OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS
An efficient route for the synthesis of some monoazo disperse dyes derived from nicotinic acid derivatives
Abdulaziz Alnajjar (1) , Marzouq Alsaiedi (2) , Morsy Ahmed El-Apasery (3,*)
(1) Applied Science Department, College of Technological Studies, Public Authority for Applied Education and Training, Safat, 70654, Kuwait
(2) Applied Science Department, College of Technological Studies, Public Authority for Applied Education and Training, Safat, 70654, Kuwait
(3) Dyeing, Printing and Textile Auxiliaries Department, Textile Research Division, National Research Centre, 12622 Dokki, Giza, Egypt
(*) Corresponding Author
Received: 03 Jan 2013 | Revised: 04 Feb 2013 | Accepted: 05 Feb 2013 | Published: 31 Mar 2013 | Issue Date: March 2013
Ethyl 2-amino-3-cyano-4-phenylnicotinates (8), could be readily synthesized via reacting ethyl propiolate with benzylidenemalononitrile in the presence of L-proline as a catalyst and subsequent rearrangement of the so formed 2-aminopyran (7), with acetic acid in the presence of ammonium acetate. A series of 2-amino and 2-hydroxyarylazonicotinates monoazo disperse dyes (12a-c), were prepared in a good yields via condensation of arylhydrazonals (11a-c), with active methylene nitriles. The compound 9 was also characterized by single crystal X-ray diffraction studies. Crystal data for compound 9, C15H18O6 (M = 294.29): hexagonal, space group P65 (no. 170), a = 11.3311(5) Å, c = 19.5375(10) Å, V = 2172.42(18) Å3, Z = 6, T = 296(2) K, μ(MoKα) = 0.879 mm-1, Dcalc = 1.350 g/mm3, 4546 reflections measured (9.02 ≤ 2Θ ≤ 132.96), 2271 unique (Rint = 0.0921) which were used in all calculations. The final R1 was 0.0686 (>2σ(I)) and wR2 was 0.1691 (all data).
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).
2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).
3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).
European Journal of Chemistry
Links for Article
| | | | | | |
| | | | | | |
| | | |
Article MetricsThis Abstract was viewed 1741 times | PDF Article downloaded 602 times
The Public Authority for Applied Education and Training (Transform grant TS-07-11) of Kuwait.
. Morsy Ahmed El-Apasery, Samar Mohamed Ashkar, Marwan Touma, Mohamed Hilmy Elnagdi
A facile synthesis of some biologically active disperse dyes derived from arylazonicotinates and their application on polyester fabrics
European Journal of Chemistry 4(3), 245, 2013
. Morsy Ahmed El-Apasery, Fawzia Al-Qalaf, Khaledah Almohammad, Huda Mahmoud
Synthesis of some biologically active monoazo disperse dyes derived from nicotinic acid derivatives under microwave irradiation for dyeing polyester fabrics
European Journal of Chemistry 4(3), 211, 2013
. Mohamed R. Eletmany, Marzough Aziz Albalawi, Reem A.K. Alharbi, Rokaia B. Elamary, Abd El-Fattah A. Harb, Moghraby A. Selim, Asmaa Sayed Abdelgeliel, Entesar A. Hassan, Islam M. Abdellah
Novel arylazo nicotinate derivatives as effective antibacterial agents: Green synthesis, molecular modeling, and structure-activity relationship studies
Journal of Saudi Chemical Society 27(3), 101647, 2023
. Saleh Mohammed Al-Mousawi, Morsy Ahmed El-Apasery, Mohamed Hilmy Elnagdi
Arylazoazines and arylazoazoles as interesting disperse dyes: Recent developments with emphasis on our contribution laboratory outcomes
European Journal of Chemistry 5(1), 192, 2014
. Sayed, A. Z.; Aboul-Fetouh, M. S.; Nassar, H. S. J. Mol. Struct. 2012, 1010, 146-151.
. Gharanjig, K.; Sadeghi-Kiakhani, M.; Arami, M.; Mahmoodi, N. M.; Khosravi, A. Color. Technol. 2010, 126(1), 37-41.
. Suesat, J.; Mungmeechai, T.; Suwanruji, P.; Parasuk, W.; Taylor, J. A.; Phillips, D. A. S. Color. Technol. 2011, 127(4), 217-222.
. El-Apasery, M. A.; Al-Mousawi, S. M.; Mahmoud, H.; Elnagdi, M. H. Eur. J. Chem. 2011, 2(2), 168-172.
. Khalil, K.; Al-Matar, H.; Elnagdi, M. H. Eur. J. Chem. 2010, 1(4), 252-258.
. Behbehani, H.; Abdel-Khalik, M. M.; Elnagdi, M. H. Org. Prep. Proced. Int. 1999, 31(5), 551-557.
. Al-Mousawi, S. M.; El-Apasery, M. A.; Mahmoud, H. M. Molecules 2012, 17, 11495-11506.
. Al-Mousawi, S. M.; El-Apasery, M. A. Molecules 2012, 17, 6547-6556.
. Al-Mousawi, S. M.; El-Apasery, M. A.; Mahmoud, H.; Elnagdi, M. H. Int. Res. J. Pure Appl. Chem. 2012, 2, 77-90.
. Kim, K. R.; Rhee, S. D.; Kim, H. Y.; Jung, W. H.; Yang, S. D.; Kim, S. S.; Ahn, J. H.; Cheon, H. Eur. J. Pharm. 2005, 518(1), 63-70.
. Zaky, O. S.; Moustafa, M. S.; Selim, M. A.; El-Maghraby, A. M.; Elnagdi, M. H. Molecules 2012, 17(5), 5924-34.
. Mohanta, G. P.; Manna, P. K.; Manavalan, R. Ind. J. Pharm. Sci. 2002, 64(5), 489-491.
. El-Apasery, M. A.; Al-Mousawi, S. M.; Mahmoud, H.; Elnagdi, M. H. Int. Res. J. Pure Appl. Chem. 2011, 1, 69-93.
. Bazhin, D. N.; Kudyakova, Y. S.; Burgart, Y. V.; Saloutin, V. I. Tetrahedron Lett. 2012, 53(15), 1961-1963.
. Elnagdi, N. M. H.; Al-Hokbany, N. S. Molecules 2012, 17, 4300-4312.
The Supplementary Material for this article can be found online at: Supplementary files
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.4.1.53-57.733
| | | | | | | |
| | | | | | |
Save to Zotero Save to Mendeley
European Journal of Chemistry 2013, 4(1), 53-57 | doi: https://doi.org/10.5155/eurjchem.4.1.53-57.733 | Get rights and content
- There are currently no refbacks.
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.