European Journal of Chemistry

A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)

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Published: Jun 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.2.174-178.1570
Keywords:
Oxidation, T-TMPSDC, Alcohol oxidation, Silver dichromate, Oxidative reagent, 2, 4, 6-Trimethylpyridine
Section
Research Article
Issue
Vol. 8 No. 2 (2017): June 2017
Dates
Received 2017-03-23
Accepted 2017-05-05
Published 2017-06-30


Main Article Content

Fatma Aydin
Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
Semih Dersin
Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey

Abstract

Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) was easily synthesized by addition of 2,4,6-trimethylpyridine to an aqueous precipitation of silver dichromate and characterized thoroughly, using spectroscopic and others analytical methods such as FT-IR, 1H NMR, 13C NMR, DTA, SEM-EDS and XRD. When T-TMPSDC was used as an oxidative reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to their corresponding carbonyl compounds in presence of benzylic carbons and arenes such as tetraline, anthracene and phenanthrene.


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Aydin, F.; Dersin, S. A New Oxidative Reagent Synthesis and Its Applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) Dichromate (T-TMPSDC). Eur. J. Chem. 2017, 8, 174-178.

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Supporting Agencies

This work was financially supported by Çanakkale Onsekiz Mart University Research Fund. (Project No, BAP, 2014/191-Turkey). The authors would also like to thank Yıldız YILDIRIM (KALESERAMIK A.Ş. ArGe, Turkey) for the TG/DTG and XRD analysis.
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