Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine | European Journal of Chemistry

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Published: Jun 30, 2017

DOI: https://doi.org/10.5155/eurjchem.8.2.137-143.1557

Keywords:

Complex, Schiff base, Crystal structure, NMR spectroscopy, Antioxidant activity, Magnetic properties

Section

Research Article

Issue

Vol. 8 No. 2 (2017): June 2017

Dates

Received 2017-02-22
Accepted 2017-04-01
Published 2017-06-30

Mbosse Ndiaye Gueye

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Moussa Dieng

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Djiby Lo

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Ibrahima Elhadji Thiam

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Aliou Hamady Barry

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Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania

Mohamed Gaye

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Abdou Salam Sall

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Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal

Pascal Retailleau

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Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS-UPR2301, Gif sur Yvette, 91198, France

Abstract

Two isotype mononuclear yttrium(III) and erbium(III) complexes, {[Y(HL)(OAc)₂(H₂O)₂]. (H₂O)∙(NO₃)} (1) and {[Er(HL) (OAc)₂(H₂O)₂].(H₂O)∙(NO₃)} (2), where HL is the neutral Schiff base ligand 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine, and OAc is the acetate anion, have been synthesized and characterized by physicochemical methods and single crystal X-ray determination. Both complexes crystallizes in the triclinic space group Pī with unit cell dimensions for complex of Y(III) a = 7.909 (2) Å, b = 11.718 (4) Å, c = 12.497 (3) Å, α = 78.907 (3)°, b = 73.840 (3)°, γ = 72.074 (3)°, V = 1051.26 (6) Å³, Z = 2, R₁ = 0.051 and wR₂ = 0.112 and for complex of Er(III)a = 7.913 (1) Å, b = 11.719 (2) Å, c = 12.487 (2) Å, α = 78.832 (1)°, α = 73.674 (1)°, γ = 72.012 (1)°, V = 1049.64 (3) Å³, Z = 2, R₁ = 0.028, and wR₂ = 0.062. In both complexes, the coordination polyhedra around Ln(III) atoms are best described as a distorted tricapped trigonal prism. Antioxidant activities of the ligand and its Y(III) and Er(III) complexes are studied.

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Gueye, M. N.; Dieng, M.; Lo, D.; Thiam, I. E.; Barry, A. H.; Gaye, M.; Sall, A. S.; Retailleau, P. Synthesis, Physical Studies and Crystal Structure Determination of Y(III) and Er(III) Complexes of 1-(pyridin-2-Yl)-2-(pyridine-2-ylmethylene)hydrazine. Eur. J. Chem. 2017, 8, 137-143.

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References

[1]. Biswas, S.; Diaz, C.; Ghosh, A. Polyhedron 2013, 51, 96-101.
https://doi.org/10.1016/j.poly.2012.12.019

[2]. Kaabi, I.; Sibous, L.; Douadi, T.; Chafaa, S. J. Mol. Struct. 2015, 1084, 216-222.
https://doi.org/10.1016/j.molstruc.2014.12.023

[3]. Bhattacharjee, C. R.; Goswami, P.; Mondal, P. Inorg. Chim. Acta 2012, 387, 86-92.
https://doi.org/10.1016/j.ica.2011.12.056

[4]. Wang, W. M.; Ren, Y. H.; Wang, S.; Zhang, C. F.; Wu, Z. L.; Zhang, H.; Fang, M. Inorg. Chim. Acta 2016, 453, 452-456.
https://doi.org/10.1016/j.ica.2016.09.002

[5]. Gu, Z. G.; Pang, C. Y.; Qiu, D.; Zhang, J.; Huang, J. L.; Qin, L. F.; Sun, A. Q.; Li, Z. Inorg. Chem. Commun. 2013, 35, 164-168.
https://doi.org/10.1016/j.inoche.2013.06.025

[6]. Gorczynski, A.; Zaranek, M.; Witomska, S.; Bocian, A.; Stefankiewicz, A. R.; Kubicki, M.; Patroniak, V.; Pawluc, P. Catal. Commun. 2016, 78, 71-74.
https://doi.org/10.1016/j.catcom.2016.02.009

[7]. Al Zoubi, W.; Ko, Y. G. J. Organomet. Chem. 2016, 822, 173-188.
https://doi.org/10.1016/j.jorganchem.2016.08.023

[8]. Sarıoglu, A. O.; Ceylan, U.; Yalcin, S. P.; Sonmez, M.; Ceyhan, G.; Aygun, M. J. Lumin. 2016, 176, 193-201.
https://doi.org/10.1016/j.jlumin.2016.03.021

[9]. Hui, Y.; Feng, W.; Wei, T.; Lu, X.; Song, J.; Zhao, S.; Wong, W. K.; Jones, R. A. Inorg. Chem. Commun. 2011, 14, 200-204.
https://doi.org/10.1016/j.inoche.2010.10.022

[10]. Cristovao, B.; Hnatejko, Z. J. Mol. Struct. 2015, 1088, 50-55.
https://doi.org/10.1016/j.molstruc.2015.01.032

[11]. Cristovao, B.; Klak, J.; Pelka, R.; Miroslaw, B.; Hnatejko, Z. Polyhedron 2014, 68, 180-190.
https://doi.org/10.1016/j.poly.2013.10.019

[12]. Anacona, J. R.; Rincones, M. Spectrochim. Acta A 2015, 141, 169-175.
https://doi.org/10.1016/j.saa.2015.01.009

[13]. Soliman, A. A.; Amin, M. A.; El-Sherif, A. A.; Ozdemir, S.; Varlikli, C.; Zafer, C. Dyes Pigm. 2013, 99, 1056-1064.
https://doi.org/10.1016/j.dyepig.2013.08.007

[14]. Sarkar, A.; Pal, S. Polyhedron 2006, 25, 1689-1694.
https://doi.org/10.1016/j.poly.2005.11.009

[15]. Meng, Z.; Liu, J. L.; Leng, J. D.; Guo, F. S.; Tong, M. L. Polyhedron 2011, 30, 3095-3099.
https://doi.org/10.1016/j.poly.2011.02.043

[16]. Baraniak, E.; Bruce, R. S. L.; Freeman, H. C.; Hair, N. J.; James, J. Inorg. Chem. 1976, 15, 2226-2228.
https://doi.org/10.1021/ic50163a046

[17]. Ito, M.; Hamada, D.; Ono, H.; Matsumoto, N.; Sunatsuki, Y.; Re, N. Inorg. Chim. Acta, 2016, 443, 274-278.
https://doi.org/10.1016/j.ica.2015.12.029

[18]. Kaczmarek, M. T.; Jastrząb, R.; Kubicki, M.; Gierszewski, M.; Sikorski, M. Inorg. Chim. Acta 2015, 430, 108-113.
https://doi.org/10.1016/j.ica.2015.02.026

[19]. Sheldrick, G. M. SHELXTL Version 5. 10, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.

[20]. Sheldrick, G. M. SHELXTL-97, University of Göttingen, Göttingen, Germany, 1997.

[21]. Farrugia, L. J. J. Appl. Cryst. 1997, 30, 565.
https://doi.org/10.1107/S0021889897003117

[22]. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
https://doi.org/10.1016/S0010-8545(00)80009-0

[23]. Vleck, J. H. V.; Frank, A. Phys. Rev. 1929, 34(11), 1494-1496.
https://doi.org/10.1103/PhysRev.34.1494

[24]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed., Wiley-Interscience, New York, 1978.

[25]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
https://doi.org/10.1016/S0010-8545(00)80455-5

[26]. Xie, Q. L.; Li, S. H.; Zhang, D. K.; Zhang, Z. G.; Hu, J. M. Acta Chim. Sin. 1991, 49, 723-728.

[27]. Sonmez, M.; Levent, A.; Sekerci, M. Russ. J. Coord. Chem. 2004, 30, 655-660.
https://doi.org/10.1023/B:RUCO.0000040726.57728.a3

[28]. Fomina, I. G.; Dobrokhotova, Z. V.; Ilyukhin, A. B.; Aleksandrov, G. G.; Kazak, V. O.; Gehman, A. E.; Efimov, N. N.; Bogomyakov, A. S.; Zavorotny, Y. S.; Gerasimova, V. I.; Novotortsev, V. M.; Eremenko, I. L. Polyhedron 2013, 65, 152-160.
https://doi.org/10.1016/j.poly.2013.08.017

[29]. Oliveira, C. A. F.; Silva, F. F.; Malvestiti, I.; S. Malta, V. R.; Dutra, J. D. L.; Costa, N. B.; Freire, R. O.; Alves, S. J. Mol. Struct. 2013, 1041, 61-67.

[30]. Tamboura, F. B.; Haba, P. M.; Gaye, M.; Sall, A. S.; Barry, A. H.; Jouini, T. Polyhedron 2004, 23, 1191-1197.
https://doi.org/10.1016/j.poly.2004.01.014

[31]. Ajlouni, A. M.; Taha, Z. A.; Al-Hassan, K. A.; Anzeh, A. M. A. J. Lumin. 2012, 132, 1357-1363.
https://doi.org/10.1016/j.jlumin.2012.01.013

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