European Journal of Chemistry

Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand

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Published: Sep 30, 2021
DOI: https://doi.org/10.5155/eurjchem.12.3.248-255.2091
Keywords:
DFT, Ag(I) dimer, Photophysics, Imino-pyridyl ligand, X-ray crystal structure, Hirshfeld surface studies
Section
Research Article
Issue
Vol. 12 No. 3 (2021): September 2021
Dates
Received 2021-01-29
Accepted 2021-04-30
Published 2021-09-30
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Jahangir Mondal
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-9867-5193
Meman Sahu
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-9397-4805
Bhaskar Sharma
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-7944-4955
Rakesh Ganguly
Shiv Nadar University, Greater Noida, Gautam Buddha Nagar, Uttar Pradesh, 201314, India
https://orcid.org/0000-0002-9523-6918
Shubhamoy Chowdhury
Department of Chemistry, University of Gour Banga, Malda, West Bengal, 732103, India
https://orcid.org/0000-0003-1545-9693
Goutam Kumar Patra
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0003-3151-0284

Abstract

The synthesis and characterization of an imino-pyridyl ligand N,N'-(butane-1,4-diyl)bis(1-(pyridin-2-yl)methanimine) (L) and its Ag(I)ClO4 complex (I) by various spectroscopic techniques and elemental analyses is presented in this study. X-ray single crystal structure of complex I revealed that in complex I, each Ag(I) ion is tetra coordinated with two pyridine N-atoms and two imine N-atoms of the ligand L, forming a macrocyclic dimeric Ag(I) grid. In the macrocyclic dimer complex I, Ag-Ag separation along the chain is 5.318 Å. The Ag-Npy average distance is 2.396 Å and that of the Ag-Nim is 2.257 Å. The macrocyclic dimer complex I is supramolecularly arranged by π-stacking interactions. Computational, Hirshfeld surface analysis and photophysical studies on ligand L and complex I have also been performed. Crystal data for C32H36Ag2Cl2N8O8 (M =947.33 g/mol): Triclinic, space group P-1 (no. 2), a = 9.1714(12) Å, b = 10.4373(14) Å, c = 10.8297(14) Å, α = 112.317(3)°, β = 91.391(3)°, γ = 92.353(3)°, V = 957.3(2) Å3, Z = 1, T = 293.15 K, μ(MoKα) = 1.220 mm-1, Dcalc = 1.643 g/cm3, 10248 reflections measured (4.07° ≤ 2Θ ≤ 53.098°), 3966 unique (Rint = 0.0280, Rsigma = 0.0331) which were used in all calculations. The final R1 was 0.0722 (I > 2σ(I)) and wR2 was 0.2229 (all data).


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Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. K. Synthesis, Crystal Structure, and Theoretical Studies of a Macrocyclic silver(I) Complex of Imino-Pyridyl Schiff Base Ligand. Eur. J. Chem. 2021, 12, 248-255.

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References

[1]. Yamada, S. Coord. Chem. Rev.1999, 190-192, 537-555.
https://doi.org/10.1016/S0010-8545(99)00099-5

[2]. Wang, X.; Qin, C.; Wang, E.; Li, Y.; Hao, N.; Hu, C.; Xu, L. Inorg. Chem. 2004, 43 (6), 1850-1856.
https://doi.org/10.1021/ic035151s

[3]. Qin, C.; Wang, X.; Wang, E.; Xu, L. J. Mol. Struct. 2005, 738 (1-3), 91-98.
https://doi.org/10.1016/j.molstruc.2004.11.039

[4]. Wen, L.; Li, Y.; Dang, D.; Tian, Z.; Ni, Z.; Meng, Q. J. Solid State Chem. 2005, 178 (11), 3336-3341.
https://doi.org/10.1016/j.jssc.2005.07.035

[5]. Majumder, A.; Rosair, G. M.; Mallick, A.; Chattopadhyay, N.; Mitra, S. Polyhedron 2006, 25 (8), 1753-1762.
https://doi.org/10.1016/j.poly.2005.11.029

[6]. Muthu, S.; Ni, Z.; Vittal, J. J. Inorg. Chim. Acta 2005, 358 (3), 595-605.
https://doi.org/10.1016/j.ica.2004.09.038

[7]. Yue, S.-M.; Xu, H.-B.; Ma, J.-F.; Su, Z.-M.; Kan, Y.-H.; Zhang, H.-J. Polyhedron 2006, 25 (3), 635-644.
https://doi.org/10.1016/j.poly.2005.07.021

[8]. Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246 (1-2), 247-289.
https://doi.org/10.1016/S0010-8545(03)00126-7

[9]. Beauvais, L. G.; Long, J. R. Inorg. Chem. 2006, 45 (1), 236-243.
https://doi.org/10.1021/ic051087y

[10]. Chandler, B. D.; Cramb, D. T.; Shimizu, G. K. H. J. Am. Chem. Soc. 2006, 128 (32), 10403-10412.
https://doi.org/10.1021/ja060666e

[11]. Gu, Z.-G.; Fang, H.-C.; Yin, P.-Y.; Tong, L.; Ying, Y.; Hu, S.-J.; Li, W.-S.; Cai, Y.-P. Cryst. Growth Des. 2011, 11 (6), 2220-2227.
https://doi.org/10.1021/cg1015753

[12]. Dybtsev, D. N.; Chun, H.; Yoon, S. H.; Kim, D.; Kim, K. J. Am. Chem. Soc. 2004, 126 (1), 32-33.
https://doi.org/10.1021/ja038678c

[13]. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem. Int. Ed Engl. 2004, 43 (12), 1466-1496.
https://doi.org/10.1002/anie.200300588

[14]. Lee, J.-Y.; Chen, C.-Y.; Lee, H. M.; Passaglia, E.; Vizza, F.; Oberhauser, W. Cryst. Growth Des. 2011, 11 (4), 1230-1237.
https://doi.org/10.1021/cg101453m

[15]. Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34 (4), 319-330.
https://doi.org/10.1021/ar000034b

[16]. Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101 (6), 1629-1658.
https://doi.org/10.1021/cr9900432

[17]. Janiak, C. Dalton Trans. 2003, 14, 2781-2804.
https://doi.org/10.1039/b305705b

[18]. Roesky, H. W.; Andruh, M. Coord. Chem. Rev. 2003, 236 (1-2), 91-119.
https://doi.org/10.1016/S0010-8545(02)00218-7

[19]. Luan, X.-J.; Wang, Y.-Y.; Li, D.-S.; Liu, P.; Hu, H.-M.; Shi, Q.-Z.; Peng, S.-M. Angew. Chem. Int. Ed Engl. 2005, 44 (25), 3864-3867.
https://doi.org/10.1002/anie.200500744

[20]. Ding, B.-B.; Weng, Y.-Q.; Mao, Z.-W.; Lam, C.-K.; Chen, X.-M.; Ye, B.-H. Inorg. Chem. 2005, 44 (24), 8836-8845.
https://doi.org/10.1021/ic051195k

[21]. Angeloni, A.; Crawford, P. C.; Orpen, A. G.; Podesta, T. J.; Shore, B. J. Chemistry 2004, 10 (15), 3783-3791.
https://doi.org/10.1002/chem.200400165

[22]. Balamurugan, V.; Hundal, M. S.; Mukherjee, R. Chemistry 2004, 10 (7), 1683-1690.
https://doi.org/10.1002/chem.200305701

[23]. Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98 (4), 1375-1406.
https://doi.org/10.1021/cr960091b

[24]. Janiak, C.; Scharmann, T. G. Polyhedron 2003, 22 (8), 1123-1133.
https://doi.org/10.1016/S0277-5387(03)00098-6

[25]. Pal, S.; Pal, S. Polyhedron 2003, 22 (6), 867-873.
https://doi.org/10.1016/S0277-5387(03)00008-1

[26]. Patra, G. K.; Pal, P. K.; Mondal, J.; Ghorai, A.; Mukherjee, A.; Saha, R.; Fun, H.-K. Inorg. Chim. Acta 2016, 447, 77-86.
https://doi.org/10.1016/j.ica.2016.03.032

[27]. Mondal, J.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 463, 44-53.
https://doi.org/10.1016/j.ica.2017.03.031

[28]. Mondal, J.; Pal, P. K.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 466, 274-284.
https://doi.org/10.1016/j.ica.2017.06.025

[29]. Bruker (2008). SAINT, SMART. Bruker AXS Inc., Madison, Wisconsin, USA.

[30]. Sheldrick, G. M. Acta Crystallogr. A 2008, 64 (1), 112-122.
https://doi.org/10.1107/S0108767307043930

[31]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32 (4), 837-838.
https://doi.org/10.1107/S0021889899006020

[32]. Frisch, M. J.; Trucks G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; A. J. Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian, Inc. , Gaussian 09, Revision A. 02, Wallingford CT, 2009.

[33]. Dennington, R.; Keith, T.; Millam, J.; Gaussview. Version 5; Semichem Inc: Shawnee Mission, KS, 2009.

[34]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82 (1), 299-310.
https://doi.org/10.1063/1.448975

[35]. Barone, V.; Cossi, M. J. Phys. Chem. A 1998, 102 (11), 1995-2001.
https://doi.org/10.1021/jp9716997

[36]. Tomasi, J.; Mennucci, B.; Cammi, R. Chem. Rev. 2005, 105 (8), 2999-3093.
https://doi.org/10.1021/cr9904009

[37]. Norret, M.; Makha, M.; Sobolev, A. N.; Raston, C. L. New J. Chem. 2008, 32 (5), 808-812.
https://doi.org/10.1039/b718937k

[38]. Spackman, M. A.; McKinnon, J. J. CrystEngComm 2002, 4 (66), 378-392.
https://doi.org/10.1039/B203191B

[39]. Meng, X. X. Applications of Hirshfeld surfaces to ionic and mineral crystals, Ph.D. Thesis, University of New England, 2004.

[40]. Pendás, A. M.; Luaña, V.; Pueyo, L.; Francisco, E.; Mori-Sánchez, P. J. Chem. Phys. 2002, 117 (3), 1017-1023.
https://doi.org/10.1063/1.1483851

[41]. Hyde, S.; Andersson, S.; Larsson, K.; Blum, Z.; Landh, T.; Lidin, S.; Ninham, B. W. The Language of Shape; Elsevier: Amsterdam, 1997.

[42]. Nishikawa, M.; Nomoto, K.; Kume, S.; Inoue, K.; Sakai, M.; Fujii, M.; Nishihara, H. J. Am. Chem. Soc. 2010, 132 (28), 9579-9581.
https://doi.org/10.1021/ja103718e

[43]. Desiraju, G. R. Angew. Chem. Int. Ed Engl. 2007, 46 (44), 8342-8356.
https://doi.org/10.1002/anie.200700534

[44]. Schmidt, G. M. J. Pure Appl. Chem. 1971, 27 (4), 647-678.
https://doi.org/10.1351/pac197127040647

[45]. Sebastian, S.; Sundaraganesan, N. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2010, 75 (3), 941-952.
https://doi.org/10.1016/j.saa.2009.11.030

[46]. Luque, F. J.; López, J. M.; Orozco, M. Theor. Chem. Acc. 2000, 103 (3-4), 343-345.
https://doi.org/10.1007/s002149900013

[47]. Bhattacharya, A.; Naskar, J. P.; Majumder, S.; Ganguly, R.; Mitra, P.; Chowdhury, S. Inorg. Chim. Acta 2015, 425, 124-133.
https://doi.org/10.1016/j.ica.2014.10.004

[48]. Sahu, M.; Manna, A. K.; Chowdhury, S.; Patra, G. K. RSC Adv. 2020, 10 (73), 44860-44875.
https://doi.org/10.1039/D0RA09023A

Supporting Agencies

Department of Science and Technology (SR/FST/CSI-264/2014 and EMR/ 2017/0001789) and Department of Biotechnology, Government of India, New Delhi, India.
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