European Journal of Chemistry 2018, 9(4), 281-286. doi:10.5155/eurjchem.9.4.281-286.1761
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Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex


Amadou Gueye (1) orcid , Farba Bouyagui Tamboura (2,*) orcid , Jean-Marc Planeix (3) orcid , Nathalie Gruber (4) orcid , Mohamed Gaye (5) orcid

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal
(2) Department of Chemistry, University Alioune DIOP, Bambey 21400, Senegal
(3) Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France
(4) Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France
(5) Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal
(*) Corresponding Author

Received: 09 Jun 2018, Accepted: 28 Aug 2018, Published: 31 Dec 2018

Abstract


The reactions of the Schiff base 2-((2-hydroxyphenylimino)methyl)-6-methoxyphenol (H2L), obtained by direct condensation of 2-aminophenol and 2-hydroxy-3-methoxybenzaldehyde, with some transition  metal ions (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) afforded complexes of general formulae [M2(L)2(solvent)x] (M: Mn, Co, Ni, Cu or Zn; Solvent: DMSO or H2O). These compounds were characterized by elemental analysis, UV-Vis, IR, 1H- and 13C-NMR spectroscopies, molar conductivity and room temperature magnetic measurements. The structure of zinc(II) complex has been determined by X-ray crystallography. Crystal data for C32H34N2O8S2Zn2 (=769.47 g/mol): Orthorhombic, space group Pbca (no. 61), a = 16.3176(7) Å, b = 9.1247(3) Å, c = 21.8274(10) Å, = 3250.0(2) Å3, Z = 4, T = 173(2) K, μ(MoKα) = 1.658 mm-1, Dcalc = 1.573 g/cm3, 28116 reflections measured (4.5° ≤ 2Θ ≤ 60.3°), 4457 unique (Rint = 0.0409, Rsigma = 0.0371) which were used in all calculations. The final R1 was 0.0307(0.0466) and wR2 was 0.0649 (0.0701) (all data). The coordination sphere of the Zn center is best described as a trigonal bipyramid.


Keywords


Schiff base; Benzaldehyde; Metal complexes; Trigonal bipyramidal; X-ray crystallography; Single crystal structure

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DOI: 10.5155/eurjchem.9.4.281-286.1761

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How to cite


Gueye, A.; Tamboura, F.; Planeix, J.; Gruber, N.; Gaye, M. Eur. J. Chem. 2018, 9(4), 281-286. doi:10.5155/eurjchem.9.4.281-286.1761
Gueye, A.; Tamboura, F.; Planeix, J.; Gruber, N.; Gaye, M. Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex. Eur. J. Chem. 2018, 9(4), 281-286. doi:10.5155/eurjchem.9.4.281-286.1761
Gueye, A., Tamboura, F., Planeix, J., Gruber, N., & Gaye, M. (2018). Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex. European Journal of Chemistry, 9(4), 281-286. doi:10.5155/eurjchem.9.4.281-286.1761
Gueye, Amadou, Farba Bouyagui Tamboura, Jean-Marc Planeix, Nathalie Gruber, & Mohamed Gaye. "Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex." European Journal of Chemistry [Online], 9.4 (2018): 281-286. Web. 7 Dec. 2019
Gueye, Amadou, Tamboura, Farba, Planeix, Jean-Marc, Gruber, Nathalie, AND Gaye, Mohamed. "Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex" European Journal of Chemistry [Online], Volume 9 Number 4 (31 December 2018)

DOI Link: https://doi.org/10.5155/eurjchem.9.4.281-286.1761

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