European Journal of Chemistry

A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)

Article Sidebar

PDF
Published: Jun 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.2.174-178.1570
Keywords:
Oxidation, T-TMPSDC, Alcohol oxidation, Silver dichromate, Oxidative reagent, 2, 4, 6-Trimethylpyridine
Section
Research Article
Issue
Vol. 8 No. 2 (2017): June 2017
Dates
Received 2017-03-23
Accepted 2017-05-05
Published 2017-06-30


Main Article Content

Fatma Aydin
Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
Semih Dersin
Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey

Abstract

Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) was easily synthesized by addition of 2,4,6-trimethylpyridine to an aqueous precipitation of silver dichromate and characterized thoroughly, using spectroscopic and others analytical methods such as FT-IR, 1H NMR, 13C NMR, DTA, SEM-EDS and XRD. When T-TMPSDC was used as an oxidative reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to their corresponding carbonyl compounds in presence of benzylic carbons and arenes such as tetraline, anthracene and phenanthrene.


icon graph This Abstract was viewed 1587 times | icon graph Article PDF downloaded 805 times

How to Cite
(1)
Aydin, F.; Dersin, S. A New Oxidative Reagent Synthesis and Its Applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) Dichromate (T-TMPSDC). Eur. J. Chem. 2017, 8, 174-178.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Cainelli, G.; Cardillo, G. Chromium Oxidations in Organic Chemistry; Springer: Berlin, 1984.
https://doi.org/10.1007/978-3-642-69362-5

[2]. Muzart, J. Chem. Rev. 1992, 92(1), 113-140.

[3]. Corey, E. J.; Suggs, J. W. Tetrahedron Lett. 1975, 16(31), 2647-2650.
https://doi.org/10.1016/S0040-4039(00)75204-X

[4]. Piancatelli, G.; Scattri, A.; Auria, A. D. Synthesis 1982, 4, 245-258.
https://doi.org/10.1055/s-1982-29766

[5]. Bhattacharjee, M. K.; Chaudhuri, H.S.; Dasgupta, N. R. Synthesis 1982, 7, 588-590.
https://doi.org/10.1055/s-1982-29872

[6]. Corey, E. J.; Schmidt, G. Tetrahedron Lett. 1979, 20, 399-402.
https://doi.org/10.1016/S0040-4039(01)93515-4

[7]. Aydin, F.; Ozen, R. Org. Prep. Proced. Int. 2007, 39(6), 616-620.
https://doi.org/10.1080/00304940709458647

[8]. Firouzabadi, H.; Sardarian, A.; Garibi, H. Synth. Commun. 1984, 14, 89-94.
https://doi.org/10.1080/00397918408060869

[9]. Corey, E. J.; Fleet, G. W. J. Tetrahedron Lett. 1973, 14, 4499-4501.
https://doi.org/10.1016/S0040-4039(01)87260-9

[10]. Turunc, E.; Aydin, F. Org. Prep. Proced. Int. 2004, 36(4), 363-366.
https://doi.org/10.1080/00304940409458680

[11]. Collins, J. C.; Hess, W. W.; Frank, F.J. Tetrahedron Lett. 1968, 30, 3363-3366.
https://doi.org/10.1016/S0040-4039(00)89494-0

[12]. Hashemi, M. H.; Ghazaanfari, D.; Akhbari, M. Monatsh. Chem. 2004, 135, 797-797.

[13]. Loonker, K.; Sharma, P. K.; Banerji, K. K. J. Chem. Res. (S) 1997, 194-195.

[14]. Khazaei, A.; Mehdipour, E.; Yadegari, S. Phosphorus, Sulfur, Silicon Relat. Elem. 2004, 179, 437-441.
https://doi.org/10.1080/10426500490262603

[15]. Frechet, J. M. J.; Darling, P.; Farrall, M. J. Org. Chem. 1981, 46, 1728-1730.
https://doi.org/10.1021/jo00321a042

[16]. Guziec, F. S. Jr.; Luzzio, F. A. J. Org. Chem. 1982, 47, 1787-1792.
https://doi.org/10.1021/jo00348a045

[17]. Degirmenbasi, N.; Ozgun, B. Monatsh. Chem. 2002, 133, 1417-1421.
https://doi.org/10.1007/s00706-002-0476-9

[18]. Vogel, A. Vogel's Textbook of Practical Organic Chemistry, 5th Edition. Longman Scientific and Technical: New York, 1989.

[19]. Soofivand, F.; Mohandes, F.; Salavati-Niasari, M. Mater. Res. Bull. 2013, 48, 2084-2094.
https://doi.org/10.1016/j.materresbull.2013.02.025

[20]. Cieglak-Golonka, M. J. Therm. Anal. Calorim. 1992, 38, 2501-2513.
https://doi.org/10.1007/BF01974628

Supporting Agencies

This work was financially supported by Çanakkale Onsekiz Mart University Research Fund. (Project No, BAP, 2014/191-Turkey). The authors would also like to thank Yıldız YILDIRIM (KALESERAMIK A.Ş. ArGe, Turkey) for the TG/DTG and XRD analysis.
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).