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A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)
Fatma Aydin (1,*)
, Semih Dersin (2) (1) Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
(*) Corresponding Author
Received: 23 Mar 2017 | Revised: 03 May 2017 | Accepted: 05 May 2017 | Published: 30 Jun 2017 | Issue Date: June 2017
Abstract
Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) was easily synthesized by addition of 2,4,6-trimethylpyridine to an aqueous precipitation of silver dichromate and characterized thoroughly, using spectroscopic and others analytical methods such as FT-IR, 1H NMR, 13C NMR, DTA, SEM-EDS and XRD. When T-TMPSDC was used as an oxidative reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to their corresponding carbonyl compounds in presence of benzylic carbons and arenes such as tetraline, anthracene and phenanthrene.
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DOI: 10.5155/eurjchem.8.2.174-178.1570
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Funding information
This work was financially supported by Çanakkale Onsekiz Mart University Research Fund. (Project No: BAP, 2014/191-Turkey). The authors would also like to thank Yıldız YILDIRIM (KALESERAMIK A.Ş. ArGe, Turkey) for the TG/DTG and XRD analysis.
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DOI Link: https://doi.org/10.5155/eurjchem.8.2.174-178.1570
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European Journal of Chemistry 2017, 8(2), 174-178 | doi: https://doi.org/10.5155/eurjchem.8.2.174-178.1570 | Get rights and content
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