European Journal of Chemistry 2021, 12(3), 248-255 | doi: https://doi.org/10.5155/eurjchem.12.3.248-255.2091 | Get rights and content

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Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand


Jahangir Mondal (1) orcid , Meman Sahu (2) orcid , Bhaskar Sharma (3) orcid , Rakesh Ganguly (4) orcid , Shubhamoy Chowdhury (5) orcid , Goutam Kumar Patra (6,*) orcid

(1) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(2) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(3) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(4) Shiv Nadar University, Greater Noida, Gautam Buddha Nagar, Uttar Pradesh, 201314, India
(5) Department of Chemistry, University of Gour Banga, Malda, West Bengal, 732103, India
(6) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(*) Corresponding Author

Received: 29 Jan 2021 | Revised: 14 Mar 2021 | Accepted: 30 Apr 2021 | Published: 30 Sep 2021 | Issue Date: September 2021

Abstract


The synthesis and characterization of an imino-pyridyl ligand N,N'-(butane-1,4-diyl)bis(1-(pyridin-2-yl)methanimine) (L) and its Ag(I)ClO4 complex (I) by various spectroscopic techniques and elemental analyses is presented in this study. X-ray single crystal structure of complex I revealed that in complex I, each Ag(I) ion is tetra coordinated with two pyridine N-atoms and two imine N-atoms of the ligand L, forming a macrocyclic dimeric Ag(I) grid. In the macrocyclic dimer complex I, Ag-Ag separation along the chain is 5.318 Å. The Ag-Npy average distance is 2.396 Å and that of the Ag-Nim is 2.257 Å. The macrocyclic dimer complex I is supramolecularly arranged by π-stacking interactions. Computational, Hirshfeld surface analysis and photophysical studies on ligand L and complex I have also been performed. Crystal data for C32H36Ag2Cl2N8O8 (=947.33 g/mol): Triclinic, space group P-1 (no. 2), a = 9.1714(12) Å, b = 10.4373(14) Å, c = 10.8297(14) Å, α = 112.317(3)°, β = 91.391(3)°, γ = 92.353(3)°, = 957.3(2) Å3, Z = 1, T = 293.15 K, μ(MoKα) = 1.220 mm-1, Dcalc = 1.643 g/cm3, 10248 reflections measured (4.07° ≤ 2Θ ≤ 53.098°), 3966 unique (Rint = 0.0280, Rsigma = 0.0331) which were used in all calculations. The final R1 was 0.0722 (I > 2σ(I)) and wR2 was 0.2229 (all data).


Keywords


DFT; Ag(I) dimer; Photophysics; Imino-pyridyl ligand; X-ray crystal structure; Hirshfeld surface studies

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DOI: 10.5155/eurjchem.12.3.248-255.2091

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Department of Science and Technology (SR/FST/CSI-264/2014 and EMR/ 2017/0001789) and Department of Biotechnology, Government of India, New Delhi, India.

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How to cite


Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. Eur. J. Chem. 2021, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand. Eur. J. Chem. 2021, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, J., Sahu, M., Sharma, B., Ganguly, R., Chowdhury, S., & Patra, G. (2021). Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand. European Journal of Chemistry, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, Jahangir, Meman Sahu, Bhaskar Sharma, Rakesh Ganguly, Shubhamoy Chowdhury, & Goutam Kumar Patra. "Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand." European Journal of Chemistry [Online], 12.3 (2021): 248-255. Web. 4 Dec. 2021
Mondal, Jahangir, Sahu, Meman, Sharma, Bhaskar, Ganguly, Rakesh, Chowdhury, Shubhamoy, AND Patra, Goutam. "Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand" European Journal of Chemistry [Online], Volume 12 Number 3 (30 September 2021)

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