European Journal of Chemistry

Synthesis, characterization, X-ray crystal structure and Hirshfeld surface analysis of Ni(II) complex of 1,2-bis(pyridin-2-ylmethylene)hydrazine

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Published: Mar 31, 2022
DOI: https://doi.org/10.5155/eurjchem.13.1.1-7.2166
Keywords:
Hydrazone, Ni(II)triple helix, Crystal structure, 2-Pyridinaldazine, Hirshfield surface analysis, 1, 2-Bis(Pyridin-2-ylmethylene)hydrazine
Section
Research Article
Issue
Vol. 13 No. 1 (2022): March 2022
Dates
Received 2021-07-30
Accepted 2021-10-17
Published 2022-03-31
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Meman Sahu
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur (Chhattisgarh), 495009, India
https://orcid.org/0000-0001-9397-4805
Amit Kumar Manna
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur (Chhattisgarh), 495009, India
https://orcid.org/0000-0002-9605-2168
Dinesh De
Department of Basic Science, Vishwavidyalaya Engineering College, Ambikapur, CSVTU-Bhilai, Chhattisgarh, 497001, India
https://orcid.org/0000-0001-7850-8718
Goutam Kumar Patra
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur (Chhattisgarh), 495009, India
https://orcid.org/0000-0003-3151-0284

Abstract

We report the synthesis, characterization, X-ray crystal structure and Hirshfeld surface analysis of Ni(II) perchlorate complex (1, Ni2L3·4ClO4·2CH3CN) of 1,2-bis(pyridin-2-ylmethylene)hydrazine (L) ligand. The X-ray crystallographic study of complex 1 reveals that in the presence of Ni(II) ions,the ligand L forms a dimeric triple helix with a Ni(II)-Ni(II) distance of 3.794 Å. Crystal data for C40H36Cl4N14Ni2O16: Monoclinic, space group P21/c (no. 14), a = 20.7558(19) Å, b = 13.1937(12) Å, c = 20.0181(18) Å, β = 96.9510(10)°, V = 5441.6(9) Å3, Z = 4, T = 293.15 K, μ(MoKα) = 0.965 mm-1, Dcalc = 1.498 g/cm3, 38075 reflections measured (1.976° ≤ 2Θ ≤ 43.728°), 6557 unique (Rint = 0.0695, Rsigma = 0.0466) which were used in all calculations. The final R1 was 0.0518 (I > 2σ(I)) and wR2 was 0.1270 (all data). The Hirshfeld surface analysis of complex 1 shows that C···H, H···H, N···H and O···H interactions of 10.9, 26.4, 6.7, and 33.4%; respectively, which exposed that the main intermolecular interactions were H···H intermolecular interactions.


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Sahu, M.; Manna, A. K.; De, D.; Patra, G. K. Synthesis, Characterization, X-Ray Crystal Structure and Hirshfeld Surface Analysis of Ni(II) Complex of 1,2-bis(pyridin-2-ylmethylene)hydrazine. Eur. J. Chem. 2022, 13, 1-7.

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Supporting Agencies

The Department of Science and Technology (SR/FST/CSI-264/2014 and EMR/2017/0001789) and the Department of Biotechnology, Government of India, New Delhi India.
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