European Journal of Chemistry

Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties

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Published: Jun 30, 2014
DOI: https://doi.org/10.5155/eurjchem.5.2.370-373.1032
Keywords:
Ninhydrin, Naked-eye, Anion receptor, UV-Vis titration, Association constant, 2, 4-Dinitrophenylhydrazine
Section
Research Article
Issue
Vol. 5 No. 2 (2014): June 2014
Dates
Received 2014-02-06
Accepted 2014-03-02
Published 2014-06-30


Main Article Content

Fatma Aydın
Çanakkale Onsekiz Mart University, Department of Chemistry, 17100, Çanakkale, Turkey

Abstract

A new receptor named, 2-(2-(2,4-dinitrophenyl)hydrazono)2H-indene-1,3-dione, used as a colorimetric sensor based on 2,4-dinitrophenylhydrazone derivative of ninhydrin was synthesized by simple step with good yields and characterized by IR and 1H, 13C NMR and MS spectroscopic techniques. The anion recognition properties were studied by UV-Vis spectroscopic technique. The results showed that the receptor had a higher affinity to F-, CN-, H2PO4-, CH3COO- and OH-, but showed no evident binding with Cl-, Br- and I-. Binding of the reseptor to anions such as CN-, AcO-, F-, H2PO4- and OH-exhibited an obvious color change from greenish yellow to purplish blue, which was possible to observe by the naked eye.


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Aydın, F. Synthesis and Recognition Properties of Colorimetric Anion Chemosensor Bearing 2,4-Dinitrophenylhydrazone and Indene-1,3-Dione Moieties. Eur. J. Chem. 2014, 5, 370-373.

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Supporting Agencies

Çanakkale Onsekiz Mart University Research Fund (Project No, BAP-2010-57), Çanakkale Onsekiz Mart University, Çanakkale, Turkey
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