) atoms are best described as a distorted tricapped trigonal prism. Antioxidant activities of the ligand and its Y(III) and Er(III) complexes are studied.

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Gueye, M. N.; Dieng, M.; Lo, D.; Thiam, I. E.; Barry, A. H.; Gaye, M.; Sall, A. S.; Retailleau, P. Synthesis, Physical Studies and Crystal Structure Determination of Y(III) and Er(III) Complexes of 1-(pyridin-2-Yl)-2-(pyridine-2-ylmethylene)hydrazine. Eur. J. Chem. 2017, 8, 137-143.

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