European Journal of Chemistry 2017, 8(2), 137-143 | doi: https://doi.org/10.5155/eurjchem.8.2.137-143.1557 | Get rights and content






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Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine


Mbosse Ndiaye Gueye (1) , Moussa Dieng (2) , Djiby Lo (3) , Ibrahima Elhadji Thiam (4) , Aliou Hamady Barry (5) , Mohamed Gaye (6,*) , Abdou Salam Sall (7) , Pascal Retailleau (8)

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(5) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(6) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(7) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(8) Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS-UPR2301, Gif sur Yvette, 91198, France
(*) Corresponding Author

Received: 22 Feb 2017 | Accepted: 01 Apr 2017 | Published: 30 Jun 2017 | Issue Date: June 2017

Abstract


Two isotype mononuclear yttrium(III) and erbium(III) complexes, {[Y(HL)(OAc)2(H2O)2]. (H2O)∙(NO3)} (1) and {[Er(HL) (OAc)2(H2O)2].(H2O)∙(NO3)} (2), where HL is the neutral Schiff base ligand 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine, and OAc is the acetate anion, have been synthesized and characterized by physicochemical methods and single crystal X-ray determination. Both complexes crystallizes in the triclinic space group Pī with unit cell dimensions for complex of Y(III) a = 7.909 (2) Å, b = 11.718 (4) Å, c = 12.497 (3) Å,    α = 78.907 (3)°, b = 73.840 (3)°, γ = 72.074 (3)°, V = 1051.26 (6) Å3, Z = 2, R1 = 0.051 and    wR2 = 0.112 and for complex of Er(III)a = 7.913 (1) Å, b = 11.719 (2) Å, c = 12.487 (2) Å,          α = 78.832 (1)°, α = 73.674 (1)°, γ = 72.012 (1)°, V = 1049.64 (3) Å3, Z = 2, R1 = 0.028, and   wR2 = 0.062. In both complexes, the coordination polyhedra around Ln(III) atoms are best described as a distorted tricapped trigonal prism. Antioxidant activities of the ligand and its Y(III) and Er(III) complexes are studied.


Keywords


Complex; Schiff base; Crystal structure; NMR spectroscopy; Antioxidant activity; Magnetic properties

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DOI: 10.5155/eurjchem.8.2.137-143.1557

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[1]. Mamour Sarr, Mayoro Diop, Elhadj Ibrahima Thiam, Aliou Hamady Barry, Mohamed Gaye, Pascal Retailleau
Crystal structure of aquachlorido(nitrato-κ2 O,O′)[1-(pyridin-2-yl-κN)-2-(pyridin-2-ylmethylidene-κN)hydrazine-κN 2]manganase(II)
Acta Crystallographica Section E Crystallographic Communications  74(4), 450, 2018
DOI: 10.1107/S2056989018003493
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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

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Gueye, M.; Dieng, M.; Lo, D.; Thiam, I.; Barry, A.; Gaye, M.; Sall, A.; Retailleau, P. Eur. J. Chem. 2017, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, M.; Dieng, M.; Lo, D.; Thiam, I.; Barry, A.; Gaye, M.; Sall, A.; Retailleau, P. Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine. Eur. J. Chem. 2017, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, M., Dieng, M., Lo, D., Thiam, I., Barry, A., Gaye, M., Sall, A., & Retailleau, P. (2017). Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine. European Journal of Chemistry, 8(2), 137-143. doi:10.5155/eurjchem.8.2.137-143.1557
Gueye, Mbosse, Moussa Dieng, Djiby Lo, Ibrahima Elhadji Thiam, Aliou Hamady Barry, Mohamed Gaye, Abdou Salam Sall, & Pascal Retailleau. "Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine." European Journal of Chemistry [Online], 8.2 (2017): 137-143. Web. 5 Dec. 2020
Gueye, Mbosse, Dieng, Moussa, Lo, Djiby, Thiam, Ibrahima, Barry, Aliou, Gaye, Mohamed, Sall, Abdou, AND Retailleau, Pascal. "Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

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DOI Link: https://doi.org/10.5155/eurjchem.8.2.137-143.1557

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